Preparation and Mixture Corrosion Inhibition of Doped Polianiline for Mild Steel
摘 要
采用化学氧化法合成了聚丙烯酸掺杂态聚苯胺(PANI); 采用傅立叶红外法(FTIR)对合成产物进行了表征; 采用电化学阻抗谱和动电位极化方法研究了PANI单独作用和复配时对Q235钢在0.5 mol ·L-1 HCl溶液中的缓蚀性能。结果表明, PANI单独作用时, 当用量为20 mg·L-1时缓蚀效率最高为73.6%; 将聚苯胺与聚丙烯酰胺、三乙醇胺、脲按质量比1∶2∶1∶1进行复配, 缓蚀效率大大提高, 复配缓蚀剂PANI浓度为80 mg·L-1时缓蚀效率达到92.7% 。复合缓蚀剂在Q235钢表面的吸附服从修正后的朗缪尔吸附等温式。
Abstract
Polyaniline acid (PAAC) was chosen as doping acid to prepare polyaniline( PANI) by direct chemical oxidation. The results of FTIR absorption spectra were used to characterize the product. And the inhibition effects of single and compound PANI on corrosion of Q235 steel in 0.5 mol·L-1 HCl solution were investigated by polarization curvers and electrochemical impedance spectroscopy (EIS). The results showed that the corrosion inhibition performance of PANI alone was just average. When the concentration of PANI was 20 mg·L-1, the best inhibition efficiency was only 73.6%. Corrosion inhibition performance was better when polyaniline was compounded with polyacrylamide, triethanolamine and urea, with a mass ratio of 1∶2∶1∶1 . When the concentration of polypaniline was 80 mg·L-1, the inhibition efficiency reached 92.7%. Adsorption of polyaniline on Q235 steel obbeys the modified Langmuir adsorption isotherm.
中图分类号 TG174
所属栏目 试验研究
基金项目
收稿日期 2013/9/3
修改稿日期
网络出版日期
作者单位点击查看
联系人作者郭英(gy310@163.com)
备注郭英(1958-),教授,硕士,从事金属材料的腐蚀与防护研究,
引用该论文: GUO Ying,HOU Yuan-chun,FAN Bing-bing. Preparation and Mixture Corrosion Inhibition of Doped Polianiline for Mild Steel[J]. Corrosion & Protection, 2014, 35(7): 729
共有人对该论文发表了看法,其中:
人认为该论文很差
人认为该论文较差
人认为该论文一般
人认为该论文较好
人认为该论文很好
参考文献
【1】林卫丽,杜美利,邓宇强,等. 水溶性聚苯胺在5%盐酸中对碳钢缓蚀效果的研究[J]. 材料保护,2006,5(39):7-9.
【2】邓俊英,李伟华,吴茂涛,等. 羧甲基壳聚糖掺杂聚苯胺的制备及其在盐酸溶液中对碳钢的缓蚀性能研究[J]. 高分子学报,2010(5):588-592.
【3】MACDIARMID A G,MU S L,SOMASIRI N L D,et al. Electrochemical characteristics of “polyaniline” cathodes anodes in a aqueous electrolytes[J]. Molecular Crystals And Liquid Crystals,1985,121(5):187-190.
【4】曹楚南,张鉴清. 电化学阻抗谱导论[M]. 北京:科学出版社,2002,170-177.
【5】郭英,宋诗哲. 盐酸介质中Tw-20与聚丙烯酸对铁腐蚀的协同缓蚀作用[J]. 化工学报,2001,52(3):261-265.
【6】王佳,曹楚南. 缓蚀剂阳极脱附现象的研究. 缓蚀剂阳极脱附机制Ⅳ[J]. 中国腐蚀与防护学报,1996,16(1):9-14.
【7】王佳,曹楚南. 缓蚀剂阳极脱附现象的研究. 缓蚀剂阳极脱附机制Ⅱ[J]. 中国腐蚀与防护学报,1996,16(1):15-19.
【2】邓俊英,李伟华,吴茂涛,等. 羧甲基壳聚糖掺杂聚苯胺的制备及其在盐酸溶液中对碳钢的缓蚀性能研究[J]. 高分子学报,2010(5):588-592.
【3】MACDIARMID A G,MU S L,SOMASIRI N L D,et al. Electrochemical characteristics of “polyaniline” cathodes anodes in a aqueous electrolytes[J]. Molecular Crystals And Liquid Crystals,1985,121(5):187-190.
【4】曹楚南,张鉴清. 电化学阻抗谱导论[M]. 北京:科学出版社,2002,170-177.
【5】郭英,宋诗哲. 盐酸介质中Tw-20与聚丙烯酸对铁腐蚀的协同缓蚀作用[J]. 化工学报,2001,52(3):261-265.
【6】王佳,曹楚南. 缓蚀剂阳极脱附现象的研究. 缓蚀剂阳极脱附机制Ⅳ[J]. 中国腐蚀与防护学报,1996,16(1):9-14.
【7】王佳,曹楚南. 缓蚀剂阳极脱附现象的研究. 缓蚀剂阳极脱附机制Ⅱ[J]. 中国腐蚀与防护学报,1996,16(1):15-19.
相关信息