稀土强化镁合金耐蚀性能的研究进展
Research Progress of Corrosion Resistance of Magnesium Alloys Strengthened by Rare-earth
摘 要
综述了稀土合金元素加入及稀土盐化学转化处理等方法强化镁合金耐蚀性能的国内外研究现状, 展望了稀土强化镁合金耐蚀性能的发展前景。
镁合金
稀土转化膜
耐蚀性
rare-earth
magnesium alloy
rare-earth conversion film
corrosion resistance
Abstract
The research progress of corrosion resistance of magnesium alloys strengthened by rare-earth elements and rare-earth conversion technology at home and abroad is reviewed. The prospect of the two techniques is discussed.
中图分类号 TG146.2+2 TB304
所属栏目 专论
基金项目 国家973重大基础研究项目(2007CB613700); 国家杰出青年科学基金(No.50725413); 重庆市科技攻关计划项目(CSTC2008AC4088)
收稿日期 2011/3/29
修改稿日期
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备注陈昌国,教授,博士生导师,
引用该论文: JIANG Xiao-jun,CHEN Chang-guo,LIU Yu-Ping,YIN Ling,ZHANG Ding-fei. Research Progress of Corrosion Resistance of Magnesium Alloys Strengthened by Rare-earth[J]. Corrosion & Protection, 2012, 33(1): 46
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参考文献
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【3】Nakatsugawa T R,Martin R,Knystautas E J. Improving corrosion resistance of AZ91D magnesium alloy by nitrogenI on implantation[J]. Corrosion,1996,52(12):921-926.
【4】Sharma A K. Chromate conversion coatings for magnesium lithium alloys[J]. Metal Finishing,1989,67(2):73-74.
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【6】Wang Q,Liu Y H,Fang S J,et al. Evaluating the improvement of corrosion residual strength by adding 1.0% yttrium into an AZ91D magnesium alloy[J]. Materials Charactization,2010,61:674-682.
【7】张诗昌,胡衍生,魏伯康. 钇对压铸AZ91镁合金耐腐蚀性能的影响[J]. 铸造,2005,54(9):881-883.
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【9】Liu W J,Cao F H,Chang L R,et.al. Effect of rare earth element Ce and La on corrosion behavior of AM60 magnesium alloy[J]. Corrosion Science,2009,51:1334-1343.
【10】Niu J X,Chen Q R,Xu N X,et al. Effect of combinative addition of strontium and rare earth elements on corrosion resistance of AZ91D magnesium alloy[J]. Transactions of Nonferrous Metals Society of China,2008,18:1058-1064.
【11】刘生发,王慧源,徐萍. 钕对AZ91镁合金腐蚀性能的影响[J]. 铸造,2006,55(3):296-299.
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【13】Zhou X H,Huang Y W,Wei Z L,et al. Improvement of corrosion resistance of AZ91D magnesium alloy by holmium addition[J]. Corrosion Science,2006,48:4223-4233.
【14】Liu M,Patrik S,Peter J,et.al. The influence of yttrium (Y) on the corrosion of Mg-Y binary alloys[J]. Corrosion Science,2010,52:3687-3701.
【15】Birbilis N,Cavanaugh M K,Sudholz A D,et.al. A combined neural network and mechanistic approach for the prediction of corrosion rate and yield strength of magnesium-rare earth alloys[J]. Corrosion Science,2011,53:168-176.
【16】Pinto R,Ferreira M G S,Carmezim M J,et.al. The corrosion behavior of rare-earth containing magnesium alloys in borate buffer solution[J]. Electrochimica Acta,2011,56:1535-1545.
【17】孙凤仙,纪红,李永丰. 镁合金无铬化学转化处理的发展现状[J]. 腐蚀与防护,2010,31(5):402-406.
【18】赵强,周婉秋,武士威,等. 镁合金无铬化学转化膜的研究进展[J]. 电镀与精饰,2010,32(8):30-33.
【19】胡会利,陈丽姣. 表面转化膜无铬化技术的研究动向[J]. 腐蚀与防护,2009,30(10):727-731.
【20】Gray J E,Luan B. Ptrotective coatings on magnesium and Its alloy-a critical review[J]. Journal of Alloys and Compunds,2002,336:88-113.
【21】Montemor M F,Simǒes A M,Ferreira M G S,et al. Composition and corrosion resistance of cerium conversion films on the AZ31 magnesium alloy and its relation to the anion[J]. Surface Science,2008,254:1806-1814.
【22】Manuele D,Katya B,Enrico N,et.al. Cerium-based chemical conversion coating on AZ63 magnesium alloy[J]. Surface and Coatings Technology,2003,172:227-232.
【23】易建龙,张新明,马光,等. Mg-Gd-Y-Zr合金表面铈转化膜制备及耐蚀性能[J]. 稀有金属材料工程,2009,38(10):1852-1855.
【24】杨潇薇,王桂香,董国君,等. AZ31镁合金稀土转化成膜及其耐蚀性能的研究[J]. 电镀与环保,2008,28(2):31-34.
【25】张丽丽,王桂香,董国君,等. 镁合金双稀土转化膜及其耐蚀性能的研究[J]. 材料保护,2008,41(12):1-4.
【26】Yue S X,Lü Q Y,Han J,et al. Preparation and performance of rare earths chemical conversion film on magnesium alloy[J]. Journal of Rare Earths,2006,24:397-400.
【27】曹大勇. AZ31镁合金稀土转化成膜工艺研究[J]. 化学工程师,2009,167(8):72-74.
【28】Katya B,Manuele D,Irene C,et al. Effect of HCl pre-treatment on corrosion resistance of cerium-based conversion coatings on magnesium and magnesium alloys[J]. Corrosion Science,2005,47:989-1000.
【29】白丽群,舒康颖,郭敏,等. 预处理对镁合金镧转化膜及耐腐蚀性能的影响[J]. 中国稀土学报,2008,26(5):592-597.
【30】钟丽应,曹发和,施彦彦,等. AZ91镁合金表面铈基稀土转化膜的制备及腐蚀电化学行为[J]. 金属学报,2008,44(8):979-985.
【31】杨在兴,霍宏伟,王艳,等. AZ91D镁合金表面铈转化膜成膜工艺及其耐腐蚀性的研究[J]. 腐蚀科学与防护技术,2009,21(2):200-202.
【32】杨潇薇,王桂香,董国君,等. 镁-锂合金稀土转化工艺的研究[J]. 电镀与环保,2010,30(1):31-34.
【33】古锐,张新明,陈明安,等. 两种成膜促经剂对Mg-Gd-Y-Zr镁合金表面铈盐转化膜耐蚀性能的影响[J]. 腐蚀与防护,2009,30(11):839-842.
【34】赵爱彬,尹志娟,席慧智,等. AZ91镁合金热扩渗涂层的研究[J]. 应用科技,2006,33(8):58-61.
【35】张勇,许越,周德瑞,等. 稀土铈对AZ91镁合金表面腐蚀性能的影响[J]. 哈尔滨工业大学学报,2002,34(3):376-378.
【36】许越,李莎. 镁合金表面铈氧化物陶瓷涂层的腐蚀特性及耐蚀机理研究[J]. 稀有金属材料与工程,2007,36(2):725-727.
【37】史敬伟,邵忠财,田彦文,等. 稀土元素对镁合金微弧氧化的影响[J]. 材料保护,2007,40(5):7-9.
【38】Yi J L,Zhang X M,Chen M A,et al. Effect of Na2CO3 on corrosion resistance of cerium film on Mg-Gd-Y-Zr magnesium alloy surface[J]. Scripta Materialia,2008,59:955-958.
【39】李仕慧,陈芙蓉. 含稀土镁铝系合金耐腐蚀性能的研究[J]. 腐蚀与防护,2007,28(7):333-336.
【40】Hinton B R W,Amott D R,Ryan N E. Cerium conversion coating for the corrosion protection of aluminum[J]. Materials Forum,1986,9(3):1622-1628.
【41】Amott D R,Ryan N E,Hinton B R W. Auger and XPS studies of cerium corrosion inhibition on 7075 aluminum alloy[J]. Application of Surface Science,1984,22(1):2362-2366.
【42】白丽群,钱建刚,舒康颖,等. 镁合金稀土镧化学转化工艺研究[J]. 腐蚀与防护,2009,30(7):466-469.
【43】尧玉芬,陈昌国,刘渝萍,等. 镧对AZ31镁合金电化学行为的影响[J]. 中国稀土学报,2009,27(5):688-690.
【2】Allan F,Terje K A,David H. Corrosion of magnesium and magnesium alloys[M]. ASTM International. Metal Handbook 9th EditionVol.13 Corrosion.
【3】Nakatsugawa T R,Martin R,Knystautas E J. Improving corrosion resistance of AZ91D magnesium alloy by nitrogenI on implantation[J]. Corrosion,1996,52(12):921-926.
【4】Sharma A K. Chromate conversion coatings for magnesium lithium alloys[J]. Metal Finishing,1989,67(2):73-74.
【5】宋光铃. 镁合金腐蚀与防护[M]. 北京:化学工业出版社,2006,169.
【6】Wang Q,Liu Y H,Fang S J,et al. Evaluating the improvement of corrosion residual strength by adding 1.0% yttrium into an AZ91D magnesium alloy[J]. Materials Charactization,2010,61:674-682.
【7】张诗昌,胡衍生,魏伯康. 钇对压铸AZ91镁合金耐腐蚀性能的影响[J]. 铸造,2005,54(9):881-883.
【8】Luo T J,Yang Y S,Li Y J,et.al. Inuence of rare earth Y on the corrosion behavior of as-cast AZ91 alloy[J]. Electrochimica Acta,2009,54:6433-6437.
【9】Liu W J,Cao F H,Chang L R,et.al. Effect of rare earth element Ce and La on corrosion behavior of AM60 magnesium alloy[J]. Corrosion Science,2009,51:1334-1343.
【10】Niu J X,Chen Q R,Xu N X,et al. Effect of combinative addition of strontium and rare earth elements on corrosion resistance of AZ91D magnesium alloy[J]. Transactions of Nonferrous Metals Society of China,2008,18:1058-1064.
【11】刘生发,王慧源,徐萍. 钕对AZ91镁合金腐蚀性能的影响[J]. 铸造,2006,55(3):296-299.
【12】刘生发,刘林艳,黄尚宇,等. 铈对AZ91镁合金腐蚀性能的影响[J]. 中国稀土学报,2006,24(2):211-216.
【13】Zhou X H,Huang Y W,Wei Z L,et al. Improvement of corrosion resistance of AZ91D magnesium alloy by holmium addition[J]. Corrosion Science,2006,48:4223-4233.
【14】Liu M,Patrik S,Peter J,et.al. The influence of yttrium (Y) on the corrosion of Mg-Y binary alloys[J]. Corrosion Science,2010,52:3687-3701.
【15】Birbilis N,Cavanaugh M K,Sudholz A D,et.al. A combined neural network and mechanistic approach for the prediction of corrosion rate and yield strength of magnesium-rare earth alloys[J]. Corrosion Science,2011,53:168-176.
【16】Pinto R,Ferreira M G S,Carmezim M J,et.al. The corrosion behavior of rare-earth containing magnesium alloys in borate buffer solution[J]. Electrochimica Acta,2011,56:1535-1545.
【17】孙凤仙,纪红,李永丰. 镁合金无铬化学转化处理的发展现状[J]. 腐蚀与防护,2010,31(5):402-406.
【18】赵强,周婉秋,武士威,等. 镁合金无铬化学转化膜的研究进展[J]. 电镀与精饰,2010,32(8):30-33.
【19】胡会利,陈丽姣. 表面转化膜无铬化技术的研究动向[J]. 腐蚀与防护,2009,30(10):727-731.
【20】Gray J E,Luan B. Ptrotective coatings on magnesium and Its alloy-a critical review[J]. Journal of Alloys and Compunds,2002,336:88-113.
【21】Montemor M F,Simǒes A M,Ferreira M G S,et al. Composition and corrosion resistance of cerium conversion films on the AZ31 magnesium alloy and its relation to the anion[J]. Surface Science,2008,254:1806-1814.
【22】Manuele D,Katya B,Enrico N,et.al. Cerium-based chemical conversion coating on AZ63 magnesium alloy[J]. Surface and Coatings Technology,2003,172:227-232.
【23】易建龙,张新明,马光,等. Mg-Gd-Y-Zr合金表面铈转化膜制备及耐蚀性能[J]. 稀有金属材料工程,2009,38(10):1852-1855.
【24】杨潇薇,王桂香,董国君,等. AZ31镁合金稀土转化成膜及其耐蚀性能的研究[J]. 电镀与环保,2008,28(2):31-34.
【25】张丽丽,王桂香,董国君,等. 镁合金双稀土转化膜及其耐蚀性能的研究[J]. 材料保护,2008,41(12):1-4.
【26】Yue S X,Lü Q Y,Han J,et al. Preparation and performance of rare earths chemical conversion film on magnesium alloy[J]. Journal of Rare Earths,2006,24:397-400.
【27】曹大勇. AZ31镁合金稀土转化成膜工艺研究[J]. 化学工程师,2009,167(8):72-74.
【28】Katya B,Manuele D,Irene C,et al. Effect of HCl pre-treatment on corrosion resistance of cerium-based conversion coatings on magnesium and magnesium alloys[J]. Corrosion Science,2005,47:989-1000.
【29】白丽群,舒康颖,郭敏,等. 预处理对镁合金镧转化膜及耐腐蚀性能的影响[J]. 中国稀土学报,2008,26(5):592-597.
【30】钟丽应,曹发和,施彦彦,等. AZ91镁合金表面铈基稀土转化膜的制备及腐蚀电化学行为[J]. 金属学报,2008,44(8):979-985.
【31】杨在兴,霍宏伟,王艳,等. AZ91D镁合金表面铈转化膜成膜工艺及其耐腐蚀性的研究[J]. 腐蚀科学与防护技术,2009,21(2):200-202.
【32】杨潇薇,王桂香,董国君,等. 镁-锂合金稀土转化工艺的研究[J]. 电镀与环保,2010,30(1):31-34.
【33】古锐,张新明,陈明安,等. 两种成膜促经剂对Mg-Gd-Y-Zr镁合金表面铈盐转化膜耐蚀性能的影响[J]. 腐蚀与防护,2009,30(11):839-842.
【34】赵爱彬,尹志娟,席慧智,等. AZ91镁合金热扩渗涂层的研究[J]. 应用科技,2006,33(8):58-61.
【35】张勇,许越,周德瑞,等. 稀土铈对AZ91镁合金表面腐蚀性能的影响[J]. 哈尔滨工业大学学报,2002,34(3):376-378.
【36】许越,李莎. 镁合金表面铈氧化物陶瓷涂层的腐蚀特性及耐蚀机理研究[J]. 稀有金属材料与工程,2007,36(2):725-727.
【37】史敬伟,邵忠财,田彦文,等. 稀土元素对镁合金微弧氧化的影响[J]. 材料保护,2007,40(5):7-9.
【38】Yi J L,Zhang X M,Chen M A,et al. Effect of Na2CO3 on corrosion resistance of cerium film on Mg-Gd-Y-Zr magnesium alloy surface[J]. Scripta Materialia,2008,59:955-958.
【39】李仕慧,陈芙蓉. 含稀土镁铝系合金耐腐蚀性能的研究[J]. 腐蚀与防护,2007,28(7):333-336.
【40】Hinton B R W,Amott D R,Ryan N E. Cerium conversion coating for the corrosion protection of aluminum[J]. Materials Forum,1986,9(3):1622-1628.
【41】Amott D R,Ryan N E,Hinton B R W. Auger and XPS studies of cerium corrosion inhibition on 7075 aluminum alloy[J]. Application of Surface Science,1984,22(1):2362-2366.
【42】白丽群,钱建刚,舒康颖,等. 镁合金稀土镧化学转化工艺研究[J]. 腐蚀与防护,2009,30(7):466-469.
【43】尧玉芬,陈昌国,刘渝萍,等. 镧对AZ31镁合金电化学行为的影响[J]. 中国稀土学报,2009,27(5):688-690.
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