具有超疏水表面的铜及铜合金耐蚀行为研究进展
Progress in Research on Corrosion Performance of Copper and Copper Alloys with Super-hydrophobic Surface
摘 要
随着铜及其合金的广泛应用, 腐蚀问题也造成了巨大的社会和经济损失,超疏水表面处理是一种新型且非常有前景的金属防腐蚀方法。本文简要介绍了用于制备铜基超疏水表面的疏水材料和方法; 重点分析了超疏水表面对铜及铜合金耐蚀性能的影响; 归纳了超疏水表面防腐蚀的机理; 总结了超疏水表面防腐蚀的技术障碍; 最后提出了超疏水表面与缓蚀剂联合防腐蚀的新思路。
腐蚀
铜
接触角
super-hydrophobic surface
corrosion
copper
contact angle
Abstract
With the extensive use of copper and its alloys, corrosion causes tremendous social and economic losses. Super-hydrophobic surface is a new and promising method for corrosion prevention. In this paper, hydrophobic materials and methods for the preparation of copper-based super-hydrophobic surface are outlined briefly. The impact of super-hydrophobic surface on corrosion of copper and copper alloys is analyzed. The mechanism of super-hydrophobic suface for anti-corrosion is summarized. The possible technical barriers in practical application are also summarized. A new idea combining super-hydrophobic surface with inhibitor for corrosion control is proposed.
中图分类号 TG174.42
所属栏目 专论
基金项目 国家自然科学基金(No.21003089)
收稿日期 2011/3/15
修改稿日期
网络出版日期
作者单位点击查看
备注徐群杰,教授,
引用该论文: Deng Xian-Qin,XU Qun-jie,YUN Hong,PAN Hong-tao. Progress in Research on Corrosion Performance of Copper and Copper Alloys with Super-hydrophobic Surface[J]. Corrosion & Protection, 2012, 33(1): 51
被引情况:
【1】李美明,徐群杰,韩杰,张志国, "绿色铜缓蚀剂的研究进展",腐蚀与防护 35, 1243-1247(2014)
【2】李美明,徐群杰,韩杰, "海上风电的防腐蚀研究与应用现状",腐蚀与防护 35, 584-589(2014)
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参考文献
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【22】王燕华,钟莲,刘圆圆,等. 镁基体超疏水表面制备及表征[J]. 腐蚀科学与防护技术,2010,22(4):329-332.
【23】Chen S,Chen Y,Lei Y,et al. Novel strategy in enhancing stability and corrosion resistance for hydrophobic functional films on copper surfaces[J]. Electrochemistry Communications,2009,11(8):1675-1679.
【24】Chen L,Thermophysics S L R Y,Sciences C A O,et al. n-Octadecanethiol self-assembled monolayer coating with microscopic roughness for dropwise condensation of steam[J]. Journal of Thermal Science,2009,18(2):160-165.
【25】Kang Z,Ye Q,Sang J,et al. Fabrication of super-hydrophobic surface on copper surface by polymer plating[J]. Journal of Materials Processing Technology,2009,209(9):4543-4547.
【26】Yin Y,Liu T,Chen S,et al. Structure stability and corrosion inhibition of super-hydrophobic film on aluminum in seawater[J]. Applied Surface Science,2008,255(5):2978-2984.
【27】Ishizaki T,Hieda J,Saito N,et al. Corrosion resistance and chemical stability of super-hydrophobic film deposited on magnesium alloy AZ31 by microwave plasma-enhanced chemical vapor deposition[J]. Electrochimica Acta,2010,55(23):7094-7101.
【28】Wang P,Qiu R,Zhang D,et al. Fabricated super-hydrophobic film with potentiostatic electrolysis method on copper for corrosion protection[J]. Electrochimica Acta,In Press,Accepted Manuscript.
【29】李松梅,周思卓,刘建华. 铝合金表面原位自组装超疏水膜层的制备及耐蚀性能[J]. 物理化学学报,2009,25(12):2581-2589.
【30】Yang H,Pi P,Cai Z,et al. Facile preparation of super-hydrophobic and super-oleophilic silica film on stainless steel mesh via sol-gel process[J]. Applied Surface Science,2010,256(13):4095-4102.
【31】Liu T,Chen S,Cheng S,et al. Corrosion behavior of super-hydrophobic surface on copper in seawater[J]. Electrochimica Acta,2007,52(28):8003-8007.
【32】Zhu H,Chen S,Chen Y,et al. Investigation of the corrosion resistance of n-tetradecanoic acid and its hybrid film with bis-silane on copper surface in seawater[J]. Journal of Molecular Structure,2009,928(1-3): 40-45.
【33】时士峰,蔡希宏,徐群杰. 疏水处理对白铜B30缓蚀作用的电化学研究[C]//2010年全国腐蚀电化学及测试方法学术会议论文集,杭州:2010.
【2】许立国. 某火电厂凝汽器铜管初期腐蚀的原因[J]. 腐蚀与防护,2010,31(1):92-94.
【3】徐群杰,万宗跃,黄诗俊,等. 模拟冷却水中黄铜管耐蚀性影响因素的光电化学研究[J]. 华东电力,2008,36(4):94-96.
【4】余存烨. 滨海石化厂钛铜共用海水冷却器牺牲阳极保护探讨[J]. 腐蚀与防护,2004,25(2):61-64.
【5】徐群杰,李春香,周国定,等. 3-氨基-1,2,4-三氮唑对铜的缓蚀性能和吸附行为[J]. 物理化学学报,2009,25(1):86-90.
【6】徐群杰,朱律均,曹为民,等. 绿色缓蚀剂聚天冬氨酸对铜的缓蚀性能与吸附行为[J]. 物理化学学报,2008,24(9):1724-1728.
【7】卢锦堂,袁美蓉,孔纲. 金属表面防腐蚀硅溶胶涂层的研究进展[J]. 腐蚀与防护,2009,30(1):11-14.
【8】郑顺兴,臧殿荣. 有机无机杂化涂料的防腐蚀性能[J]. 涂料工业,2009,39(6):56-59.
【9】白春钰,梁燕萍. 不锈钢表面导电聚苯胺薄膜的耐腐蚀性能[J]. 材料保护,2008,41(7):1-3.
【10】Hao C,Yin R,Wan Z,et al. Electrochemical and photoelectrochemical study of the self-assembled monolayer phytic acid on cupronickel B30[J]. Corrosion Science,2008,50(12):3527-3533.
【11】Feng L,Li S,Li Y,et al. Super-hydrophobic surfaces:from natural to artificial[J]. Advanced Materials,2002,14(24):1857-1860.
【12】Chen L J,Chen M,Zhou H D,et al. Preparation of super-hydrophobic surface on stainless steel[J]. Applied Surface Science,2008,255(5):3459-3462.
【13】Liu T,Yin Y,Chen S,et al. Super-hydrophobic surfaces improve corrosion resistance of copper in seawater[J]. Electrochimica Acta,2007,52(11):3709-3713.
【14】Yin B,Fang L,Hu J,et al. Preparation and properties of super-hydrophobic coating on magnesium alloy[J]. Applied Surface Science,2011,257(6):1821-1827.
【15】He T,Wang Y,Zhang Y,et al. Super-hydrophobic surface treatment as corrosion protection for aluminum in seawater[J]. Corrosion Science,2009,51(8):1757-1761.
【16】Wang D,Liu Y,Hu H,et al. Electrochemical characterization of the solution accessibility of CaTiO3 microstructures and improved biomineralization[J]. The Journal of Physical Chemistry C,2008,112(41):16123-16129.
【17】Xu X,Zhang Z,Yang J. Fabrication of biomimetic superhydrophobic surface on engineering materials by a simple electroless galvanic deposition method[J]. Langmuir,2010,26(5):3654-3658.
【18】Fu X,He X. Fabrication of super-hydrophobic surfaces on aluminum alloy substrates[J]. Applied Surface Science,2008,255(5):1776-1781.
【19】Liu K,Zhang M,Zhai J,et al. Bioinspired construction of Mg-Li alloys surfaces with stable superhydrophobicity and improved corrosion resistance[J]. Applied Physics Letters,2008,92(18):183103.
【20】Shen G X,Chen Y C,Lin L,et al. Study on a hydrophobic nano-TiO2 coating and its properties for corrosion protection of metals[J]. Electrochimica Acta,2005,50(25-26):5083-5089.
【21】Liu T,Dong L,Liu T,et al. Investigations on reducing microbiologically-influenced corrosion of aluminum by using super-hydrophobic surfaces[J]. Electrochimica Acta,2010,55(18):5281-5285.
【22】王燕华,钟莲,刘圆圆,等. 镁基体超疏水表面制备及表征[J]. 腐蚀科学与防护技术,2010,22(4):329-332.
【23】Chen S,Chen Y,Lei Y,et al. Novel strategy in enhancing stability and corrosion resistance for hydrophobic functional films on copper surfaces[J]. Electrochemistry Communications,2009,11(8):1675-1679.
【24】Chen L,Thermophysics S L R Y,Sciences C A O,et al. n-Octadecanethiol self-assembled monolayer coating with microscopic roughness for dropwise condensation of steam[J]. Journal of Thermal Science,2009,18(2):160-165.
【25】Kang Z,Ye Q,Sang J,et al. Fabrication of super-hydrophobic surface on copper surface by polymer plating[J]. Journal of Materials Processing Technology,2009,209(9):4543-4547.
【26】Yin Y,Liu T,Chen S,et al. Structure stability and corrosion inhibition of super-hydrophobic film on aluminum in seawater[J]. Applied Surface Science,2008,255(5):2978-2984.
【27】Ishizaki T,Hieda J,Saito N,et al. Corrosion resistance and chemical stability of super-hydrophobic film deposited on magnesium alloy AZ31 by microwave plasma-enhanced chemical vapor deposition[J]. Electrochimica Acta,2010,55(23):7094-7101.
【28】Wang P,Qiu R,Zhang D,et al. Fabricated super-hydrophobic film with potentiostatic electrolysis method on copper for corrosion protection[J]. Electrochimica Acta,In Press,Accepted Manuscript.
【29】李松梅,周思卓,刘建华. 铝合金表面原位自组装超疏水膜层的制备及耐蚀性能[J]. 物理化学学报,2009,25(12):2581-2589.
【30】Yang H,Pi P,Cai Z,et al. Facile preparation of super-hydrophobic and super-oleophilic silica film on stainless steel mesh via sol-gel process[J]. Applied Surface Science,2010,256(13):4095-4102.
【31】Liu T,Chen S,Cheng S,et al. Corrosion behavior of super-hydrophobic surface on copper in seawater[J]. Electrochimica Acta,2007,52(28):8003-8007.
【32】Zhu H,Chen S,Chen Y,et al. Investigation of the corrosion resistance of n-tetradecanoic acid and its hybrid film with bis-silane on copper surface in seawater[J]. Journal of Molecular Structure,2009,928(1-3): 40-45.
【33】时士峰,蔡希宏,徐群杰. 疏水处理对白铜B30缓蚀作用的电化学研究[C]//2010年全国腐蚀电化学及测试方法学术会议论文集,杭州:2010.
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