Microstructure and Properties of 2A97 Aluminum-Lithium Alloy after Different Aging Processes
摘 要
对2A97铝锂合金进行自然时效(0~90 d)、不同温度的单级人工时效(145, 165, 185 ℃)和自然时效(T4)+185 ℃人工时效的双级时效处理, 研究了时效工艺对合金硬化曲线、组织和力学性能的影响, 并分析了拉伸断口形貌。结果表明: 试验合金经自然时效(T4)处理后的主要强化相为δ′、GP区和δ′/β′复合粒子, 此时合金的强度较低、塑性较高, 拉伸断口上分布着较多韧窝; 经不同温度单级人工时效处理后, 合金抗拉强度显著提高的同时塑性明显下降, 断口形貌呈冰糖状, 其中185 ℃×10 h单级时效处理后的强塑性均较好, 其抗拉强度、屈服强度和伸长率分别为537, 506 MPa和7.0%; 与185 ℃单级时效的相比, T4(60 d)+185 ℃双级时效后, 合金的硬度出现了先下降后上升的现象, 并且达到峰值的时间推迟了20 h, 但强度和塑性均有所提高, 断口为沿晶、穿晶约各占一半的混合型断裂, 塑性有所改善。
Abstract
Natural aging (0-90 d), single stage artificial aging at different temperature (145,165, 185 ℃) and double aging of natural aging (T4) with artificial aging at 185 ℃ for 2A97 Al-Li alloy were carried out. The effects of aging process on hardening curves, microstructure and mechanical properties were studied, and the tensile fracture morphology was observed also. The results show that the main strengthed precipitations of the alloy after natural aging were δ′, GP zone and δ′/β′ composite particles, and in that state the alloy had a preferable plasticity with poor strength and tensile fracture surface with plenty of dimples. The strength of the alloy was enhanced markedly while the plasticity declined distinctly after single artificial aging at different temperatures, and rock candy shape fracture morphology was also shown. Favorable strength and plasticity were obtained after the alloy was aged at 185 ℃ for 10 h, and the tensile strength, yield strength and elongation were 537 MPa, 506 MPa and 7.0%, respectively. Compared with the alloy after single-stage artificial aging at 185 ℃, a reversion phenomenon appeared in the alloy, i.e., the hardness decreased firstly and then increased during further aging when aging at 185 ℃ following by natural aging for 60 days. And its peak time delayed about 20 h, but the strength and plasticity were both improved, and the fracture morphology was mixed intergranular and transgranular fracture.
中图分类号 TG146.2
所属栏目 试验研究
基金项目 国家自然科学基金资助项目(51271076);广东省教育部产学研结合项目(2011B090400500)
收稿日期 2013/3/22
修改稿日期 2013/10/1
网络出版日期
作者单位点击查看
备注高文理(1964-), 男, 黑龙江集贤人, 副教授, 博士。
引用该论文: GAO Wen-li,YAN Hao,FENG Zhao-hui,LU Zheng. Microstructure and Properties of 2A97 Aluminum-Lithium Alloy after Different Aging Processes[J]. Materials for mechancial engineering, 2014, 38(5): 21~25
高文理,闫豪,冯朝辉,陆政. 不同工艺时效后2A97铝锂合金的组织与性能[J]. 机械工程材料, 2014, 38(5): 21~25
被引情况:
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【2】曾旭,张显程,涂善东,轩福贞, "热处理对GH4169合金组织及低周疲劳寿命的影响",机械工程材料 40, 21-24(2016)
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参考文献
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【2】SANDERS J T H, BALMUTH E S. Aluminum-lithium alloys: low density and high stiffness[J].Metal Progress,1978,113(1):32-35.
【3】AHMADI S, ARABI H, SHOKUHFAR A. Effects of multiple strengthening treatments on mechanical properties and stability of nanoscale precipitated phases in an aluminum-copper-lithium alloy[J].Journal of Materials Science,2010,26(12):1078-1082.
【4】夏德顺. 新型轻合金结构材料在航天运载器上的应用与分析(上)[J].导弹与航天运载技术,2000(4):18-22.
【5】PICKENS JR, KRAMER L S, LANGAN T J, et al. The effect of Zn on nucleation in Al-Cu-Li-Ag-Mg Alloy[C]//Sixth International Alumium -Lithium Conference.[S.l]:[s.n.].1991: 357-362.
【6】CROSS C E, LOECHEL LW, BRAUN G F. Weldalite049 weld development for aerospace tankage. [C]//Sixth International Alumium-Lithium Conference.[S.l]:[s.n.].1991: 1165-1170.
【7】GUPTA R K, NAYAN N, NAGASIREESHA G, et al. Development and characterization of Al-Li alloys[J].Materials Science and Engineering:A,2006,420(1):228-234.
【8】钟申,郑子樵,廖忠全,等.时效制度对2A97铝锂合金强韧性的影响[J].中国有色金属学报,2011,21(3):448-552.
【9】李红英,王晓峰,宾杰,等.2种时效制度对2A97合金组织和性能的影响[J].中南大学学报: 自然科学版,2011,42(5):1262-1268.
【10】WILLIAMS D B, EDINGTON J W. The precipitation of δ′ (Al3Li) in dilute aluminium-lithium alloys[J].Metal Science,1975,9(12):529-532.
【11】HUANG B P, ZHENG Z Q. Independent and combined roles of trace Mg and Ag additions in properties precipitation process and precipitation kinetics of Al-Cu-Li-(Mg)-(Ag)-Zr-Ti alloys[J].Acta Materialia,1998,46(12):4381-4393
【12】NOBLE B, THONGSON G E. T1(Al2CuLi) precipitation in aluminium-copper-lithium alloys[J].Metal Science,1972,6(1):167-174.
【13】夏卿坤,刘志义,余日成,等.Al-Cu-Mg-Ag铝合金高温持久过程中组织与性能的演变[J].机械工程材料,2007,31(2):9-11.
【14】袁志山,吴秀亮,陆政,等.2A97铝锂合金时效行为研究[J].稀有金属材料与工程,2008,37(11):1898-1902.
【15】GAYLE F W, HEUBAUM F H, PICKENS J R. Structure and properties during aging of an ultra-high strength Al-Cu-Li-Ag-Mg alloy[J].Scripta Metallurgica et Materialia,1990,24(5):79-84.
【16】KUMAR K S, HEUBAUM F H. The effect of Li content on the natural aging response of Al-Cu-Li-Mg-Ag-Zr alloys[J].Acta Materialia,1997,45(6):2317-2326.
【17】KUMAR K S, BROWN S A, PICKENS J R. Microstructu-ral evolution during aging of an Al-Cu-Li-Ag-Mg-Zr alloy[J].Acta Materialia,1996,44(5):1899-1915.
【18】宁爱林,孙瑜,黄继武.不同时效工艺对6063铝合金组织和力学性能的影响[J].机械工程材料,2013,37(3):28-31.
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