Alternative Method for Determination of Over-All Migration from Plastic Wares Intended to Come into Contact with Food
摘 要
针对欧盟法规(EU) 10/2011规定,测定食品接触材料(塑料器皿)的总迁移量时,需将塑料制品置于模拟液中于40 ℃浸泡10 d,检测周期过长的问题,试验了在几种不同的模拟液中改变浸泡温度及时间,以期达到缩短检测周期的目的。最终选择了以下几种浸泡条件:① 以乙醇-水(10+90)混合液作为模拟液,于100 ℃浸泡88 h;② 乙酸-水(3+97)溶液为模拟液,于100 ℃浸泡6 h;③ 乙醇-水(95+5)混合液为模拟液,在60 ℃浸泡40 h;④ 异辛烷为模拟液,于60 ℃浸泡5 h。浸泡结束后,将模拟液移入已称至恒重的蒸发皿(m1)中,蒸发至干,移入105 ℃烘箱中放置过夜并称至恒重(m2),根据m2与m1的差值(残渣量)除以浸泡体积即得总迁移量。采用上述改进的浸泡条件,不仅缩短了检测时间,而且能满足相关法规的要求。
Abstract
As stipulated in the regulation of (EU) 10/2011, for determination of over-all migration from plastic wares intended to come into contact with food, the sample should be immersed in simulated liquor at 40 ℃ for 10 days. Aiming to shorten the testing time, conditions of immersion of different kinds of plastics in various simulated liquor under different temperatures with a shorter time were tested, and the following procedures were proposed: ① immerse in mixture of C2H5OH-H2O (10+90) at 100 ℃ for 88 h;② immerse in CH3COOH-H2O (3+97) at 100 ℃ for 6 h;③ immerse in C2H5OH-H2O (95+5) at 60 ℃ for 40 h;④ immerse in iso-octane at 60 ℃ for 5 h. At the end of immersion, the simulated liquor was removed to an evaporating dish (weighed to constant mass of m1 previously), and evaporated to dryness. The dish together with the residue was placed in an oven (at 105 ℃) overnight and its mass was weighed to constant (m2). Value of all-over migration was calculated by m2-m1/volume of simulated liquor. By using either of the 4 modified immersion conditions, not only the testing time was shortened, and the results were also found to meet with the requirements of the relative regulations.
中图分类号 O65
所属栏目 工作简报
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收稿日期 2013/11/29
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备注刘艇飞(1983-),男,浙江东阳人,工程师,主要从事分析检验工作。
引用该论文: LIU Ting-fei,WANG Jian-ling,LIN Li,CHEN Tong,GE Ya-hong,HU Yan,YE Wen-xiu. Alternative Method for Determination of Over-All Migration from Plastic Wares Intended to Come into Contact with Food[J]. Physical Testing and Chemical Analysis part B:Chemical Analysis, 2014, 50(11): 1397~1400
刘艇飞,王建玲,林丽,陈彤,葛亚红,胡燕,叶文秀. 食品接触(塑料器皿)总迁移量测试的替代试验方法[J]. 理化检验-化学分册, 2014, 50(11): 1397~1400
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参考文献
【1】王洪涛,张玉霞,彭彦泽,等,中欧塑料食品包装总迁移量检测方法比较[J].食品安全质量检测学报, 2012,3(5):548-552.
【2】(EU)10/2011On plastic materials and articles intended to come into contact with food (text with EEA relevance)[S].
【3】82/711/EECOfficail journal of the european communities[S].
【4】BRADLEY E L. Use of overall migration methodology to test for food-contact substances with specific migration limits[J]. Food Additives and Contaminants, 2009,26(4):574-582.
【5】BS EN 1186-3:2002Materials and articles in contact with foodstuffs-plastics-part 3: test methods for overall migration into aqueous food simulants by total immersion[S].
【6】BS EN1186-1:2002Materials and articles in contact with foodstuffs-plastics-part 1: guide to the selection of conditions and test methods for overall migration[S].
【7】BS EN 1186-14Materials and articles in contact with foodstuffs-plastics-part 14: test methods for ‘substitute tests’ for overall migration from plastics intended to come into contact with fatty foodstuffs using test media iso-octane and 95% ethanol[S].
【2】(EU)10/2011On plastic materials and articles intended to come into contact with food (text with EEA relevance)[S].
【3】82/711/EECOfficail journal of the european communities[S].
【4】BRADLEY E L. Use of overall migration methodology to test for food-contact substances with specific migration limits[J]. Food Additives and Contaminants, 2009,26(4):574-582.
【5】BS EN 1186-3:2002Materials and articles in contact with foodstuffs-plastics-part 3: test methods for overall migration into aqueous food simulants by total immersion[S].
【6】BS EN1186-1:2002Materials and articles in contact with foodstuffs-plastics-part 1: guide to the selection of conditions and test methods for overall migration[S].
【7】BS EN 1186-14Materials and articles in contact with foodstuffs-plastics-part 14: test methods for ‘substitute tests’ for overall migration from plastics intended to come into contact with fatty foodstuffs using test media iso-octane and 95% ethanol[S].
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