H2S/CO2油气田地面工程的腐蚀监测技术
Techniques of Corrosion Monitoring for Surface Engineering in Oil and Natural Gas Field with H2S/CO2
摘 要
油气田地面管网和设备装置中接触的流体介质范围广泛, 流体介质通常含有H2O、H2S、CO2、高Cl-等腐蚀性介质组份, 形成不同的腐蚀体系。大部分油气田地面管道设备选择碳钢材质, 碳钢材质在这些腐蚀条件下存在腐蚀风险, 在运行期间需要对碳钢的腐蚀情况进行监测和检测, 以便即时调整运行期间的腐蚀控制方案, 确保管道设备的完整性。腐蚀监测技术种类繁多, 不同的腐蚀监测技术其原理各异, 各具优缺点。介绍了常见的腐蚀监测技术的作用原理、优点以及使用的局限性, 以期为工程设计和管理人员在进行腐蚀监测设计和腐蚀综合管理过程中提供参考。
腐蚀监测
H2S
CO2
腐蚀管理
corrosion risk
corrosion monitoring
H2S
CO2
corrosion management
Abstract
The pipe and production facility for oil and nature gas suffer from the wide range of fluids, which may contain usually carbon dioxide (CO2), hydrogen sulphide (H2S) and water (H2O) with high concentration chloride. The majority of pipes and facilities are made from carbon steel, which has the corrosion risk depending on the composition of the fluid. Corrosion rate should be monitored and inspected to ensure the integrality of pipes and facilities, and to adjust the corrosion control measure immediately. There are a lot of corrosion monitor techniques with various advantages and limitation depending on their principle. This paper provides a review of monitoring methods available to oil and nature gas field with H2S/CO2, and their principles, benefit and limitation are introduced in order to provide some reference for designers and managers when they select monitoring methods and carry out corrosion management.
中图分类号 TG174.4
所属栏目 专论
基金项目 国家科技重大专项(2011ZX-05059-004); 中石油科技项目(2011GJTC-09-01)
收稿日期 2013/9/28
修改稿日期
网络出版日期
作者单位点击查看
联系人作者裴承河(53672398@qq.com)
备注裴承河(1967-),高级工程师,博士,从事油气田开发研究,
引用该论文: PEI Cheng-he,XIAN Ning,TONG Fu-liang,CHEN Bin-yuan,RONG Ming. Techniques of Corrosion Monitoring for Surface Engineering in Oil and Natural Gas Field with H2S/CO2[J]. Corrosion & Protection, 2014, 35(7): 761
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【2】GB/T 23258-2009钢质管道内腐蚀控制规范[S].
【3】SY/T 0611-2008高含硫化氢气田集输管道系统内腐蚀控制要求[S].
【4】胡永碧, 谷坛. 高含硫气田腐蚀特征及腐蚀控制技术[J]. 天然气工业, 2012, 32(12):92-96.
【5】杨发平, 王贵波. 普光气田地面集输系统腐蚀监测及控制体系[J]. 天然气工业, 2012, 32(1).
【6】谢伟, 郑然, 别记平,等. 含CO2天然气集输系统腐蚀监测技术[J]. 腐蚀与防护, 2012, 33(1): 82-84.
【7】BILL HEDGES,KIP SPRAGUE,HUEY J. A review of monitoring and inspection techniques for CO2 & H2S corrosion in oil & gas production facilities:Location Location Location[C]//Houston:NACE International Annual Conference,2006,Paper No.06120.
【8】杨列太. 腐蚀监测技术[M]. 北京: 化学工业出版社, 2012.
【9】YANG L,SRIDHAR N,BROSSIA C S. Evaluation of the coupled multielectrode array sensor a real time corrosion monitor[J]. Corrosion Sceience,2005,47:1794-1809.
【10】LIETAI Y,KUANG-TSAN K C,PAVAN K. Shukla. Internal current effects on localized corrosion rate measurements using coupled multielectrode array sensors[C]//Houston:NACE International Annual Conference,2009:Paper No.09446.
【11】ROE D STROMMEN. Seven years experience from subsea,deepwater pipeline internal corrosion monitoring[C]//Houston:NACE International Annual Conference,2002:Paper No.02251.
【12】ALLEYNE D N,PAVLAKOVIC B,LOWE M J S. Rapid long-range inspection of chemical plant pipework using guided waves[C]//Rome:15th World Conference on NDT,2000.
【13】BOUAZAZE H,HUET F,NOGUEIRA R P. Monitoring corrosion and flow characteristics in oil/brine mixtures of various compositions[C]//NACE International Annual Conference.Houston:2004:Paper No.04466.
【14】MARTINEZ R G,FLORES J M,LlONGUERAS J G,et al. Electrochemical noise study on the corrosion of X52 pipeline steel in aqueous solution containing H2S[C]//Houston:NACE International Annual Conference,2004:Paper No.04432.
【15】LOZEV M G,SMITH R W,GRIMMENT B B. Evaluation of methods for detecting and monitoring of corrosion damage in risers[J]. Journal of Pressure Vessel Technology,2005,127(3):244-251.
【16】SUN X,YANG L. Real-time monitoring of localized and general corrosion rates in drinking water utilizing coupled multielectrode array sensors[C]//Houston:NACE International Annual Conference,2006:Paper No.06094.
【17】SRIDHAR N,YANG L,SONG F. Application of multielectrode array to study dewpoint corrosion in high pressure natural gas pipeline environments[C]//Houston:NACE International Annual Conference,2006:Paper No. 06094.
【18】TARJEI R,ROY J B. Using ultrasound measurements for real-time process control of pipelines and process equipment subjected to corrosion and/or Erosion[C]//Houston:NACE International Annual Conference,2008:Paper 08285.
【19】TURNBULL A,HINDS G,COOLING P, et al. A multi-electrode approach to evaluating inhibition of underdeposit corrosion in CO2 environments[C]//Houston:NACE International Annual Conference,2009:Paper No.09945.
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【21】张居生, 杜月侠, 兰云峰,等. 腐蚀监测技术及其适用性选择[J]. 腐蚀与防护, 2012, 33(1): 75-78.
【22】TARJEI ROMMETVEIT,ROY JOHNSEN,TONNI F JOHANSEN. High resolution ultrasound wall thickness measurements through polyester coating and real-time process control[C]//Houston:NACE International Annual Conference,2009:Paper No.09452.
【23】MISHAEL S J,DEAN F W H,FOWLER C. Practical applications of hydrogen permeation monitoringl[C]//Houston:NACE International Annual Conference,2004:Paper No.04476.
【24】吕瑞典, 薛有祥. 油气田腐蚀监测技术综述[J]. 石油化工腐蚀与防护, 2009, 26(1): 4-6.
【25】YANG J W,ZHANG L,LU M X,et al. Influence of H2S and CO2 Corrosion Scales on Hydrogen Permeation in X65 Steel[C]//Houston:NACE International Annual Conference,2008:Paper No.088412.
【26】JEAN KITTEL,FRANCOIS ROPITAL,JULIE PELLIER. New insights into hydrogen permeation in steels:measurements through thick membranes[C]//Houston:NACE International Annual Conference,2008:Paper No.088409.
【27】曹建树, 李杨, 林立,等. 天然气管道在线无损检测技术[J]. 无损检测, 2013, 35(5): 20-25.
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