430不锈钢表面GPTMS/PFDS自组装双层膜的制备及缓蚀性能
Preparation and Corrosion Inhibition of GPTMS/PFDS Self-assembled Bilayer on 430 Stainless Steel
摘 要
在430不锈钢表面制备了γ-缩水甘油醚氧丙基三甲氧基硅烷(GPTMS)/全氟癸基三乙氧基硅烷(PFDS)自组装双层膜。采用傅里叶变换红外光谱、电化学测试、接触角和SEM研究了自组装膜的吸附及对不锈钢电极的缓蚀性能。结果表明, GPTMS/PFDS双层膜比GPTMS单层膜和PFDS单层膜具有更优异的抗腐蚀性能。
GPTMS
PFDS
自组装双层膜
缓蚀性
430 stainless steel
GPTMS
PFDS
self-assembled bilayer
corrosion inhibition
Abstract
Self-assembled bilayer of GPTMS/PFDS was prepared on the surface of 430 stainless steel. Fourier transform infrared (FTIR) spectroscopy, electrochemical measurements, contact angle and scanning electron microscopy (SEM) were used to study the adsorption of self-assembled films and their corrosion inhibition for 430 stainless steel. The results showed that the GPTMS/PFDS bilayer exhibited better corrosion resistance than the single layer film of GPTMS SAM or PFDS SAM.
中图分类号 TG174.42
所属栏目 试验研究
基金项目
收稿日期 2013/3/4
修改稿日期
网络出版日期
作者单位点击查看
联系人作者屈钧娥(qje@hubu.edu.cn)
备注屈钧娥(1978-),副教授,博士,从事材料腐蚀与防护研究,
引用该论文: WANG Hai-ren,LI Min-ya,QU Jun-e,CAO Zhi-yong,XIE E-mei,ZHEN Guo-hui. Preparation and Corrosion Inhibition of GPTMS/PFDS Self-assembled Bilayer on 430 Stainless Steel[J]. Corrosion & Protection, 2014, 35(1): 60
共有人对该论文发表了看法，其中：
人认为该论文很差
人认为该论文较差
人认为该论文一般
人认为该论文较好
人认为该论文很好
参考文献
【1】SINAPI F,FORGET L,DELHALLE J,et al. Self-assembly of (3-mercaptopropyl) trimethoxysilane on polycrystalline zinc substrates towards corrosion protection[J]. Thin Solid Films,2002,405(112):186-193.
【2】MEKHALIF Z,SINAPIA F,DELHALLEA J. XPS and electrochemical evaluation of two-dimensional organic films obtained by chemicalmodification of self-assembled monolayers of (3-mercaptopropyl) trimethoxysilane on copper surfaces[J]. Materials Science and Engineering,2002,22(9):345-353.
【3】FRANQUET A,LEPEN C,TERRYN H,et al. Effect of both concentration and curing time on the structure of non-functional thin organosilane layers on aluminium[J]. Electrochimica Acta,2003,48(9):1245-1255.
【4】VANOOIJ W J,ZHU D. Electrochemical impedance spectroscopy of bis[triethoxysilypropyl]tetrasulfide on Al 2024-T3 substrates[J]. Corrosion,2001,57(5):413-427.
【5】BECCARTA A M,CHTARUTTINI L. The inhibitive action of metacryloxpropylmethoxysilane on aluminium corrosion in NaCl solutions[J]. Corrosion Science,1999,41(5):885-899.
【6】ZUCCHI F,GRASSI V,FRIGNANI A,et al. Influence of a silane treatment on the corrosion resistance of a WE43 magnesium alloy[J]. Surface and Coatings Technology,2006,200(12/13):4136-4143.
【7】MONTEMOR M F,PTNTO R,FERREIRA M G S. Chemical composition and corrosion protection of silane films modified with CeO2 nanoparticles[J]. Electrochimica Acta,2009,54(22):5179-5189.
【8】GHAREBA S,OMANOVIC S. Interaction of 12-aminododecanoic acid with a carbon steel surface:Towards the development of green corrosion inhibitors[J]. Corrosion Science,2010,52(6):2104-2113.
【2】MEKHALIF Z,SINAPIA F,DELHALLEA J. XPS and electrochemical evaluation of two-dimensional organic films obtained by chemicalmodification of self-assembled monolayers of (3-mercaptopropyl) trimethoxysilane on copper surfaces[J]. Materials Science and Engineering,2002,22(9):345-353.
【3】FRANQUET A,LEPEN C,TERRYN H,et al. Effect of both concentration and curing time on the structure of non-functional thin organosilane layers on aluminium[J]. Electrochimica Acta,2003,48(9):1245-1255.
【4】VANOOIJ W J,ZHU D. Electrochemical impedance spectroscopy of bis[triethoxysilypropyl]tetrasulfide on Al 2024-T3 substrates[J]. Corrosion,2001,57(5):413-427.
【5】BECCARTA A M,CHTARUTTINI L. The inhibitive action of metacryloxpropylmethoxysilane on aluminium corrosion in NaCl solutions[J]. Corrosion Science,1999,41(5):885-899.
【6】ZUCCHI F,GRASSI V,FRIGNANI A,et al. Influence of a silane treatment on the corrosion resistance of a WE43 magnesium alloy[J]. Surface and Coatings Technology,2006,200(12/13):4136-4143.
【7】MONTEMOR M F,PTNTO R,FERREIRA M G S. Chemical composition and corrosion protection of silane films modified with CeO2 nanoparticles[J]. Electrochimica Acta,2009,54(22):5179-5189.
【8】GHAREBA S,OMANOVIC S. Interaction of 12-aminododecanoic acid with a carbon steel surface:Towards the development of green corrosion inhibitors[J]. Corrosion Science,2010,52(6):2104-2113.
相关信息
