Electrochemical Behavior of Corrosion of X70 Steel under Thin Layer of Electrolytes Containing Hydrogen Sulfide
摘 要
采用极化曲线和电化学阻抗法研究了H2S浓度、酸度以及液膜厚度对X70钢在含H2S薄层液膜下腐蚀行为的影响。结果表明,薄层液膜下,H2S促进了X70钢腐蚀的阴阳极过程; 随着H2S浓度升高,自腐蚀电位(Ecorr)正移,自腐蚀电流密度(Jcorr)增大,腐蚀速率增加; pH减小,Ecorr负移,Jcorr增大;当pH<3.02时,低频端一维扩散特征的Warburg阻抗由一感抗弧所代替; 液膜厚度减薄,电荷传递电阻减小,X70钢腐蚀速率加快。
Abstract
Corrosion behavior of X70 steel under thin layer of electrolytes containing hydrogen sulfide was studied by means of polarization curves and electrochemical impedance spectroscopy. The influence of hydrogen sulfide concentration, pH value and layer thickness were examined. The results showed that under thin electrolyte layers the cathodic and anodic processes both were promoted by hydrogen sulfide. With the increase of the hydrogen sulfide concentration, the corrosion potential (Ecorr), corrosion current (Jcorr) and corrosion rate of the steel increased. With the decrease of pH, Ecorr decreased, Jcorr increased to some extent. When the pH value was less than 3.02, a low-frequency inductance loop emerged and the Warburg impedance disappeared. The charge transfer resistance decreased and the corrosion rate increased with layer thickness decreasing.
中图分类号 TG174
所属栏目 试验研究
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收稿日期 2013/8/1
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备注邓祖宇(1982-),讲师,硕士,从事电化学及幼儿科学教育研究,
引用该论文: DENG Zu-yu. Electrochemical Behavior of Corrosion of X70 Steel under Thin Layer of Electrolytes Containing Hydrogen Sulfide[J]. Corrosion & Protection, 2014, 35(6): 557
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【4】TRAN T T M,FIAUD C,SUTTER E M M,et al. The atmospheric corrosion of copper by hydrogen sulfide in underground conditions[J]. Corrosion Science,2003,45:2787-2802.
【5】QI Y M,LUO H Y,ZHENG S Q,et al. Effect of immersion time on the hydrogen content and tensile properties of A350LF2 steel exposed to hydrogen sulphide environments[J]. Corrosion Science,2013,69:164-174.
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【9】何晓英,邓祖宇,邓海英. (NH4)2SO4薄层液膜下X70钢腐蚀的电化学研究[J]. 腐蚀科学与防护技术,2008,20(3): 213-215.
【10】李明,李晓刚,陈华. 在湿H2S环境中金属腐蚀行为和机理研究概述[J]. 腐蚀科学与防护技术,2005,17(2): 107-111.
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【12】AHMED G El-Mahdy,NISHIKATA A,TSURU T. AC impedance study on corrosion of 55% Al-Zn alloy-coated steel under thin electrolyte layers[J]. Corrosion Science,2000,41:1509.
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