Corrosion and Protection of Buried Important Pipelines

摘 要
埋地重要管线在周围土壤环境中的腐蚀与防护是管线安全可靠性和寿命管理的关键内容之一.本文第一部分简要综述了近年来有关埋地管线腐蚀与防护的世界性热点问题之一:高压管线在土壤中的应力腐蚀破裂(SCC),介绍了作者针对西气东输华东段和上海高压天然气管网材料在相关的高pH和近中性pH两类土壤环境中SCC特性和防护措施的研究.本文第二部分简要综述了外防护涂层的发展,并介绍了作为上海重点工程之一的青草沙引水工程输水管线的外防护涂层和性能检测.












Abstract
The corrosion and protection in soil environments is one of the key issues of the structural integrity and life management of buried important pipelines.In the first part of this paper,the stress corrosion cracking (SCC) of high pressure pipelines as one of the hot problems of corrosion and protection of buried pipelines in the world is briefly reviewed,and the research of the authors on the SCC behavior and its protection of the pipeline steels in relevant high pH and near-neutral pH soil environments for high pressure gas long-distance transmission pipeline in eastern China and network in Shanghai area is described.In the second part of this paper,the development of anti-corrosion coatings for pipelines is briefly reviewed,and the coating selected and relevant tests for the main pipeline in Qingcaosha Water Project as one of the ongoing key projects in Shanghai are also introduced.
中图分类号 TG174.4
所属栏目 专题报告
基金项目 上海市科委国际合作基金资助项目(08520708000)
收稿日期 2009/7/15
修改稿日期
网络出版日期

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备注李光福,教授.
引用该论文: LI Guang-fu,YANG Wu. Corrosion and Protection of Buried Important Pipelines[J]. Corrosion & Protection, 2009, 30(9): 620~630
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参考文献
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【4】杨武.埋地油气管线应力腐蚀破裂研究的一些新进展[J].腐蚀与防护,2003,24(11):461-467.
【5】Sridhar N,Dunn D S,Anderko A.Prediction of conditions leading to stress corrosion cracking of gas transmission lines[C]//Environmentally Assisted Cracking: Predictive Methods for Risk Assessment and Evaluation of Materials,Equipment,and Structures.ASTM STP 1401 R D Kane,Ed.West Conshohocken PA USA:American Society for Testing and Materials,2000:241-258.
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【8】方丙炎,王俭秋,朱自勇,等.埋地管道在近中性pH和高pH环境中的应力腐蚀破裂[J].金属学报,2001,37(5):453-45.
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【10】Beavers J A,Jaske C E.Near-neutral pH SCC in pipelines: effects of pressure fluctuations on crack propagation[C]//Corrosion/98,NACE International,Houston TX:1998:257.
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【14】Song F M,Kird D W,Graydon J W,et al.Steel corrosion under a disbonded coating with a holiday,Part 1:the model and validation[J].Corrosion,2002,58(12):1015-1024.
【15】Chen W,King F,Jack T R,et al.Environmental aspects of near-neutral pH stress corrosion cracking of pipeline steels[J].Metallurgical and Materials Transactions A,2002,33A:1429-1436.
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【18】Parkins R N.Strain rate effects in stress corrosion cracking[J].Corrosion,1990,46(3):178-189.
【19】霍春勇,马秋荣,冯耀荣,等.高压天然气管线与高钢级管线钢[C]//石油管工程应用基础研究论文集.北京:石油工业出版社,2001:53-66.
【20】Wang J Q,Atrens A,Cousens D R,et al.Microstructure of X52 and X65 pipeline steels[J].Journal of Materials Science,1999,34:1721-1728.
【21】Sharma U,Ivey D G.Microstructure of microalloyed linepipe steels[C]//2000 International Pipeline Conference-volume 1.ASME,2000:193-201.
【22】Kushida T,Nose K,Asahi H,et al.Effects of metallurgical factors and test conditions on near neutral pH SCC of pipeline steels[C]//Corrosion/2001.Houston TX:NACE International,2001:01213.
【23】Beavers J A,Johnson J T,Sutherby R L.Materials factors influencing the initiation of near-neutral pH SCC on underground pipelines[C]//2000 International Pipeline Conference-Volume 2.ASME,2000:979-988.
【24】Hunt C P.The effect of impurities on the intergranular stress corrosion cracking of a C/Mn steel[J].Corrosion Science,1988,28(9):901-922.
【25】Jeffrey B,Luo J L.Effect of microstructure on near-neutral-pH SCC[C]//2000 International Pipeline Conference-volume 2.ASME,2000:947-952.
【26】Asahi H,Kushida T,Kimura M,et al.Role of microstructures on stress corrosion cracking of pipeline steels in carbonate-bicarbonate solution[J].Corrosion,1999,55(7):644-652.
【27】Beavers J A,Harper W V.Stress corrosion cracking prediction model[C]//Corrosion/2004.Houston TX:NACE International,2004:04189.
【28】King F,Boven G V,Jack T,et al.Predicting the growth of low-and high pH SCC on gas transmission pipelines based on operating conditions[C]//Corrosion/2003:Research Topical Symposium:Modeling and Prediction of Lifetimes for Corrodible Structure.NACE International,Houston:2003:127-155.
【29】Yang W,Li G F,Zhang G L,et al.Effects of pH and potential on stress corrosion cracking behaviors of pipeline steels[C]//Proceedings of 17th International Corrosion Congress.NACE International,Houston,2008:2576.
【30】Li G F,Zhang G L,Huang C B,et al.Stress corrosion cracking behavior of pipeline steel X60 in near-neutral pH soil environments around shanghai[C]//Proceedings of 9th International Conference on Engineering Structural Integrity-Research,Development and Application.2007:Beijing,269-272.
【31】李光福,张国良,孙振华,等.管线钢X60和SS400在上海相关近中性pH土壤环境中的应力腐蚀破裂特性[C]//2007全国埋地管线腐蚀控制和检测评估工程技术交流会论文集.吉林延吉:2007:259-262.
【32】李光福,张国良,孙振华,等.电极电位和材料因素对X60和SS400在高pH模拟土壤环境中应力腐蚀破裂的影响[C]//2007全国埋地管线腐蚀控制和检测评估工程技术交流会论文集.吉林延吉:2007,255-258.
【33】张国良,李光福,周建江,等.电极电位和温度对X70钢在高pH模拟土壤环境中应力腐蚀破裂的影响[J].腐蚀与防护,2007,28(9):437-441.
【34】Li G F,Zhang G L,Zhou J J,et al.Characteristics and mechanism of high pH stress corrosion cracking of high pH stress corrosion cracking of pipeline steel X70[J].Key Engineering Materials,2007,353-358:219-222.
【35】Li G F,Huang C B,Guo H,et al.Stress corrosion cracking of pipeline steel in soil environments of eastern china[J].Key Engineering Materials,2007,353-358:223-226.
【36】Yang W,Li G F,Guo H,et al.Stress corrosion cracking of pipeline steels[C]//Proceedings of 16th International Corrosion Congress.北京:2005,10-SCC-13.
【37】Guo H,Li G F,Cai X,et al.Effect of cyclic loading on SCC behaviour of X-70 pipeline steel in near-neutral pH solutions[J].Journal of Materials Science and Technology,2005,21(4):459-464.
【38】Guo H,Li G F,Cai X,et al.SCC behavior of X-70 pipeline steel in near-neutral pH solutions[J].Journal of Materials Science and Technology,2005,21(1):33-38.
【39】黄春波,李光福,杨武.X70管线钢焊缝应力腐蚀破裂的研究[J].腐蚀与防护,2005,26(1):1-5.
【40】Yang W,Li G F,Guo H,et al.Effects of environmental factors on stress corrosion cracking of pipeline steels[J].Key Engineering Materials,2005,297-300(Part 2):939-944.(下转第644页)
【41】Guo H,Li G F,Cai X,et al.Effect of cyclic loading on crack propagation of X-70 pipeline steel in near-neutral pH solutions[J].Key Engineering Materials,2005,297-300(Part 4):2501-2507.
【42】郭浩,李光福,蔡珣,等.恒位移加载条件下X-70管线钢在近中性pH溶液中的裂纹扩展行为[J].腐蚀与防护,2004,25(12):510-512.
【43】郭浩,李光福,蔡珣,等.外加电位对X70管线钢在近中性pH溶液中的应力腐蚀破裂的影响[J].中国腐蚀与防护学报,2004,24(4):208-212.
【44】郭浩,李光福,蔡珣,等.X70管线钢在不同温度近中性pH溶液中的应力腐蚀破裂行为[J].金属学报,2004,40(9):967-971.
【45】杨武,李光福,郭浩.国产管线钢的环境开裂性能研究[J].材料导报,2004,18(8):127-130.
【46】Parkins R N.Mechanisms of stress-corrosion cracking[M].in Corrosion,Vol.1(metal/environment reactions),Third edition.Shreir L L Ed.UK:Newnes-Butterworths-Heinemann Ltd,Oxford,1994:1-31.
【47】胡士信.阴极保护工程手册[M].北京:化学工业出版社,1999:232-254.
【48】唐谊平,李建新,黄子阳,等.长输管线外防护涂层技术的现状与发展探讨[J].腐蚀与防护,待发表.
【2】郭浩,蔡珣,杨武.影响管线钢应力腐蚀破裂的力学和材料因素[J].机械工程材料,2002,26(4):1-5.
【3】郭浩,蔡珣,杨武.管线钢应力腐蚀破裂的机理与寿命预测[J].机械工程材料,2002,26(10):1-3.
【4】杨武.埋地油气管线应力腐蚀破裂研究的一些新进展[J].腐蚀与防护,2003,24(11):461-467.
【5】Sridhar N,Dunn D S,Anderko A.Prediction of conditions leading to stress corrosion cracking of gas transmission lines[C]//Environmentally Assisted Cracking: Predictive Methods for Risk Assessment and Evaluation of Materials,Equipment,and Structures.ASTM STP 1401 R D Kane,Ed.West Conshohocken PA USA:American Society for Testing and Materials,2000:241-258.
【6】左景伊.应力腐蚀破裂[M].西安:西安交通大学出版社,1985,1-3.
【7】Kentish P J.Gas pipeline failures: Australian experience[J].Br Corros J,1985,20(3):139-146.
【8】方丙炎,王俭秋,朱自勇,等.埋地管道在近中性pH和高pH环境中的应力腐蚀破裂[J].金属学报,2001,37(5):453-45.
【9】Sridhar N,Lichtner P C,Dunn D S.Evolution of environment under disbonded coating on cathodically protected pipeline——preliminary modeling and experimental studies[C]//Corrosion/98.Houston TX:NACE International,1998:680.
【10】Beavers J A,Jaske C E.Near-neutral pH SCC in pipelines: effects of pressure fluctuations on crack propagation[C]//Corrosion/98,NACE International,Houston TX:1998:257.
【11】李鹤林.天然气输送钢管研究与应用中的几个热点问题[C]//石油管工程应用基础研究论文集.北京:石油工业出版社,2001:3-18.
【12】National Energy Board (NEB),Public Inquiry Concerning Stress Corrosion Cracking on Canadian Oil and Gas Pipelines[C]//NEB Report MH-2-95,Calgary,AB Canada:1996.
【13】Jack T R,Erno B,Krist K.Generation of near neutral pH and high pH SCC environments on buried pipelines[C]//Corrosion/2000.Houston TX:NACE International,2000:362.
【14】Song F M,Kird D W,Graydon J W,et al.Steel corrosion under a disbonded coating with a holiday,Part 1:the model and validation[J].Corrosion,2002,58(12):1015-1024.
【15】Chen W,King F,Jack T R,et al.Environmental aspects of near-neutral pH stress corrosion cracking of pipeline steels[J].Metallurgical and Materials Transactions A,2002,33A:1429-1436.
【16】Beavers J A,Delanty B S,Sutherby R L,et al.Near-neutral pH SCC in susceptible soil environments[C]//Corrosion/2001.Houston:NACE International,2001:01217.
【17】Wang Y Z,Revie R W,Shehata M T,et al.Initiation of environment induced cracking in pipeline steel: microstructural correlations[C]//International Pipeline Conference-Volume 2.ASME,2000:979-988.
【18】Parkins R N.Strain rate effects in stress corrosion cracking[J].Corrosion,1990,46(3):178-189.
【19】霍春勇,马秋荣,冯耀荣,等.高压天然气管线与高钢级管线钢[C]//石油管工程应用基础研究论文集.北京:石油工业出版社,2001:53-66.
【20】Wang J Q,Atrens A,Cousens D R,et al.Microstructure of X52 and X65 pipeline steels[J].Journal of Materials Science,1999,34:1721-1728.
【21】Sharma U,Ivey D G.Microstructure of microalloyed linepipe steels[C]//2000 International Pipeline Conference-volume 1.ASME,2000:193-201.
【22】Kushida T,Nose K,Asahi H,et al.Effects of metallurgical factors and test conditions on near neutral pH SCC of pipeline steels[C]//Corrosion/2001.Houston TX:NACE International,2001:01213.
【23】Beavers J A,Johnson J T,Sutherby R L.Materials factors influencing the initiation of near-neutral pH SCC on underground pipelines[C]//2000 International Pipeline Conference-Volume 2.ASME,2000:979-988.
【24】Hunt C P.The effect of impurities on the intergranular stress corrosion cracking of a C/Mn steel[J].Corrosion Science,1988,28(9):901-922.
【25】Jeffrey B,Luo J L.Effect of microstructure on near-neutral-pH SCC[C]//2000 International Pipeline Conference-volume 2.ASME,2000:947-952.
【26】Asahi H,Kushida T,Kimura M,et al.Role of microstructures on stress corrosion cracking of pipeline steels in carbonate-bicarbonate solution[J].Corrosion,1999,55(7):644-652.
【27】Beavers J A,Harper W V.Stress corrosion cracking prediction model[C]//Corrosion/2004.Houston TX:NACE International,2004:04189.
【28】King F,Boven G V,Jack T,et al.Predicting the growth of low-and high pH SCC on gas transmission pipelines based on operating conditions[C]//Corrosion/2003:Research Topical Symposium:Modeling and Prediction of Lifetimes for Corrodible Structure.NACE International,Houston:2003:127-155.
【29】Yang W,Li G F,Zhang G L,et al.Effects of pH and potential on stress corrosion cracking behaviors of pipeline steels[C]//Proceedings of 17th International Corrosion Congress.NACE International,Houston,2008:2576.
【30】Li G F,Zhang G L,Huang C B,et al.Stress corrosion cracking behavior of pipeline steel X60 in near-neutral pH soil environments around shanghai[C]//Proceedings of 9th International Conference on Engineering Structural Integrity-Research,Development and Application.2007:Beijing,269-272.
【31】李光福,张国良,孙振华,等.管线钢X60和SS400在上海相关近中性pH土壤环境中的应力腐蚀破裂特性[C]//2007全国埋地管线腐蚀控制和检测评估工程技术交流会论文集.吉林延吉:2007:259-262.
【32】李光福,张国良,孙振华,等.电极电位和材料因素对X60和SS400在高pH模拟土壤环境中应力腐蚀破裂的影响[C]//2007全国埋地管线腐蚀控制和检测评估工程技术交流会论文集.吉林延吉:2007,255-258.
【33】张国良,李光福,周建江,等.电极电位和温度对X70钢在高pH模拟土壤环境中应力腐蚀破裂的影响[J].腐蚀与防护,2007,28(9):437-441.
【34】Li G F,Zhang G L,Zhou J J,et al.Characteristics and mechanism of high pH stress corrosion cracking of high pH stress corrosion cracking of pipeline steel X70[J].Key Engineering Materials,2007,353-358:219-222.
【35】Li G F,Huang C B,Guo H,et al.Stress corrosion cracking of pipeline steel in soil environments of eastern china[J].Key Engineering Materials,2007,353-358:223-226.
【36】Yang W,Li G F,Guo H,et al.Stress corrosion cracking of pipeline steels[C]//Proceedings of 16th International Corrosion Congress.北京:2005,10-SCC-13.
【37】Guo H,Li G F,Cai X,et al.Effect of cyclic loading on SCC behaviour of X-70 pipeline steel in near-neutral pH solutions[J].Journal of Materials Science and Technology,2005,21(4):459-464.
【38】Guo H,Li G F,Cai X,et al.SCC behavior of X-70 pipeline steel in near-neutral pH solutions[J].Journal of Materials Science and Technology,2005,21(1):33-38.
【39】黄春波,李光福,杨武.X70管线钢焊缝应力腐蚀破裂的研究[J].腐蚀与防护,2005,26(1):1-5.
【40】Yang W,Li G F,Guo H,et al.Effects of environmental factors on stress corrosion cracking of pipeline steels[J].Key Engineering Materials,2005,297-300(Part 2):939-944.(下转第644页)
【41】Guo H,Li G F,Cai X,et al.Effect of cyclic loading on crack propagation of X-70 pipeline steel in near-neutral pH solutions[J].Key Engineering Materials,2005,297-300(Part 4):2501-2507.
【42】郭浩,李光福,蔡珣,等.恒位移加载条件下X-70管线钢在近中性pH溶液中的裂纹扩展行为[J].腐蚀与防护,2004,25(12):510-512.
【43】郭浩,李光福,蔡珣,等.外加电位对X70管线钢在近中性pH溶液中的应力腐蚀破裂的影响[J].中国腐蚀与防护学报,2004,24(4):208-212.
【44】郭浩,李光福,蔡珣,等.X70管线钢在不同温度近中性pH溶液中的应力腐蚀破裂行为[J].金属学报,2004,40(9):967-971.
【45】杨武,李光福,郭浩.国产管线钢的环境开裂性能研究[J].材料导报,2004,18(8):127-130.
【46】Parkins R N.Mechanisms of stress-corrosion cracking[M].in Corrosion,Vol.1(metal/environment reactions),Third edition.Shreir L L Ed.UK:Newnes-Butterworths-Heinemann Ltd,Oxford,1994:1-31.
【47】胡士信.阴极保护工程手册[M].北京:化学工业出版社,1999:232-254.
【48】唐谊平,李建新,黄子阳,等.长输管线外防护涂层技术的现状与发展探讨[J].腐蚀与防护,待发表.
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