质子交换膜燃料电池用不锈钢双极板的腐蚀与表面改性研究进展
Review on Corrosion and Surface Modification of Stainless Steel Bipolar Plates for Proton Exchange Membrane Fuel Cells
摘 要
双极板是质子交换膜燃料电池(PEMFC)的核心组件之一, 占电池组重量和成本的大部分。不锈钢由于具有强度高、导电、传热性好以及耐腐蚀等优点, 因此被作为双极板材料。然而, 在PEMFC环境下, 不锈钢会发生腐蚀并且表面会产生高电阻钝化膜, 从而降低电池性能。为此, 国内外研究者对不锈钢双极板的腐蚀与表面处理展开了广泛的研究, 本文对此进行了详细阐述。
不锈钢双极板
腐蚀
表面改性
PEMFC
stainless steel bipolar plate
corrosion
surface modification
Abstract
The bipolar plate is one of key core components of the proton exchange membrane fuel cell (PEMFC), accounting for a significant part of total weight and cost of the PEMFC stack. Stainless steels have high strength, superior conductivity and thermal conductivity, good corrosion resistance, so they are often used as bipolar plate material. However, in PEMFC environment, stainless steels will be corroded and can produce high resistance passive film, and thus reduces the cell performance. Therefore, the corrosion and surface treatment of stainless steel bipolar plates are extensively investigated. In this paper, the progress in research is described in detail.
中图分类号 TG174
所属栏目 综述
基金项目 国家自然科学基金项目(No.21003089)
收稿日期 2010/11/22
修改稿日期 2010/12/13
网络出版日期
作者单位点击查看
备注徐群杰, 教授,
引用该论文: PAN Hong-tao,XU Qun-jie,YUN Hong,Deng Xian-qin. Review on Corrosion and Surface Modification of Stainless Steel Bipolar Plates for Proton Exchange Membrane Fuel Cells[J]. Corrosion & Protection, 2011, 32(8): 585
被引情况:
【1】张名涛,王冠仲,郭平义, "高能微弧合金化法制备Co-40Mn涂层的组织结构",腐蚀与防护 36, 914-917(2015)
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参考文献
【1】Ren Y J, Zeng C L. Corrosion protection of 304 stainless steel bipolar plates using TiC films produced by high-energy micro-arc alloying process[J]. Journal of Power Sources, 2007, 171(2):778-782.
【2】Tsuchiya H, Kobayashi O. Mass production cost of PEM fuel cell by learning curve[J]. International Journal of Hydrogen Energy, 2004, 29(10):985-990.
【3】Delas Heras N, Roberts E P L, Langton R, et al. A review of metal separator plate materials suitable for automotive PEM fuel cells[J]. Energy Environmental Science, 2009, 2:206-214.
【4】Kumagai M, Myung S, Ichikawa T, et al. Applicability of extra low interstitials ferritic stainless steels for bipolar plates of proton exchange membrane fuel cells[J]. Journal of Power Sources, 2010, 195(21):7181-7186.
【5】Yun Y, Choi S. Surface modification of stainless steel bipolar plates for PEMFC (proton exchange membrane fuel cell) application[J]. Journal of Electro ceramics, 2009, 23(2):462-467.
【6】Davies D P, Adcock P L, Turpin M, et al. Stainless steel as a bipolar plate material for solid polymer fuel cells[J]. Journal of Power Sources, 2000, 86(1/2):237-242.
【7】Lee S, Lai J, Huang C.Stainless steel bipolar plates[J]. Journal of Power Sources, 2005, 145(2):362-368.
【8】Brent C, Donald G B. The development of economical bipolar plates for fuel cells[J]. Journal of Materials Chemistry, 2006, 16:4385-4388.
【9】熊麟, 秦少雄, 颜学敏, 等. 质子交换膜燃料电池双极板材料研究进展[J]. 能源研究与信息, 2010, 26(1):1-6.
【10】Scherer J, Münter D, Strbel R. Influence of Metallic Bipolar Plates on the Durability of Polymer Electrolyte Fuel Cells[M]. New York:Springer, 2009:243-255.
【11】Dhakate S R, Sharma S, Chauhan N, et al. CNTs nanostructuring effect on the properties of graphite composite bipolar plate[J]. International Journal of Hydrogen Energy, 2010, 35(9):4195-4200.
【12】Hermann A, Chaudhuri T, Spagnol P. Bipolar plates for PEM fuel cells:A review[J]. International Journal of Hydrogen Energy, 2005, 30(12):1297-1302.
【13】Lee J H, Jang Y K, Hong C E, et al. Effect of carbon fillers on properties of polymer composite bipolar plates of fuel cells[J]. Journal of Power Sources, 2009, 193(2):523-529.
【14】Du C, Ming P, Hou M, et al. The preparation technique optimization of epoxy/compressed expanded graphite composite bipolar plates for proton exchange membrane fuel cells[J]. Journal of Power Sources, 2010, 195(16):5312-5319.
【15】Ren Y J, Chen J, Zeng C L. Corrosion protection of type 304 stainless steel bipolar plates of proton-exchange membrane fuel cells by doped polyaniline coating[J]. Journal of Power Sources, 2010, 195(7):1914-1919.
【16】Brady M P, Yang B, Wang H, et al. The formation of protective nitride surfaces for PEM fuel cell metallic bipolar plates[J]. JOM, 2006, 58(8):50-57.
【17】Mele C, Bozzini B. Localised corrosion processes of austenitic stainless steel bipolar plates for polymer electrolyte membrane fuel cells[J]. Journal of Power Sources, 2010, 195(11):3590-3596.
【18】Masanobu K, Seung-Taek M, Shiho K, et al. Corrosion behavior of austenitic stainless steels as a function of pH for use as bipolar plates in polymer electrolyte membrane fuel cells[J]. Electrochimica Acta, 2008, 53:4205-4212.
【19】李谋成, 曾潮流, 林海潮, 等. 316不锈钢在F-/Cl-酸性溶液中的腐蚀行为[J]. 中国腐蚀与防护学报, 2002, 22(3):162-166.
【20】Lafront A M, Ghali E, Morales A T. Corrosion behavior of two bipolar plate materials in simulated PEMFC environment by electrochemical noise technique[J]. Electro chemica Acta, 2007, 52(15):5076-5085.
【21】Zhang D M, Duan L T, Guo L, et al. Corrosion behavior of austenitic stainless steels as a function of pH for use as bipolar plates in polymer electrolyte membrane fuel cells[J]. Electrochimica Acta, 2008, 53:4205-4212.
【22】Chung C, Chen S, Chiu P, et al. Carbon film-coated 304 stainless steel as PEMFC bipolar plate[J]. Journal of Power Sources, 2008, 176(1):276-281.
【23】Yi P, Peng L, Feng L, et al. Performance of a proton exchange membrane fuel cell stack using conductive amorphous carbon-coated 304 stainless steel bipolar plates[J]. Journal of Power Sources, 2010, 195(20):7061-7066.
【24】Fukutsuka T, Yamaguchi T, Miyano S, et al. Carbon-coated stainless steel as PEFC bipolar plate material[J]. Journal of Power Sources, 2007, 174(1):199-205.
【25】Fu Y, Lin G, Hou M, et al. Carbon-based films coated 316L stainless steel as bipolar plate for proton exchange membrane fuel cells[J]. International Journal of Hydrogen Energy, 2009, 34(1):405-409.
【26】Joseph S, Mcclure J C, Chianelli R, et al. Conducting polymer-coated stainless steel bipolar plates for proton exchange membrane fuel cells (PEMFC)[J]. International Journal of Hydrogen Energy, 2005, 30(12):1339-1344.
【27】Ren Y J, Zeng C L. Effect of conducting composite polypyrrole/polyaniline coatings on the corrosion resistance of type 304 stainless steel for bipolar plates of proton-exchange membrane fuel cells[J]. Journal of Power Sources, 2008, 182(2):524-530.
【28】钱耀川, 谭俊, 石恭臣, 等. 电沉积铅改性304不锈钢双极板在模拟PEMFC环境中的性能[J]. 南京工业大学学报(自然科学版), 2009, 31(5):47-51.
【29】梁鹏, 徐洪峰, 刘明, 等. 镀银-石墨涂层316L不锈钢双极板的电化学性能测试及表征[J]. 物理化学学报, 2010, 26(3):595-600.
【30】Fu Y, Hou M, Xu H, et al. Ag-polytetrafluoroethylene composite coating on stainless steel as bipolar plate of proton exchange membrane fuel cell[J]. Journal of Power Sources, 2008, 182(2):580-584.
【31】王文涛, 吴博, 李红凯, 等. PEMFC不锈钢双极板离子镀CrNx薄膜表面改性[J]. 电源技术, 2009, 33(5):371-374.
【32】王文涛, 吴博, 李红凯, 等. 不锈钢双极板电弧离子镀Cr1-xNx薄膜改性研究[J]. 金属学报, 2009, 45(9):1125-1129.
【33】吴博, 王文涛, 张敏, 等. 不锈钢双极板表面电弧离子镀Cr/CrN/Cr薄膜研究[J]. 电源技术, 2007, 31(11):861-863.
【34】王剑莉, 孙俊才, 田如锦, 等. 表面改性不锈钢双极板的性能研究[J]. 电源技术, 2007, 31(9):725-727.
【35】Yoon J S, Lee J, Hwang H J, et al. Lanthanum oxide-coated stainless steel for bipolar plates in solid oxide fuel cells (SOFCs)[J]. Journal of Power Sources, 2008, 181(2):281-286.
【36】Wang H, Turner J A, Li X, et al. SnO2:F coated austenite stainless steels for PEM fuel cell bipolar plates[J]. Journal of Power Sources, 2007, 171(2):567-574.
【37】Park H, Park H, Hill R H. Direct-patterning of SnO2 thin film by photochemical metal-organic deposition[J]. Sensors and Actuators A:Physical.2006, 132(2):429-433.
【38】闫斌, 陈宏霞, 陈嘉宾, 等. SUS304不锈钢耐腐蚀性硅氧烷复合膜的研究[J]. 石油化工腐蚀与防护, 2008, 25(5):1-4.
【39】Chen L J, Chen M, Zhou H D, et al. Preparation of super-hydrophobic surface on stainless steel[J]. Applied Surface Science, 2008, 255(5, Part 2):3459-3462.
【40】Wang H, Zou M, Wei R. Superhydrophilic textured-surfaces on stainless steel substrates[J]. Thin Solid Films, 2009, 518(5):1571-1574.
【41】Feng K, Cai X, Sun H, et al. Carbon coated stainless steel bipolar plates in polymer electrolyte membrane fuel cells[J]. Diamond and Related Materials, 2010, 19(11):1354-1361.
【42】狄志勇, 何建平, 周建华, 等. 有机-无机自组装制备类荷叶结构超疏水涂层及其性能研究[J]. 无机材料学报, 2010, 25(7):765-769.
【43】Tadanaga K, Fujii T, Matsuda A, et al. Micropatterning of SnO2 thin films using hydrophobic-hydrophilic patterned surface[J]. Ceramics International, 2004, 30(7):1815-1817.
【44】Chen A, Peng X S, Koczkur K. Super-hydrophobic tin oxide nanoflowers[J]. Chem Commun, 2004, 1964-1965.
【45】沈广霞, 陈艺聪, 林昌健. 疏水型纳米TiO2膜的制备、表征及耐蚀性能研究[J]. 电化学, 2004, 10(1):65-69.
【2】Tsuchiya H, Kobayashi O. Mass production cost of PEM fuel cell by learning curve[J]. International Journal of Hydrogen Energy, 2004, 29(10):985-990.
【3】Delas Heras N, Roberts E P L, Langton R, et al. A review of metal separator plate materials suitable for automotive PEM fuel cells[J]. Energy Environmental Science, 2009, 2:206-214.
【4】Kumagai M, Myung S, Ichikawa T, et al. Applicability of extra low interstitials ferritic stainless steels for bipolar plates of proton exchange membrane fuel cells[J]. Journal of Power Sources, 2010, 195(21):7181-7186.
【5】Yun Y, Choi S. Surface modification of stainless steel bipolar plates for PEMFC (proton exchange membrane fuel cell) application[J]. Journal of Electro ceramics, 2009, 23(2):462-467.
【6】Davies D P, Adcock P L, Turpin M, et al. Stainless steel as a bipolar plate material for solid polymer fuel cells[J]. Journal of Power Sources, 2000, 86(1/2):237-242.
【7】Lee S, Lai J, Huang C.Stainless steel bipolar plates[J]. Journal of Power Sources, 2005, 145(2):362-368.
【8】Brent C, Donald G B. The development of economical bipolar plates for fuel cells[J]. Journal of Materials Chemistry, 2006, 16:4385-4388.
【9】熊麟, 秦少雄, 颜学敏, 等. 质子交换膜燃料电池双极板材料研究进展[J]. 能源研究与信息, 2010, 26(1):1-6.
【10】Scherer J, Münter D, Strbel R. Influence of Metallic Bipolar Plates on the Durability of Polymer Electrolyte Fuel Cells[M]. New York:Springer, 2009:243-255.
【11】Dhakate S R, Sharma S, Chauhan N, et al. CNTs nanostructuring effect on the properties of graphite composite bipolar plate[J]. International Journal of Hydrogen Energy, 2010, 35(9):4195-4200.
【12】Hermann A, Chaudhuri T, Spagnol P. Bipolar plates for PEM fuel cells:A review[J]. International Journal of Hydrogen Energy, 2005, 30(12):1297-1302.
【13】Lee J H, Jang Y K, Hong C E, et al. Effect of carbon fillers on properties of polymer composite bipolar plates of fuel cells[J]. Journal of Power Sources, 2009, 193(2):523-529.
【14】Du C, Ming P, Hou M, et al. The preparation technique optimization of epoxy/compressed expanded graphite composite bipolar plates for proton exchange membrane fuel cells[J]. Journal of Power Sources, 2010, 195(16):5312-5319.
【15】Ren Y J, Chen J, Zeng C L. Corrosion protection of type 304 stainless steel bipolar plates of proton-exchange membrane fuel cells by doped polyaniline coating[J]. Journal of Power Sources, 2010, 195(7):1914-1919.
【16】Brady M P, Yang B, Wang H, et al. The formation of protective nitride surfaces for PEM fuel cell metallic bipolar plates[J]. JOM, 2006, 58(8):50-57.
【17】Mele C, Bozzini B. Localised corrosion processes of austenitic stainless steel bipolar plates for polymer electrolyte membrane fuel cells[J]. Journal of Power Sources, 2010, 195(11):3590-3596.
【18】Masanobu K, Seung-Taek M, Shiho K, et al. Corrosion behavior of austenitic stainless steels as a function of pH for use as bipolar plates in polymer electrolyte membrane fuel cells[J]. Electrochimica Acta, 2008, 53:4205-4212.
【19】李谋成, 曾潮流, 林海潮, 等. 316不锈钢在F-/Cl-酸性溶液中的腐蚀行为[J]. 中国腐蚀与防护学报, 2002, 22(3):162-166.
【20】Lafront A M, Ghali E, Morales A T. Corrosion behavior of two bipolar plate materials in simulated PEMFC environment by electrochemical noise technique[J]. Electro chemica Acta, 2007, 52(15):5076-5085.
【21】Zhang D M, Duan L T, Guo L, et al. Corrosion behavior of austenitic stainless steels as a function of pH for use as bipolar plates in polymer electrolyte membrane fuel cells[J]. Electrochimica Acta, 2008, 53:4205-4212.
【22】Chung C, Chen S, Chiu P, et al. Carbon film-coated 304 stainless steel as PEMFC bipolar plate[J]. Journal of Power Sources, 2008, 176(1):276-281.
【23】Yi P, Peng L, Feng L, et al. Performance of a proton exchange membrane fuel cell stack using conductive amorphous carbon-coated 304 stainless steel bipolar plates[J]. Journal of Power Sources, 2010, 195(20):7061-7066.
【24】Fukutsuka T, Yamaguchi T, Miyano S, et al. Carbon-coated stainless steel as PEFC bipolar plate material[J]. Journal of Power Sources, 2007, 174(1):199-205.
【25】Fu Y, Lin G, Hou M, et al. Carbon-based films coated 316L stainless steel as bipolar plate for proton exchange membrane fuel cells[J]. International Journal of Hydrogen Energy, 2009, 34(1):405-409.
【26】Joseph S, Mcclure J C, Chianelli R, et al. Conducting polymer-coated stainless steel bipolar plates for proton exchange membrane fuel cells (PEMFC)[J]. International Journal of Hydrogen Energy, 2005, 30(12):1339-1344.
【27】Ren Y J, Zeng C L. Effect of conducting composite polypyrrole/polyaniline coatings on the corrosion resistance of type 304 stainless steel for bipolar plates of proton-exchange membrane fuel cells[J]. Journal of Power Sources, 2008, 182(2):524-530.
【28】钱耀川, 谭俊, 石恭臣, 等. 电沉积铅改性304不锈钢双极板在模拟PEMFC环境中的性能[J]. 南京工业大学学报(自然科学版), 2009, 31(5):47-51.
【29】梁鹏, 徐洪峰, 刘明, 等. 镀银-石墨涂层316L不锈钢双极板的电化学性能测试及表征[J]. 物理化学学报, 2010, 26(3):595-600.
【30】Fu Y, Hou M, Xu H, et al. Ag-polytetrafluoroethylene composite coating on stainless steel as bipolar plate of proton exchange membrane fuel cell[J]. Journal of Power Sources, 2008, 182(2):580-584.
【31】王文涛, 吴博, 李红凯, 等. PEMFC不锈钢双极板离子镀CrNx薄膜表面改性[J]. 电源技术, 2009, 33(5):371-374.
【32】王文涛, 吴博, 李红凯, 等. 不锈钢双极板电弧离子镀Cr1-xNx薄膜改性研究[J]. 金属学报, 2009, 45(9):1125-1129.
【33】吴博, 王文涛, 张敏, 等. 不锈钢双极板表面电弧离子镀Cr/CrN/Cr薄膜研究[J]. 电源技术, 2007, 31(11):861-863.
【34】王剑莉, 孙俊才, 田如锦, 等. 表面改性不锈钢双极板的性能研究[J]. 电源技术, 2007, 31(9):725-727.
【35】Yoon J S, Lee J, Hwang H J, et al. Lanthanum oxide-coated stainless steel for bipolar plates in solid oxide fuel cells (SOFCs)[J]. Journal of Power Sources, 2008, 181(2):281-286.
【36】Wang H, Turner J A, Li X, et al. SnO2:F coated austenite stainless steels for PEM fuel cell bipolar plates[J]. Journal of Power Sources, 2007, 171(2):567-574.
【37】Park H, Park H, Hill R H. Direct-patterning of SnO2 thin film by photochemical metal-organic deposition[J]. Sensors and Actuators A:Physical.2006, 132(2):429-433.
【38】闫斌, 陈宏霞, 陈嘉宾, 等. SUS304不锈钢耐腐蚀性硅氧烷复合膜的研究[J]. 石油化工腐蚀与防护, 2008, 25(5):1-4.
【39】Chen L J, Chen M, Zhou H D, et al. Preparation of super-hydrophobic surface on stainless steel[J]. Applied Surface Science, 2008, 255(5, Part 2):3459-3462.
【40】Wang H, Zou M, Wei R. Superhydrophilic textured-surfaces on stainless steel substrates[J]. Thin Solid Films, 2009, 518(5):1571-1574.
【41】Feng K, Cai X, Sun H, et al. Carbon coated stainless steel bipolar plates in polymer electrolyte membrane fuel cells[J]. Diamond and Related Materials, 2010, 19(11):1354-1361.
【42】狄志勇, 何建平, 周建华, 等. 有机-无机自组装制备类荷叶结构超疏水涂层及其性能研究[J]. 无机材料学报, 2010, 25(7):765-769.
【43】Tadanaga K, Fujii T, Matsuda A, et al. Micropatterning of SnO2 thin films using hydrophobic-hydrophilic patterned surface[J]. Ceramics International, 2004, 30(7):1815-1817.
【44】Chen A, Peng X S, Koczkur K. Super-hydrophobic tin oxide nanoflowers[J]. Chem Commun, 2004, 1964-1965.
【45】沈广霞, 陈艺聪, 林昌健. 疏水型纳米TiO2膜的制备、表征及耐蚀性能研究[J]. 电化学, 2004, 10(1):65-69.
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