Stress Corrosion and Cathodic Protection of X80 Pipeline Steel Weldment in Acidic Seawater
摘 要
采用微观组织观察、失重、动电位扫描、四点弯曲试验、恒电位阴极极化等方法研究了TMCP X80管线钢焊接件在酸性海水中的应力腐蚀及阴极保护规律。结果表明, X80管线钢焊接件母材和热影响区的微观组织及电化学性能相似, 焊材的缺陷导致焊接件成为耐应力腐蚀的薄弱区; 四点弯曲条件会促进焊接件的腐蚀, 但在不含S2-等极易与铁结合的离子的酸性海水中, 焊接件的应力腐蚀并不严重; -900 mV(vs.SCE)更适用于抑制X80管线钢焊接件在该环境下的应力腐蚀。
Abstract
The stress corrosion cracking of TMCP X80 pipeline steel weldment and its inhibition by potentiostatic cathodic protection in acidic seawater were studied by microstructure observation, polarization curves, four-point bending test, potentiostatic cathodic polarization and weight loss method. The results show that the base metal and heat affected zone of X80 pipeline steel weldment have similar microstructure and electrochemical properties, the weldment is the weak area against stress corrosion cracking because of the defect of weld. Four-point bending conditions can promote the corrosion of weldment, but this kind of corrosion is not serious in such acidic seawater without the ions such as S2- etc which are easy to combine with iron; -900 mV (vs. SCE) is more suitable to inhibit the stress corrosion of X80 pipeline steel weldment in such a medium.
中图分类号 TG174
所属栏目 试验研究
基金项目
收稿日期 2013/6/4
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备注杜敏(1969-), 教授, 博士, 从事金属腐蚀与防护研究,
引用该论文: QIU Jing,LI Cheng-jie,DU Min. Stress Corrosion and Cathodic Protection of X80 Pipeline Steel Weldment in Acidic Seawater[J]. Corrosion & Protection, 2014, 35(4): 357
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参考文献
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【3】虞毅, 蔡文刚, 刘永贞, 等. TMCPX80管线钢焊接件耐氢渗透研究[J]. 中国海洋大学学报, 2011, 41(7/8):131-136.
【4】BERLOWITZ B J, HOROWITZ H H. The role of H2S in the corrosion and hydrogen embitterment of steel[J]. J Electrochem Soc, 1982, 129:468.
【5】孙兆栋, 杜敏, 张静, 等. 316L不锈钢在海水中的阴极极化行为研究[J]. 材料科学与工艺, 2011, 19(1):36-40.
【6】高伟, 杨帆. X65管线钢焊接件耐腐蚀性能研究[J]. 石油机械, 2009, 37(12):1-4.
【7】谢广宇, 唐荻, 武会宾, 等. X70级管线钢硫化物应力腐蚀开裂实验研究[J]. 物理测试, 2008, 26(1):26-29.
【8】NACE standard TM0177-2005NACE international standard test method laboratory testing of matals for resistance to solfide stress cracking and stress corrosion cracking in H2S environments: Methord B NACE standard bent-beam test[S].
【9】赵明纯, 单以银, 李玉海, 等. 显微组织对管线钢硫化物应力腐蚀开裂的影响[J]. 金属学报, 2001, 37(10):1087-1092.
【10】奚运涛, 刘道新, 张晓化. X80焊管H2S环境应力腐蚀开裂行为研究[J]. 石油机械, 2006, 34(8):7-10.
【11】郑传波, 黄彦良, 霍春勇, 等. APIX56钢在含H2S的海洋大气中的应力腐蚀开裂[J]. 中国腐蚀与防护学报, 2009, 29(1):19-23.
【12】OKSTAD T, RANNESTAD O, JOHNSEN R, et al. Significance of hydrogen evolution during cathodic protection of carbon steel in seawater[J]. Corrosion, 2007, 93(9):857-865.
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