Corrosion Resistance of Stainless Steel Al-6XN in Simulated Flu Gas Condensate
摘 要
采用失重法和原子吸收光谱研究了Al-6XN不锈钢在模拟烟气冷凝液中的耐蚀情况,并运用动电位极化分析了在pH=2的溶液中,Cl-、SO42-浓度对其腐蚀行为的影响。结果表明,不锈钢Al-6XN在模拟环境中有较好的耐蚀性; 在酸性Cl-体系中,材料电极表面会发生点蚀,且随Cl-浓度的增大,腐蚀电流密度增大,点蚀电位不断地负移,而SO42-的加入对材料的点蚀有抑制作用。
Abstract
The anti-corrosion conditions of Al-6XN stainless steel was studied in simulated flu gas condensate using weight loss method and atomic absorption spectrum analysis. The effects of Cl-, SO42- concentration on its corrosion behavior were investigated in the pH=2 solution by means of potentiodynamic polarization. The results showed that Al-6XN stainless steel has good corrosion resistance in simulated flu gas condensate, the surface of material electrode suffared pitting corrosion in the acidic Cl- solutions .Moreover, the corrosion current density increased and pitting potential continuously shifted negatively with Cl- concentration increasing, but the addition of SO42- inhibited the pitting corrosion.
中图分类号 TG174.2
所属栏目 试验研究
基金项目 国家自然科学基金(61074018)
收稿日期 2013/8/17
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联系人作者李宇春(iamlyc@263.net)
备注李宇春(1972-),教授,博士,从事电厂化学、材料腐蚀与防护等方面研究,
引用该论文: KANG Juan,ZHOU Nian-guang,YU Miao,LI Mei,HE Yu-wu,LI Yu-chun. Corrosion Resistance of Stainless Steel Al-6XN in Simulated Flu Gas Condensate[J]. Corrosion & Protection, 2014, 35(6): 572
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参考文献
【1】李宝顺,赵丽丽,周驰. 湿法烟气脱硫装置的腐蚀与防护[J]. 化工机械,2009,36(6):640-643.
【2】王小平,孟照杰. 燃煤电厂湿法脱硫中的腐蚀环境和防腐技术[J]. 中国电力,2000(10):68-71.
【3】周至祥. 烟气脱硫常用金属耐腐蚀性能比较和选材[J]. 上海电力,2006(5):459-465.
【4】刘道新. 材料的腐蚀与防护[M]. 西安:西北工业大学出版社,2006:119-120.
【5】LEE W J,PYUN S I. The effect of prior Cl- ion incorporation into native oxide film on pure aluminum in neutral chloride solution on pit initiation[J]. Corrosion Science,2001,43(2):353-363.
【6】王梅丰,杜楠,李晓刚,等. 利用电子散斑干涉技术研究45碳钢在NaHCO3+NaCl体系中的早期点蚀行为[J]. 中国腐蚀与防护学报,2009,29(3):210-214.
【7】DU N,LIU G,ZHAO Q. Monitoring initial pitting behaviors of 30CrMnSi steel in NaHCO3+NaCl solution by ESPI and electrochemical noise[J]. Material Science,2008,2(3):326-329.
【2】王小平,孟照杰. 燃煤电厂湿法脱硫中的腐蚀环境和防腐技术[J]. 中国电力,2000(10):68-71.
【3】周至祥. 烟气脱硫常用金属耐腐蚀性能比较和选材[J]. 上海电力,2006(5):459-465.
【4】刘道新. 材料的腐蚀与防护[M]. 西安:西北工业大学出版社,2006:119-120.
【5】LEE W J,PYUN S I. The effect of prior Cl- ion incorporation into native oxide film on pure aluminum in neutral chloride solution on pit initiation[J]. Corrosion Science,2001,43(2):353-363.
【6】王梅丰,杜楠,李晓刚,等. 利用电子散斑干涉技术研究45碳钢在NaHCO3+NaCl体系中的早期点蚀行为[J]. 中国腐蚀与防护学报,2009,29(3):210-214.
【7】DU N,LIU G,ZHAO Q. Monitoring initial pitting behaviors of 30CrMnSi steel in NaHCO3+NaCl solution by ESPI and electrochemical noise[J]. Material Science,2008,2(3):326-329.
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