两种铝青铜合金在中性盐雾中腐蚀行为比较
Comparation of Corrosion Behavior of Two Kinds of Aluminum Bronze in Neutral Salt Spray
摘 要
采用中性盐雾试验、X射线衍射、扫描电镜及能谱分析等方法研究了两种新型高强耐磨铝青铜合金(代号KK1和KK3)在模拟海洋大气环境下的耐腐蚀性能和腐蚀行为。结果表明, 在盐雾试验初期, 两种合金的腐蚀速率都随腐蚀时间的延长而降低; 168 h后, 腐蚀速率基本不变。在相同的中性盐雾腐蚀条件下, KK3合金的耐腐蚀性能优于KK1合金。在中性盐雾腐蚀过程中, 两种铝青铜的腐蚀都表现为选择性腐蚀, 此外, KK3合金发生点蚀, 而KK1未发现点蚀现象。两种合金耐腐蚀性能不同的重要原因之一是KK1合金中存在大量的块状β′相。
中性盐雾腐蚀
腐蚀速率
选择性腐蚀
aluminum bronze
neutral salt spray test
corrosion rate
selective corrosion
Abstract
The corrosion behaviors of two kinds of high-strength and wear-resistant novel aluminum bronzes (KK1 and KK3) were studied by neutral salt spray, X-ray diffraction, scanning electron microscopy and energy dispersive X-ray detector. The results showed that in the initial stage the average corrosion rate of the tested materials decreased with the increase of exposure time, then kept constant after testing for 168 h. In the neutral salt spray atmosphere, KK3 alloy had better corrosion resistantce than KK1 alloy. Pitting corrosion was found on the surface of KK3 alloy, while no pitting corrosion was found on KK1 alloy. The results of SEM showed that selective corrosion occurred in both alloys. The block β′-phase in the KK1 alloy was one of the key points which made the difference of the corrosion resistance of the two alloys.
中图分类号 TG172.6
所属栏目 试验研究
基金项目
收稿日期 2010/10/28
修改稿日期 2010/11/15
网络出版日期
作者单位点击查看
备注辛保亮, 硕士研究生,
引用该论文: XIN Bao-liang,ZHANG Wei-wen,LUO Zong-qiang,ZHANG Da-tong,LI Yuan-yuan. Comparation of Corrosion Behavior of Two Kinds of Aluminum Bronze in Neutral Salt Spray[J]. Corrosion & Protection, 2011, 32(9): 712
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参考文献
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【2】Alfantazi A M, Ahmed T M, Tromans D, et al. Corrosion behavior of copper alloys in chloride media[J]. Materials and Design, 2009, 30:2425-2430.
【3】李元元, 夏伟, 张文, 等. 高强度耐磨铝青铜合金及其摩擦学特性[J]. 中国有色金属学报, 1996, 6(3):76-80.
【4】Chen R P, Liang Z Q, Zhang W W, et al. Effect of heat treatment on microstructure and properties of hot-extruded nickel-aluminum bronze[J]. Trans Nonferrous Met Soc China, 2007, 17:1254-1258.
【5】Gilberto P T, 李筱月(译). 关于铜合金在海水中腐蚀性能近期研究的述评[J]. 材料开发与应用, 1983(4):12-20.
【6】张吉刚, 王振尧, 魏立营, 等. 铜合金及其复合材料在氯化钠盐雾中的腐蚀行为[J]. 中国有色金属学报, 2004, 14(5):836-841.
【7】Culpan E A, Rose G. Corrosion behavior of cast nickel aluminum bronze in sea water[J]. British Corrosion Journal, 1979, 14(3):160-166.
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