Corrosion Behavior of Organic Coating on Automobile Hub
摘 要
采用体式显微镜和铜加速乙酸盐雾试验、湿热试验、耐水性试验等方法研究了汽车铝轮毂材料表面高分子粉末涂层的耐蚀性能。结果表明, 轮毂样品经240 h铜加速乙酸盐雾试验(CASS试验)后划痕处边沿部分漆膜翘起且有脱落; 划痕边沿起泡数量增多, 最大单边腐蚀宽度约1.5 mm; 非划痕区域泡数量增多, 直径增大, 最大起泡直径约2 mm。铝轮毂试样和试片经过240 h湿热试验和耐水性试验后, 样品表面无起泡、剥落、起皱等现象, 漆膜附着力为0级, 硬度保持为3 H。温热试验后光泽保持率为98.6%, 色差为0.17; 耐水性试验后光泽保持率为87.9%, 色差为0.29。
Abstract
The corrosion behavior of aluminum hub with organic coating was investigated by metallographic microscopy, CASS test, wet-heat test and immersion water test. The results showed that the partial coating near the artificial defect for hub sample turned off and breaked off, the bubbles near the artificial defect became more and more, the widest corrosion distance was 1.5 mm. The bubbles in the area without the artificial defect also became more. The diameter for the bubble became bigger. The biggest diameter was 2.0 mm. The hub sample after 240 h wet-heat test showed no bubles and crinkles in the surface. The coherence strength for the coating was 0 level, the rigidity was 3 H. The glossiness was 98.6%, the chromatic aberration was 0.17. The hub sample after 240 h immersion test showed no bubles and crinkles in the surface, the coherence strength for the coating was 0 level, the glossiness was 3 H, the glossiness was 87.9%, the chromatic aberration was 0.29.
中图分类号 TG172.3
所属栏目 试验研究
基金项目 国家自然科学基金(50971048); 科技部火炬计划(2011GH031716)
收稿日期 2013/8/10
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备注周和荣(1972-),博士,高级工程师, 从事金属材料的腐蚀和防护以及粉末涂料技术研究,
引用该论文: ZHOU He-rong,JIE Gan-xin,ZHAO Yue. Corrosion Behavior of Organic Coating on Automobile Hub[J]. Corrosion & Protection, 2014, 35(7): 642
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参考文献
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【2】GRUNDMEIER G,SCHMIDT W,STRATMANN M. Corrosion protection by organic coatings:electrochemical mechanism and novel methods of investigation[J]. Electrochimica Acta,2000,45(15/16):2515-2533.
【3】胡吉明,张鉴清,谢德明. 水在有机涂层中的传输Ⅰ:Fick扩散过程[J]. 中国腐蚀与防护学报,2002,22(5):311-316.
【4】张金涛,胡吉明,张鉴清. 有机涂层的现代研究方法[J]. 材料科学与工程学报, 2003,21(5): 763-768.
【5】BASTIDAS J M,MORCILLO M,RODRIGUEZ F J. Mild steel corrosion in saline solutions:comparison between bulk solutions and steel-coating interfacial solutions[J]. Journal of Coatings Technology,1998,70(882):61-66.
【6】MORCILLO M,RODRIGUEZ F J,BASTIDAS J M. The influence of chlorides,sulphates and nitratesat the coating-steel interface on under film corrosion[J]. Progress in Organic Coatings,1997,31(3):245-353.
【7】DOHERTY M,SYKES J M. Micro-cells beneath organic lacquers:a study using scanning Kelvin probe and scanning acoustic microscopy[J]. Corrosion Science,2004,46(5):1265-1289.
【8】COLREAVY J,SCANTLEBURY J D. Electrochemical impedance spectroscopy to monitor the influence of surface preparation on the corrosion characteristics of mild steel MAG welds[J]. Journal of Materials Processing Technology,1995,55(3/4):206-212.
【9】MIKOVI-STANKOVI V B,DRAI D M,KAAREVI-POPOVI Z. The sorption characteristics of epoxy coatings electrodeposited on steel during exposure to different corrosive agents[J]. Corrosion Science,1996,38(9):1513-1523.
【10】FEDRIZZI L,RODRIGUEZ F J,ROSSI S,et al. The use of electrochemical techniques to study the corrosion behavior of organic coatings on steel pretreated with sol-gel zirconia films[J]. Electrochimica Acta,2001,46:3715-3724.
【11】OLIVEIRA C G,FERREIRA M G S. Ranking high-quality paint systems using EIS Part I:intact coatings[J]. Corrosion Science,2003,45(1):123-138.
【12】何杰, 阎瑞, 马世宁. 电化学方法研究环氧涂层/基体在3.5% NaCI溶液中的腐蚀行为[J]. 中国表面工程, 2006,19(2):47-50.
【13】REYNOLDS L B,TWITE R,KHOBAIB M,et al. Aircraft coatings by electrochemical M.Preliminary evaluation of the anticorrosive erties of methods[J]. Progress in Organic Coatings,1997,32(1):31-34.
【14】MORCILLO M. Soluble salts: their effects on premature degradation of anticorrosive paints[J]. Progress in Organic Coatings,1999,36(3):137-147.
【15】LENG A,STRECKELA H,STRATMANN M. The delamination of polymeric coatings from steel.Part Ⅲ effect of the oxygen partial pressure on the delamination reaction and current distribution at the metal: polymer interface[J]. Corrosion Science,1999,41(3):599-620.
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