有机涂层剥离的微区电化学研究进展
Progress in Study of Localized Electrochemical Measurement Techniques to Coating Disbonding
摘 要
介绍了有机涂层剥离的关键影响因素，并阐述了先进的微区电化学测试技术，包括扫描参比电极技术(SRET)、扫描振动参比电极技术(SVET)、扫描开尔文探针(SKP)、局部电化学阻抗谱(LEIS)等在有机涂层剥离研究中的应用进展。将近年来逐渐成熟的具有高空间分辨率的微区电化学理论和研究方法应用于有机涂层剥离的研究，对于探索剥离的扩展规律和机制，从本质上认识涂层/金属界面过程具有重要意义。
剥离影响因素
微区电化学测试技术
organic coating
delamination affecting factor
localized electrochemical measurement technique
Abstract
The critical affecting factors of the coating disbonding are introduced. The applications of advanced localized electrochemical measurement techniques, including scanning reference electrode technique (SRET), scanning vibrating electrode technique (SVET), scanning Kelvin probe (SKP), and localized electrochemical impedance spectroscopy (LEIS) in the field of coating disbonding are also expounded. The use of high spatially resolved localized electrochemical measurement techniques in the area of coating disbonding has vital significance for the exploration of the metal/coating interface process.
中图分类号 TG174.44
所属栏目 专论
基金项目 国家高技术研究发展计划(863计划)(2012AA040105-05)
收稿日期 2013/4/5
修改稿日期
网络出版日期
作者单位点击查看
备注王力伟(1984-),博士后,从事材料腐蚀与防护相关研究，
引用该论文: WANG Li-wei,WANG Xin-hua,LU Lin,LI Xiao-gang. Progress in Study of Localized Electrochemical Measurement Techniques to Coating Disbonding[J]. Corrosion & Protection, 2014, 35(2): 158
被引情况:
【1】王健生, "承载作用下铁红环氧脂底漆失效过程的电化学响应特征",腐蚀与防护 37, 414-418(2016)
共有人对该论文发表了看法，其中：
人认为该论文很差
人认为该论文较差
人认为该论文一般
人认为该论文较好
人认为该论文很好
参考文献
【1】张鉴清,曹楚南. 电化学阻抗谱方法研究评价有机涂层[J]. 腐蚀与防护,1998,19(2):99-104.
【2】BRASHER D M,KINGSBURY A H. Electrical measurements in the study of immersed paint coatings on metal. I. Comparison between capacitance and gravimetric methods of estimating water uptake[J]. Journal of Applied Chemistry,1954,4:62-72.
【3】HIRAYAMA R,HARUYAMA S. Electrochemical impedance for degraded coated steel having pores[J]. Corrosion,1991,47:952-958.
【4】DUARTE R G,CASTELA A S,FERREIRA M G S. Influence of ageing factors on the corrosion behaviour of polyester coated systems-A EIS study[J]. Progress in Organic Coatings,2007,59:206-213.
【5】YASUDA H,YU Q S,CHEN M. Interfacial factors in corrosion protection:An EIS study of model systems[J]. Progress in Organic Coatings,2001,41:273-279.
【6】LUO J L,LIN C J,YANG Q,et al. Cathodic disbonding of a thick polyurethane coating from steel in sodium chloride solution[J]. Progress in Organic Coatings,1997,31:289-295.
【7】温国谋,蔡长寿,刘碧环,等. 可移式电解槽测定涂装体系的交流阻抗[J]. 中国腐蚀与防护学报,1992,12:63-70.
【8】王超,盛敏奇,钟庆东,等. 碳钢/醇酸涂层在5% NaCl溶液中的极化及半导体行为[J]. 化学学报,2009,67:709-715.
【9】胡吉明,张鉴清,谢德明,等. 水在有机涂层中的传输[J]. 中国腐蚀与防护学报,2002,22:311-317.
【10】LENG A,STRECKEL H,STRATMANN M. The delamination of polymeric coatings from steel. Part 1: Calibration of the Kelvin probe and basic delamination mechanism[J]. Corrosion Science,1998,41:547-578.
【11】DEFLORIAN F,ROSSI S. An EIS study of ion diffusion through organic coatings[J]. Electrochimica Acta,2006,51:1736-1744.
【12】NAZAROV A P,THIERRY D. Scanning Kelvin probe study of metal/polymer interfaces[J]. Electrochimica Acta,2004,49:2955-2964.
【13】WESSLING B,POSDORFER J. Corrosion prevention with an organic metal (polyaniline): Corrosion test results[J]. Electrochimica Acta,1999,44:2139-2147.
【14】VANDER W D H,VANWESTING E P M,DEWIT J H W. EIS measurements on artificial blisters in organic coatings[J]. Electrochimica Acta,1996,41:1103-1107.
【15】NGUYEN V,PERRIN F,VERNET J. Water permeability of organic/inorganic hybrid coatings prepared by sol-gel method: A comparison between gravimetric and capacitance measurements and evaluation of non-Fickian sorption models[J]. Corrosion Science,2005,47:397-412.
【16】LENG A,STRECKEL H,HOFMANN K,et al. The delamination of polymeric coatings from steel Part 3:Effect of the oxygen partial pressure on the delamination reaction and current distribution at the metal/polymer interface[J]. Corrosion Science,1998,41:599-620.
【17】LEIDHEISER H,WANG W,IGETOFT L. The mechanism for the cathodic delamination of organic coatings from a metal surface[J]. Progress in Organic Coatings,1983,11:19-40.
【18】POSNER R,WAPNER K,STRARMANN M,et al. Transport processes of hydrated ions at polymer/oxide/metal interfaces: Part 1. Transport at interfaces of polymer coated oxide covered iron and zinc substrates[J]. Electrochimica Acta,2009,54:891-899.
【19】SKAR J I,STEINSMO U. Cathodic disbonding of paint films-transport of charge[J]. Corrosion Science,1993,35:1385-1389.
【20】KINSELLA E,MAYNE J. Ionic conduction in polymer films I. Influence of electrolyte on resistance[J]. British Polymer Journal,2006,1:173-176.
【21】REDDY B,SYKES J. Degradation of organic coatings in a corrosive environment: A study by scanning Kelvin probe and scanning acoustic microscope[J]. Progress in Organic Coatings,2005,52:280-287.
【22】GRUNDMEIER G,SCHMIDT W,STRATMANN M. Corrosion protection by organic coatings: Electrochemical mechanism and novel methods of investigation[J]. Electrochimica Acta,2000,45:2515-2533.
【23】FVRBETH W,STRATMANN M. Scanning Kelvinprobe investigations on the delamination of polymeric coatings from metallic surfaces[J]. Progress in Organic Coatings,2000,39:23-29.
【24】DELA F D,CHICO B,MOCcillo M. A SEM/XPS/SKP study on the distribution of chlorides in contaminated rusty steel[J]. Corrosion science,2006,48:2304-2316.
【25】NAZAROV A,THIERRY D. Scanning Kelvin probe study of metal/polymer interfaces[J]. Electrochimica Acta,2004,49:2955-2964.
【26】张伟,王佳,姜晶,等. 有机涂层失效过程的电化学阻抗和电位分布响应特征[J]. 高等学校化学学报,2009,30:722-766.
【27】ZOU F,THIERRY D. Localized electrochemical impedance spectroscopy for studying the degradation of organic coatings[J]. Electrochimica Acta,1997,42:3293-3301.
【28】ZHONG C,TANG X,CHENG Y F. Corrosion of steel under the defected coating studied by localized electrochemical impedance spectroscopy[J]. Electrochimica Acta,2008,53:4740-4747.
【29】DONG C F,FU A Q,LI X G,et al. Localized EIS characterization of corrosion of steel at coating defect under cathodic protection[J]. Electrochimica Acta,2008,54:628-633.
【30】DEHRI I,HOWARD R L,LYON S B. Local electrochemical impedance at the cut-edge of coil-coated galvanized steel after corrosion testing[J]. Corrosion Science,1999,41:141-154.
【31】JORCIN J B,ARAGON E,MERLATTI C,et al. Delaminated areas beneath organic coating: A local electrochemical impedance approach[J]. Corrosion Science,2006,48:1779-1790.
【32】ZIN I,HOWARD R,BADGER S,et al. The mode of action of chromate inhibitor in epoxy primer on galvanized steel[J]. Progress in Organic Coatings,1998,33:203-210.
【33】KARAVAI O,BASTOS A,ZHELUDKEVICH M,et al. Localized electrochemical study of corrosion inhibition in microdefects on coated AZ31 magnesium alloy[J]. Electrochimica Acta,2010,55:5401-5406.
【34】薛丽莉,许立坤,李庆芬,等. 水性环氧铝粉涂层/碳钢体系的腐蚀电化学行为[J]. 电化学,2007,13:171-176.
【35】DEVOOYS A,VANDER W H. Investigating cracks and crazes on coated steel with simultaneous SVET and EIS[J]. Progress in Organic Coatings,2011,71:250-255.
【36】SOUTO R M,GONZLEZ GARCIA Y,GONZle S. Evaluation of the corrosion performance of coil-coated steel sheet as studied by scanning electrochemical microscopy[J]. Corrosion Science,2008,50:1637-1643.
【37】SOUTO R M,GONZLEZ GARCIA Y,LZQUIERDO J,et al. Examination of organic coatings on metallic substrates by scanning electrochemical microscopy in feedback mode: Revealing the early stages of coating breakdown in corrosive environments[J]. Corrosion Science,2010,52:748-753.
【38】SOUTO R M,GONZLEZ GARCIA Y,GONZLEZ S,et al. Damage to paint coatings caused by electrolyte immersion as observed in situ by scanning electrochemical microscopy[J]. Corrosion Science,2004,46:2621-2628.
【39】BASTODS A C,SIMES A M,GONZLEZ S,et al. Application of the scanning electrochemical microscope to the examination of organic coatings on metallic substrates[J]. Progress in Organic Coatings,2005,53:177-182.
【2】BRASHER D M,KINGSBURY A H. Electrical measurements in the study of immersed paint coatings on metal. I. Comparison between capacitance and gravimetric methods of estimating water uptake[J]. Journal of Applied Chemistry,1954,4:62-72.
【3】HIRAYAMA R,HARUYAMA S. Electrochemical impedance for degraded coated steel having pores[J]. Corrosion,1991,47:952-958.
【4】DUARTE R G,CASTELA A S,FERREIRA M G S. Influence of ageing factors on the corrosion behaviour of polyester coated systems-A EIS study[J]. Progress in Organic Coatings,2007,59:206-213.
【5】YASUDA H,YU Q S,CHEN M. Interfacial factors in corrosion protection:An EIS study of model systems[J]. Progress in Organic Coatings,2001,41:273-279.
【6】LUO J L,LIN C J,YANG Q,et al. Cathodic disbonding of a thick polyurethane coating from steel in sodium chloride solution[J]. Progress in Organic Coatings,1997,31:289-295.
【7】温国谋,蔡长寿,刘碧环,等. 可移式电解槽测定涂装体系的交流阻抗[J]. 中国腐蚀与防护学报,1992,12:63-70.
【8】王超,盛敏奇,钟庆东,等. 碳钢/醇酸涂层在5% NaCl溶液中的极化及半导体行为[J]. 化学学报,2009,67:709-715.
【9】胡吉明,张鉴清,谢德明,等. 水在有机涂层中的传输[J]. 中国腐蚀与防护学报,2002,22:311-317.
【10】LENG A,STRECKEL H,STRATMANN M. The delamination of polymeric coatings from steel. Part 1: Calibration of the Kelvin probe and basic delamination mechanism[J]. Corrosion Science,1998,41:547-578.
【11】DEFLORIAN F,ROSSI S. An EIS study of ion diffusion through organic coatings[J]. Electrochimica Acta,2006,51:1736-1744.
【12】NAZAROV A P,THIERRY D. Scanning Kelvin probe study of metal/polymer interfaces[J]. Electrochimica Acta,2004,49:2955-2964.
【13】WESSLING B,POSDORFER J. Corrosion prevention with an organic metal (polyaniline): Corrosion test results[J]. Electrochimica Acta,1999,44:2139-2147.
【14】VANDER W D H,VANWESTING E P M,DEWIT J H W. EIS measurements on artificial blisters in organic coatings[J]. Electrochimica Acta,1996,41:1103-1107.
【15】NGUYEN V,PERRIN F,VERNET J. Water permeability of organic/inorganic hybrid coatings prepared by sol-gel method: A comparison between gravimetric and capacitance measurements and evaluation of non-Fickian sorption models[J]. Corrosion Science,2005,47:397-412.
【16】LENG A,STRECKEL H,HOFMANN K,et al. The delamination of polymeric coatings from steel Part 3:Effect of the oxygen partial pressure on the delamination reaction and current distribution at the metal/polymer interface[J]. Corrosion Science,1998,41:599-620.
【17】LEIDHEISER H,WANG W,IGETOFT L. The mechanism for the cathodic delamination of organic coatings from a metal surface[J]. Progress in Organic Coatings,1983,11:19-40.
【18】POSNER R,WAPNER K,STRARMANN M,et al. Transport processes of hydrated ions at polymer/oxide/metal interfaces: Part 1. Transport at interfaces of polymer coated oxide covered iron and zinc substrates[J]. Electrochimica Acta,2009,54:891-899.
【19】SKAR J I,STEINSMO U. Cathodic disbonding of paint films-transport of charge[J]. Corrosion Science,1993,35:1385-1389.
【20】KINSELLA E,MAYNE J. Ionic conduction in polymer films I. Influence of electrolyte on resistance[J]. British Polymer Journal,2006,1:173-176.
【21】REDDY B,SYKES J. Degradation of organic coatings in a corrosive environment: A study by scanning Kelvin probe and scanning acoustic microscope[J]. Progress in Organic Coatings,2005,52:280-287.
【22】GRUNDMEIER G,SCHMIDT W,STRATMANN M. Corrosion protection by organic coatings: Electrochemical mechanism and novel methods of investigation[J]. Electrochimica Acta,2000,45:2515-2533.
【23】FVRBETH W,STRATMANN M. Scanning Kelvinprobe investigations on the delamination of polymeric coatings from metallic surfaces[J]. Progress in Organic Coatings,2000,39:23-29.
【24】DELA F D,CHICO B,MOCcillo M. A SEM/XPS/SKP study on the distribution of chlorides in contaminated rusty steel[J]. Corrosion science,2006,48:2304-2316.
【25】NAZAROV A,THIERRY D. Scanning Kelvin probe study of metal/polymer interfaces[J]. Electrochimica Acta,2004,49:2955-2964.
【26】张伟,王佳,姜晶,等. 有机涂层失效过程的电化学阻抗和电位分布响应特征[J]. 高等学校化学学报,2009,30:722-766.
【27】ZOU F,THIERRY D. Localized electrochemical impedance spectroscopy for studying the degradation of organic coatings[J]. Electrochimica Acta,1997,42:3293-3301.
【28】ZHONG C,TANG X,CHENG Y F. Corrosion of steel under the defected coating studied by localized electrochemical impedance spectroscopy[J]. Electrochimica Acta,2008,53:4740-4747.
【29】DONG C F,FU A Q,LI X G,et al. Localized EIS characterization of corrosion of steel at coating defect under cathodic protection[J]. Electrochimica Acta,2008,54:628-633.
【30】DEHRI I,HOWARD R L,LYON S B. Local electrochemical impedance at the cut-edge of coil-coated galvanized steel after corrosion testing[J]. Corrosion Science,1999,41:141-154.
【31】JORCIN J B,ARAGON E,MERLATTI C,et al. Delaminated areas beneath organic coating: A local electrochemical impedance approach[J]. Corrosion Science,2006,48:1779-1790.
【32】ZIN I,HOWARD R,BADGER S,et al. The mode of action of chromate inhibitor in epoxy primer on galvanized steel[J]. Progress in Organic Coatings,1998,33:203-210.
【33】KARAVAI O,BASTOS A,ZHELUDKEVICH M,et al. Localized electrochemical study of corrosion inhibition in microdefects on coated AZ31 magnesium alloy[J]. Electrochimica Acta,2010,55:5401-5406.
【34】薛丽莉,许立坤,李庆芬,等. 水性环氧铝粉涂层/碳钢体系的腐蚀电化学行为[J]. 电化学,2007,13:171-176.
【35】DEVOOYS A,VANDER W H. Investigating cracks and crazes on coated steel with simultaneous SVET and EIS[J]. Progress in Organic Coatings,2011,71:250-255.
【36】SOUTO R M,GONZLEZ GARCIA Y,GONZle S. Evaluation of the corrosion performance of coil-coated steel sheet as studied by scanning electrochemical microscopy[J]. Corrosion Science,2008,50:1637-1643.
【37】SOUTO R M,GONZLEZ GARCIA Y,LZQUIERDO J,et al. Examination of organic coatings on metallic substrates by scanning electrochemical microscopy in feedback mode: Revealing the early stages of coating breakdown in corrosive environments[J]. Corrosion Science,2010,52:748-753.
【38】SOUTO R M,GONZLEZ GARCIA Y,GONZLEZ S,et al. Damage to paint coatings caused by electrolyte immersion as observed in situ by scanning electrochemical microscopy[J]. Corrosion Science,2004,46:2621-2628.
【39】BASTODS A C,SIMES A M,GONZLEZ S,et al. Application of the scanning electrochemical microscope to the examination of organic coatings on metallic substrates[J]. Progress in Organic Coatings,2005,53:177-182.
相关信息
