电化学噪声数据处理方法概述
A Review on Electrochemical Noise Analysis
摘 要
综述了常见的电化学噪声数据处理方法,介绍了直流趋势剔除、统计分析、快速傅立叶变换(FFT)法计算功率谱密度(PSD)以及小波变换处理电化学噪声信号的基本过程,并阐释了各种数学处理及所得参数的物理意义。
多项式拟合
统计分析
快速傅立叶变换
功率谱密度
小波变换
electrochemical noise analysis
polynomial fitting
statistical analysis
fast Fourier transform
power spectral density
wavelet transform
Abstract
The most commonly used analysis methods for electrochemical noise are reviewed. The general processes of electrochemical noise analyses,including DC trend removal,statistical analysis,power spectral density (PSD) calculation by fast Fourier transform (FFT) and wavelet transform are introduced. The parameters obtained by these mathematical treatments above are interpreted for their physical meanings.
中图分类号 TG174.3 O646
所属栏目 专论
基金项目
收稿日期 2014/4/3
修改稿日期
网络出版日期
作者单位点击查看
备注韩磊(1980-),高级工程师,博士,从事石化装置腐蚀与防护研究,0532-83786538.
引用该论文: HAN Lei. A Review on Electrochemical Noise Analysis[J]. Corrosion & Protection, 2015, 36(1): 84
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参考文献
【1】HLADKY K,DAWSON J L. The measurement of localized corrosion using electrochemical noise[J].Corrosion Science,1981,21(4):317-322.
【2】HLADKY K,DAWSON J L. The measurement of corrosion using electrochemical 1/f noise[J].Corrosion Science,1982,22(3):231-237.
【3】HLADKY K. Corrosion Monitoring[P].US Patent 4575678,1986-3-11.
【4】BERTOCCI U,HUET F,NOGUEIRA R,et al. Drift removal procedures for PSD calculation[C]//Corrosion 2001:Houston,[s.l.],2001.
【5】BERTOCCI U,HUET F,NOGUEIRA R. Drift removal procedures in the analysis of electrochemical noise[J].Corrosion,2002,58(4):337-347.
【6】MANSFELD F,SUN Z,HSU C H,et al. Concerning trend removal in electrochemical noise measurements[J].Corrosion Science,2001,43(2):341-352.
【7】TAN Y J,BAILEY S,KINSELLA B. The monitoring of the formation and destruction of corrosion inhibitor films using electrochemical noise analysis (ENA)[J].Corrosion Science,1996,38(10):1681-1695.
【8】邱于兵,黄家怿,郭兴蓬. 多项式拟合法消除电化学噪声的直流漂移[J].华中科技大学学报:自然科学版,2005,33(10):39-42.
【9】黄家怿,邱于兵,郭兴蓬. 电化学噪声直流漂移的分段多项式拟合消除[J].中国腐蚀与防护学报,2009,29(1):9-14.
【10】张鉴清,张昭,王建明,等. 电化学噪声的分析与应用-I. 电化学噪声的分析原理[J].中国腐蚀与防护学报,2001,21(5):310-320.
【11】COTTIS R A. Interpretation of electrochemical noise data[J].Corrosion,2001,57(3):265-285.
【12】MANSFELD F. The electrochemical noise technique-applications in corrosion research[C]//18th International Conference on Noise and Fluctuations:Spain,[s.l.],2005:CP780.
【13】EDEN D A,HLADKY K,JOHN D G,et al. Electrochemical noise-simultaneous monitoring of potential and current noise signals from corroding electrodes[J].Corrosion 1986:Houston,[s.l.],1986:86274.
【14】MANSFELD F,XIAO H. Electrochemical noise analysis of iron exposed to NaCl solutions of different corrosivity[J].Journal of the Electrochemical Society,1993,140(8):2205-2209.
【15】GUSMANO G,MONTESPERELLI G,PACETTI S,et al. Electrochemical noise resistance as a tool for corrosion rate prediction[J].Corrosion,1997,53(11):860-868.
【16】CHEN J F,BOGAERTS W F. The physical meaning of noise resistance[J].Corrosion Science,1997,37(11):1839-1842.
【17】MANSFELD F,SUN Z. Localization index obtained from electrochemical noise analysis[J].Corrosion,1999,55(10):915-918.
【18】CHEN J F,BOGAERTS W F. Electrochemical emission spectroscopy for monitoring uniform and localized corrosion[J].Corrosion,1996,52(10):753-759.
【19】MANSFELD F,SUN Z,HSU C H. Electrochemical noise analysis (ENA) for active and passive systems in chloride media[J].Electrochimica Acta,2001,46(24):3651-3664.
【20】COTTIS R A,Al-AWADHI M A A,Al-MAZEEDI H,et al. Measures for the detection of localized corrosion with electrochemical noise[J].Electrochimica Acta,2001,46(24):3665-3674.
【21】ROBERGE P R. Analysis of electrochemical noise by the stochastic process detector method[J].Corrosion,1994,50(7):502-512.
【22】GABRIELLI C,HUET F,KEDDAM M,et al. A review of the probabilistic aspects of localized corrosion[J].Corrosion,1990,46(4):266-279.
【23】CHENG Y F,LUO J L. Metastable pitting of carbon steel under potentiostatic control[J].Journal of the Electrochemical Society,1999,146(3):970-976.
【24】COTTIS R A. Sources of electrochemical noise in corroding systems[J].Russian Journal of Electrochemistry,2006,42(5):497-505.
【25】张昭,张鉴清,李劲风,等. 因次分析法在电化学噪声分析中的应用[J].物理化学学报,2001,17(7):651-654.
【26】曹楚南,常晓元,林海潮. 孔蚀过程中的电化学噪声特征[J].中国腐蚀与防护学报,1989,9(1):21-28.
【27】LEGAT A,DOLECEK V. Corrosion monitoring system based on measurement and analysis of electrochemical noise[J].Corrosion,1995,51(4):295-300.
【28】LEGAT A,ZEVNIK C. The electrochemical noise of mild and stainless steel in various water solutions[J].Corrosion Science,1993,35(5/8):1661-1666.
【29】EDEN D A. Electrochemical noise-the first two octaves[C]//Corrosion 98:Houston,[s.l.],1998:98386.
【30】URUCHRUTU J C,DAWSON J L. Noise analysis of pure aluminum under different pitting conditions[J].Corrosion,1987,43(1):19-25.
【31】FLIS J,DAWSON J L,GILL J,et al. Impedance and electrochemical noise measurements on iron and iron-carbon alloys in hot caustic soda[J].Corrosion Science,1991,32(8):877-892.
【32】张鉴清,张昭,王建明,等. 电化学噪声的分析与应用-II. 电化学噪声的应用[J].中国腐蚀与防护学报,2002,22(4):241-248.
【33】BERTOCCI U,FRYDMAN J,GABRIRELLI C,et al. Analysis of electrochemical noise by power spectral density applied to corrosion studies[J].Journal of the Electrochemical Society,1998,145(8):2780-2786.
【34】BERTOCCI U,HUET F,JAOUL B,et al. Frequency analysis of transients in electrochemical noise:Mathematical relationships and computer simulations[J].Corrosion,2000,56(7):675-683.
【35】CHENG Y F,LUO J L,WILMOTT M. Spectral analysis of electrochemical noise with different transient shapes[J].Electrochimica Acta,2000,45(11):1763-1771.
【36】XIAO H,MANSFELD F. Evaluation of coatings regradation with electrochemical impedance spectroscopy and electrochemical noise analysis[J].Journal of the Electrochemical Society,1994,141(9):2332-2337.
【37】MANSFELD F,LEE C C,ZHANG G. Comparison of electrochemical impedance and noise data in the frequency domain[J].Electrochimica Acta,1997,43(3/4):435-438.
【38】BERTOCCI U,GABRIELLI C,HUET F,et al. Noise resistance applied to corrosion measurements I. theoretical analysis[J].Journal of the Electrochemical Society,1997,144(1):31-37.
【39】BERTOCCI U,GABRIELLI C,HUET F,et al. Noise resistance applied to corrosion measurements II. experimental tests[J].Journal of the Electrochemical Society,1997,144(1):37-43.
【40】MANSFELD F,HAN L T,LEE C C. Analysis of electrochemical noise data for polymer coated steel in the time and frequency domains[J].Journal of the Electrochemical Society,1996,143(12):286-289.
【41】MANSFELD F,HAN L T,LEE C C,et al. Analysis of electrochemical impedance and noise data for polymer coated metals[J].Corrosion Science,1997,39(2):255-279.
【42】MANSFELD F,LEE C C. The frequency dependence of the noise resistance for polymer-coated metals[J].Journal of the Electrochemical Society,1997,144(6):2068-2071.
【43】NAGIUB A,MANSFELD F. Evaluation of corrosion inhibition of brass in chloride media using EIS and ENA[J].Corrosion Science,2001,43(11):2147-2171.
【44】SANCHEZ-AMAYA J M,COTTIS R A,BOTANA F J. Shot noise and statistical parameters for the estimation of corrosion mechanisms[J].Corrosion Science,2005,47(12):3280-3299.
【45】Al-MAZEEDI H A A,COTTIS R A. A practical evaluation of electrochemical noise parameters as indicators of corrosion type[J].Electrochimica Acta,2004,49(17/18):2787-2793.
【46】SANCHEZ-AMAYA J M,BETHENCOURT M,GONZALEZ-ROVIRA L,et al. Noise resistance and shot noise parameters on the study of IGC of aluminium alloys with different heat treatments[J].Electrochimica Acta,2007,52(23):6569-6583.
【47】CERNA M,HARVEY A F. The fundamentals of FFT-based signal analysis and measurement[J].National Instruments,2002,41:3271-3280.
【48】ABALLE A,BETHENCOURT M,BOTANA F J,et al. Wavelet transform-based analysis for electrochemical noise[J].Electrochemistry Communications,1999,1(7):266-270.
【49】ABALLE A,BETHENCOURT M,BOTANA F J,et al. Using wavelets transform in the analysis of electrochemical noise data[J].Electrochimica Acta,1999,44(26):4805-4816.
【50】ABALLE A,BETHENCOURT M,BOTANA F J,et al. Use of wavelets to study electrochemical noise transients[J].Electrochimica Acta,2001,46(15):2353-2361.
【51】PLANINSIC P,PETEK A. Wavelets in electrochemical noise analysis,wavelets in electrochemical noise analysis[J].Discrete Wavelet Transforms-Biomedical Applications,Hannu Olkkonen(Ed.),InTech,2011:201-220.
【52】PLANINSIC P,PETEK A. Analysis of electrochemical noise signals using fractal-like function wavelets[C]//Interdisciplinary Applications of Fractal and Chaos Theory:Romane,Bucaresti,Romania,2004:322-334.
【53】CAO F H,ZHANG Z,SU J X. Electrochemical noise analysis of LY12-T3 in EXCO solution by discrete wavelet transform technique[J].Electrochimica Acta,2006,51(7):1359-1364.
【54】DAROWICKI K,ZIELINSKI A. Joint time-frequency analysis of electrochemical noise[J].Journal of Electroanalytical Chemistry,2001,504(2):201-207.
【55】AIDRICH C,QI B C,BOTHA P J. Analysis of electrochemical noise data with phase space methods[J].Minerals engineering,2006,19(14):1402-1409.
【56】LEGAT A,GOVEKAR E. Detection of corrosion by analysis of electrochemical noise[J].Fractals,1994,2(2):241-244.
【57】ASTM STP 1277Electrochemical noise measuremet for corrosion applications[S].
【58】LEGAT A,DOLECEK V. Chaotic analysis of electrochemical noise measured on stainless steel[J].Journal of the Electrochemical Society,1995,142(6):1851-1858.
【59】ASTM STP 1277The identification of pitting and crevice corrosion spectra in electrochemical noise using an artificial neural network[S].
【60】张涛,杨延格,邵亚薇,等. 电化学噪声分析方法的研究进展[J].中国腐蚀与防护学报,2014,34(1):1-18.
【2】HLADKY K,DAWSON J L. The measurement of corrosion using electrochemical 1/f noise[J].Corrosion Science,1982,22(3):231-237.
【3】HLADKY K. Corrosion Monitoring[P].US Patent 4575678,1986-3-11.
【4】BERTOCCI U,HUET F,NOGUEIRA R,et al. Drift removal procedures for PSD calculation[C]//Corrosion 2001:Houston,[s.l.],2001.
【5】BERTOCCI U,HUET F,NOGUEIRA R. Drift removal procedures in the analysis of electrochemical noise[J].Corrosion,2002,58(4):337-347.
【6】MANSFELD F,SUN Z,HSU C H,et al. Concerning trend removal in electrochemical noise measurements[J].Corrosion Science,2001,43(2):341-352.
【7】TAN Y J,BAILEY S,KINSELLA B. The monitoring of the formation and destruction of corrosion inhibitor films using electrochemical noise analysis (ENA)[J].Corrosion Science,1996,38(10):1681-1695.
【8】邱于兵,黄家怿,郭兴蓬. 多项式拟合法消除电化学噪声的直流漂移[J].华中科技大学学报:自然科学版,2005,33(10):39-42.
【9】黄家怿,邱于兵,郭兴蓬. 电化学噪声直流漂移的分段多项式拟合消除[J].中国腐蚀与防护学报,2009,29(1):9-14.
【10】张鉴清,张昭,王建明,等. 电化学噪声的分析与应用-I. 电化学噪声的分析原理[J].中国腐蚀与防护学报,2001,21(5):310-320.
【11】COTTIS R A. Interpretation of electrochemical noise data[J].Corrosion,2001,57(3):265-285.
【12】MANSFELD F. The electrochemical noise technique-applications in corrosion research[C]//18th International Conference on Noise and Fluctuations:Spain,[s.l.],2005:CP780.
【13】EDEN D A,HLADKY K,JOHN D G,et al. Electrochemical noise-simultaneous monitoring of potential and current noise signals from corroding electrodes[J].Corrosion 1986:Houston,[s.l.],1986:86274.
【14】MANSFELD F,XIAO H. Electrochemical noise analysis of iron exposed to NaCl solutions of different corrosivity[J].Journal of the Electrochemical Society,1993,140(8):2205-2209.
【15】GUSMANO G,MONTESPERELLI G,PACETTI S,et al. Electrochemical noise resistance as a tool for corrosion rate prediction[J].Corrosion,1997,53(11):860-868.
【16】CHEN J F,BOGAERTS W F. The physical meaning of noise resistance[J].Corrosion Science,1997,37(11):1839-1842.
【17】MANSFELD F,SUN Z. Localization index obtained from electrochemical noise analysis[J].Corrosion,1999,55(10):915-918.
【18】CHEN J F,BOGAERTS W F. Electrochemical emission spectroscopy for monitoring uniform and localized corrosion[J].Corrosion,1996,52(10):753-759.
【19】MANSFELD F,SUN Z,HSU C H. Electrochemical noise analysis (ENA) for active and passive systems in chloride media[J].Electrochimica Acta,2001,46(24):3651-3664.
【20】COTTIS R A,Al-AWADHI M A A,Al-MAZEEDI H,et al. Measures for the detection of localized corrosion with electrochemical noise[J].Electrochimica Acta,2001,46(24):3665-3674.
【21】ROBERGE P R. Analysis of electrochemical noise by the stochastic process detector method[J].Corrosion,1994,50(7):502-512.
【22】GABRIELLI C,HUET F,KEDDAM M,et al. A review of the probabilistic aspects of localized corrosion[J].Corrosion,1990,46(4):266-279.
【23】CHENG Y F,LUO J L. Metastable pitting of carbon steel under potentiostatic control[J].Journal of the Electrochemical Society,1999,146(3):970-976.
【24】COTTIS R A. Sources of electrochemical noise in corroding systems[J].Russian Journal of Electrochemistry,2006,42(5):497-505.
【25】张昭,张鉴清,李劲风,等. 因次分析法在电化学噪声分析中的应用[J].物理化学学报,2001,17(7):651-654.
【26】曹楚南,常晓元,林海潮. 孔蚀过程中的电化学噪声特征[J].中国腐蚀与防护学报,1989,9(1):21-28.
【27】LEGAT A,DOLECEK V. Corrosion monitoring system based on measurement and analysis of electrochemical noise[J].Corrosion,1995,51(4):295-300.
【28】LEGAT A,ZEVNIK C. The electrochemical noise of mild and stainless steel in various water solutions[J].Corrosion Science,1993,35(5/8):1661-1666.
【29】EDEN D A. Electrochemical noise-the first two octaves[C]//Corrosion 98:Houston,[s.l.],1998:98386.
【30】URUCHRUTU J C,DAWSON J L. Noise analysis of pure aluminum under different pitting conditions[J].Corrosion,1987,43(1):19-25.
【31】FLIS J,DAWSON J L,GILL J,et al. Impedance and electrochemical noise measurements on iron and iron-carbon alloys in hot caustic soda[J].Corrosion Science,1991,32(8):877-892.
【32】张鉴清,张昭,王建明,等. 电化学噪声的分析与应用-II. 电化学噪声的应用[J].中国腐蚀与防护学报,2002,22(4):241-248.
【33】BERTOCCI U,FRYDMAN J,GABRIRELLI C,et al. Analysis of electrochemical noise by power spectral density applied to corrosion studies[J].Journal of the Electrochemical Society,1998,145(8):2780-2786.
【34】BERTOCCI U,HUET F,JAOUL B,et al. Frequency analysis of transients in electrochemical noise:Mathematical relationships and computer simulations[J].Corrosion,2000,56(7):675-683.
【35】CHENG Y F,LUO J L,WILMOTT M. Spectral analysis of electrochemical noise with different transient shapes[J].Electrochimica Acta,2000,45(11):1763-1771.
【36】XIAO H,MANSFELD F. Evaluation of coatings regradation with electrochemical impedance spectroscopy and electrochemical noise analysis[J].Journal of the Electrochemical Society,1994,141(9):2332-2337.
【37】MANSFELD F,LEE C C,ZHANG G. Comparison of electrochemical impedance and noise data in the frequency domain[J].Electrochimica Acta,1997,43(3/4):435-438.
【38】BERTOCCI U,GABRIELLI C,HUET F,et al. Noise resistance applied to corrosion measurements I. theoretical analysis[J].Journal of the Electrochemical Society,1997,144(1):31-37.
【39】BERTOCCI U,GABRIELLI C,HUET F,et al. Noise resistance applied to corrosion measurements II. experimental tests[J].Journal of the Electrochemical Society,1997,144(1):37-43.
【40】MANSFELD F,HAN L T,LEE C C. Analysis of electrochemical noise data for polymer coated steel in the time and frequency domains[J].Journal of the Electrochemical Society,1996,143(12):286-289.
【41】MANSFELD F,HAN L T,LEE C C,et al. Analysis of electrochemical impedance and noise data for polymer coated metals[J].Corrosion Science,1997,39(2):255-279.
【42】MANSFELD F,LEE C C. The frequency dependence of the noise resistance for polymer-coated metals[J].Journal of the Electrochemical Society,1997,144(6):2068-2071.
【43】NAGIUB A,MANSFELD F. Evaluation of corrosion inhibition of brass in chloride media using EIS and ENA[J].Corrosion Science,2001,43(11):2147-2171.
【44】SANCHEZ-AMAYA J M,COTTIS R A,BOTANA F J. Shot noise and statistical parameters for the estimation of corrosion mechanisms[J].Corrosion Science,2005,47(12):3280-3299.
【45】Al-MAZEEDI H A A,COTTIS R A. A practical evaluation of electrochemical noise parameters as indicators of corrosion type[J].Electrochimica Acta,2004,49(17/18):2787-2793.
【46】SANCHEZ-AMAYA J M,BETHENCOURT M,GONZALEZ-ROVIRA L,et al. Noise resistance and shot noise parameters on the study of IGC of aluminium alloys with different heat treatments[J].Electrochimica Acta,2007,52(23):6569-6583.
【47】CERNA M,HARVEY A F. The fundamentals of FFT-based signal analysis and measurement[J].National Instruments,2002,41:3271-3280.
【48】ABALLE A,BETHENCOURT M,BOTANA F J,et al. Wavelet transform-based analysis for electrochemical noise[J].Electrochemistry Communications,1999,1(7):266-270.
【49】ABALLE A,BETHENCOURT M,BOTANA F J,et al. Using wavelets transform in the analysis of electrochemical noise data[J].Electrochimica Acta,1999,44(26):4805-4816.
【50】ABALLE A,BETHENCOURT M,BOTANA F J,et al. Use of wavelets to study electrochemical noise transients[J].Electrochimica Acta,2001,46(15):2353-2361.
【51】PLANINSIC P,PETEK A. Wavelets in electrochemical noise analysis,wavelets in electrochemical noise analysis[J].Discrete Wavelet Transforms-Biomedical Applications,Hannu Olkkonen(Ed.),InTech,2011:201-220.
【52】PLANINSIC P,PETEK A. Analysis of electrochemical noise signals using fractal-like function wavelets[C]//Interdisciplinary Applications of Fractal and Chaos Theory:Romane,Bucaresti,Romania,2004:322-334.
【53】CAO F H,ZHANG Z,SU J X. Electrochemical noise analysis of LY12-T3 in EXCO solution by discrete wavelet transform technique[J].Electrochimica Acta,2006,51(7):1359-1364.
【54】DAROWICKI K,ZIELINSKI A. Joint time-frequency analysis of electrochemical noise[J].Journal of Electroanalytical Chemistry,2001,504(2):201-207.
【55】AIDRICH C,QI B C,BOTHA P J. Analysis of electrochemical noise data with phase space methods[J].Minerals engineering,2006,19(14):1402-1409.
【56】LEGAT A,GOVEKAR E. Detection of corrosion by analysis of electrochemical noise[J].Fractals,1994,2(2):241-244.
【57】ASTM STP 1277Electrochemical noise measuremet for corrosion applications[S].
【58】LEGAT A,DOLECEK V. Chaotic analysis of electrochemical noise measured on stainless steel[J].Journal of the Electrochemical Society,1995,142(6):1851-1858.
【59】ASTM STP 1277The identification of pitting and crevice corrosion spectra in electrochemical noise using an artificial neural network[S].
【60】张涛,杨延格,邵亚薇,等. 电化学噪声分析方法的研究进展[J].中国腐蚀与防护学报,2014,34(1):1-18.
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