固相萃取-高效液相色谱法测定偶氮染料橙黄G的降解产物1-胺基-2-萘酚-6,8-二磺酸
HPLC Determination of 1-Amino-2-naphthol-6,8-disulfonate in Degradation Product of Azo Dye Orange G with Solid-Phase Extraction
摘 要
提出了固相萃取-高效液相色谱法测定偶氮染料橙黄G的Fenton反应降解溶液中1-胺基-2-萘酚-6,8-二磺酸。用OnGuard Ⅱ H固相萃取小柱去除降解液中的Fe2+,C18柱为分离柱,以乙腈-10 mmol·L-1乙酸铵(20+80)溶液为流动相洗脱,检测波长为254 nm。1-胺基-2-萘酚-6,8-二磺酸的线性范围为0.05~5.0 mg·L-1,检出限(3S/N)为0.15 mg·L-1。加标回收率在92.1%~99.2%之间,日内及日间相对标准偏差分别在2.8%~3.4%,4.1%~7.7%之间。
偶氮染料
橙黄G
1-胺基-2-萘酚-6,8-二磺酸
固相萃取
HPLC
Azo dye
Orange G
1-Amino-2-naphthol-6,8-disulfonate
Solid-phase extraction
Abstract
SPE-HPLC was applied to the determination of 1-amino-2-naphthol-6,8-disulfonate in the Fenton′s degradation solution from azo dye orange G. Fe2+ were removed from the Fenton′s degradation solution by OnGuard Ⅱ H cartridges, C18 column was used as stationary phase and a mixture of acetonitrile and 10 mmol·L-1 NH4Ac (20+80) was used as mobile phase. UV-detection was made at the wavelength of 254 nm. Linearity range of 1-amino-2-naphthol-6,8-disulfonate was between 0.05-5.0 mg·L-1 with detection limit (3S/N) of 0.15 mg·L-1. Values of recovery found by standard addition method were in the range of 92.1%-99.2%, with RSD′s in the range of 2.8%-3.4% (intra-day), 4.1%-7.7% (inter-day).
中图分类号 O652.63
所属栏目 试验与研究
基金项目 浙江省自然科学基金项目(LY13B050003);浙江省分析测试项目(2013C37089);浙江省医药卫生科研项目(2013KYA187);宁波市自然科学基金项目(2013A610243)
收稿日期 2014/3/23
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联系人作者周丽新(jmcjc@163.com)
备注周丽新(1988-),女,内蒙古赤峰人,硕士研究生,主要从事理化检测研究工作。
引用该论文: ZHOU Li-xin,WEI Xiao-qin,CAI Mei-qiang,ZOU Bao-bo,CHEN Xiao-hong,JIN Mi-cong. HPLC Determination of 1-Amino-2-naphthol-6,8-disulfonate in Degradation Product of Azo Dye Orange G with Solid-Phase Extraction[J]. Physical Testing and Chemical Analysis part B:Chemical Analysis, 2014, 50(8): 929～932
周丽新,魏晓琴,蔡美强,邹宝波,陈晓红,金米聪. 固相萃取-高效液相色谱法测定偶氮染料橙黄G的降解产物1-胺基-2-萘酚-6,8-二磺酸[J]. 理化检验－化学分册, 2014, 50(8): 929～932
被引情况:
【1】宋志军,蔡美强, "离子液体-K2HPO4超声双水相萃取预富集-高效液相色谱法测定水产品中组胺含量",理化检验－化学分册 51, 1639-1643(2015)
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参考文献
【1】MADHAVAN J, GRIESER F, ASHOKKUMAR M. Degradation of orange-G by advanced oxidation processes［J］. Ultrason Sonochem, 2010,17(1):338-343.
【2】SUN Sheng-peng, LI Cheng-jie, SUN Jian-hui, et al. Decolorization of an azo dye Orange G in aqueous solution by Fenton oxidation process: effect of system parameters and kinetic study［J］. J Hazard Mater, 2009,161(2/3):1052-1057.
【3】CAI Mei-qiang, JIN Mi-cong, WEAVERS L K. Analysis of sonolytic degradation products of azo dye Orange G using liquid chromatography-diode array detection-mass spectrometry［J］. Ultrason Sonochem, 2011,18(5):1068-1076.
【4】SUN Jan-hui, QIAO Li-ping, SUN Sheng-peng, et al. Photocatalytic degradation of Orange G on nitrogen-doped TiO2 catalysts under visible light and sunlight irradiation［J］. J Hazard Mater, 2008,155(1):312-319.
【5】XU Xiang-rong, LI Xiang-zhong. Degradation of azo dye Orange G in aqueous solutions by persulfate with ferrous ion［J］. Sep Purif Technol, 2010,72(1):105-111.
【6】江强明,吴宏海,窦晓文.均相Fenton反应对偶氮染料橙黄G氧化脱色实验研究［J］.华南师范大学学报:自然科学版, 2012,44(1):94-98.
【7】任松洁,丛纬,张国亮,等.印染工业废水处理与回用技术的研究［J］.水处理技术, 2009,35(8):14-18.
【8】刘肖,王碗,史亚利,等.不同类型电镀液中阴离子的离子色谱法检测［J］.环境化学, 2007,6(4):541-543.
【9】李仁勇,史亚利,梁立娜,等.离子色谱法同时测定电镀液中的S2O32-、SCN-和有机酸［J］.分析试验室, 2009,28(2):42-45.
【10】赵永纲,陈晓红,李小平,等.离子抑制剂对苯甲酸等9种食品添加剂的反相液相色谱行为的影响［J］.色谱, 2011,29(10):988-994.
【11】ZHAO Yong-gang, CAI Mei-qiang, CHEN Xiao-hong, et al. Analysis of nine food additives in wine by dispersive solid-phase extraction and reversed-phase high performance liquid chromatography［J］. Food Res Int, 2013,52(1):350-358.
【2】SUN Sheng-peng, LI Cheng-jie, SUN Jian-hui, et al. Decolorization of an azo dye Orange G in aqueous solution by Fenton oxidation process: effect of system parameters and kinetic study［J］. J Hazard Mater, 2009,161(2/3):1052-1057.
【3】CAI Mei-qiang, JIN Mi-cong, WEAVERS L K. Analysis of sonolytic degradation products of azo dye Orange G using liquid chromatography-diode array detection-mass spectrometry［J］. Ultrason Sonochem, 2011,18(5):1068-1076.
【4】SUN Jan-hui, QIAO Li-ping, SUN Sheng-peng, et al. Photocatalytic degradation of Orange G on nitrogen-doped TiO2 catalysts under visible light and sunlight irradiation［J］. J Hazard Mater, 2008,155(1):312-319.
【5】XU Xiang-rong, LI Xiang-zhong. Degradation of azo dye Orange G in aqueous solutions by persulfate with ferrous ion［J］. Sep Purif Technol, 2010,72(1):105-111.
【6】江强明,吴宏海,窦晓文.均相Fenton反应对偶氮染料橙黄G氧化脱色实验研究［J］.华南师范大学学报:自然科学版, 2012,44(1):94-98.
【7】任松洁,丛纬,张国亮,等.印染工业废水处理与回用技术的研究［J］.水处理技术, 2009,35(8):14-18.
【8】刘肖,王碗,史亚利,等.不同类型电镀液中阴离子的离子色谱法检测［J］.环境化学, 2007,6(4):541-543.
【9】李仁勇,史亚利,梁立娜,等.离子色谱法同时测定电镀液中的S2O32-、SCN-和有机酸［J］.分析试验室, 2009,28(2):42-45.
【10】赵永纲,陈晓红,李小平,等.离子抑制剂对苯甲酸等9种食品添加剂的反相液相色谱行为的影响［J］.色谱, 2011,29(10):988-994.
【11】ZHAO Yong-gang, CAI Mei-qiang, CHEN Xiao-hong, et al. Analysis of nine food additives in wine by dispersive solid-phase extraction and reversed-phase high performance liquid chromatography［J］. Food Res Int, 2013,52(1):350-358.
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