Preparation and Corrosion Resistance of Amorphous Cr-C Alloy Coating
摘 要
以酒石酸为添加剂, 采用电沉积法制备了非晶态Cr-C合金镀层。用X射线衍射、扫描电子显微镜及能谱仪对镀层结构、形貌及成分进行表征, 并对镀层进行电化学耐腐蚀性测试。结果表明, 当酒石酸加入量为40 g/L时, 镀层的X射线衍射图出现非晶态的特征峰, 镀层表面平整、致密, 无裂纹和针孔, 与普通晶态Cr镀层相比, 非晶态Cr-C合金镀层具有更优良的耐腐蚀性能。
Abstract
Amorphous Cr-C alloy coating was prepared by electrodepositing in tartaric acid additive bath. The microstructure, composition and surface morphology of the coating were detected by X-ray diffraction, SEM and EDS, also the microhardness, electrochemical corrosion resistance of the coating were tested. The results showed that a broad diffraction peak appeared on the X-ray diffraction pattern, the coating had a smooth and dense surface without pinhole and crack when the dosage of tartaric acid was 40 g/L. Compared with conventional crystalline Cr coating, amorphous Cr-C alloy coating had better corrosion resistance.
中图分类号 TQ153.2
所属栏目 试验研究
基金项目 广东省教育部产学研结合项目(2009B090300185)
收稿日期 2011/6/10
修改稿日期
网络出版日期
作者单位点击查看
备注杨毕学, 硕士研究生,
引用该论文: YANG Bi-xue,JIE Xiao-hua,LI Guo-liang. Preparation and Corrosion Resistance of Amorphous Cr-C Alloy Coating[J]. Corrosion & Protection, 2012, 33(4): 304
共有人对该论文发表了看法,其中:
人认为该论文很差
人认为该论文较差
人认为该论文一般
人认为该论文较好
人认为该论文很好
参考文献
【1】关山, 张琦. 电镀铬的最新进展[J]. 材料保护, 2000, 33(3):1-3.
【2】高元成. 非晶态镀膜技术[J]. 材料保护, 1990, 23(1): 68-70.
【3】渡边澈. 非晶态电镀方法及应用[M]. 于维平, 李荻译. 北京: 北京航空航天大学出版社, 1992.
【4】Car B H, Douglas A A, Stevep J B, et al. A suface study of amorphous chromium films eletrodeposited from chromic acid solution, part I[J]. J Vac Sci Technol, 1986, A4(1): 26-30.
【5】何湘柱, 龚竹青, 蒋汉赢. 三价铬水溶液电镀非晶态铬工艺[J]. 中国有色金属学报, 1999, 9(3): 646-651.
【6】王先友, 蒋汉赢. 从三价铬镀液电沉积非晶态Cr-C镀层的研究[J]. 腐蚀与防护, 1995, 16(3):115-117.
【7】Tsai Rung-ywan, Wu Shltln-tyah. Influence of pulse plating on the crystal structure and orientation of chromiual[J]. J Electrochem Soc, 1991, 138(9): 2622-2626.
【8】Car B H, Austin L G, Herbert A L Jr, et al. A chacracterization study of amorphous chromium films eletrodeposited from chromic acid solution[J]. Appl Surf Sci, 1987, 28: 224-234.
【9】安百刚, 赵国鹏. 添加剂在电沉积非晶态Cr-C 合金工艺中的应用[J]. 腐蚀科学与防护技术, 2001, 13(3):180-181.
【10】王先友, 蒋汉赢, 郭炳昆. 非晶态铬镀层结构及其耐蚀性[J]. 中南工业大学学报, 1995, 6(26): 826-829.
【2】高元成. 非晶态镀膜技术[J]. 材料保护, 1990, 23(1): 68-70.
【3】渡边澈. 非晶态电镀方法及应用[M]. 于维平, 李荻译. 北京: 北京航空航天大学出版社, 1992.
【4】Car B H, Douglas A A, Stevep J B, et al. A suface study of amorphous chromium films eletrodeposited from chromic acid solution, part I[J]. J Vac Sci Technol, 1986, A4(1): 26-30.
【5】何湘柱, 龚竹青, 蒋汉赢. 三价铬水溶液电镀非晶态铬工艺[J]. 中国有色金属学报, 1999, 9(3): 646-651.
【6】王先友, 蒋汉赢. 从三价铬镀液电沉积非晶态Cr-C镀层的研究[J]. 腐蚀与防护, 1995, 16(3):115-117.
【7】Tsai Rung-ywan, Wu Shltln-tyah. Influence of pulse plating on the crystal structure and orientation of chromiual[J]. J Electrochem Soc, 1991, 138(9): 2622-2626.
【8】Car B H, Austin L G, Herbert A L Jr, et al. A chacracterization study of amorphous chromium films eletrodeposited from chromic acid solution[J]. Appl Surf Sci, 1987, 28: 224-234.
【9】安百刚, 赵国鹏. 添加剂在电沉积非晶态Cr-C 合金工艺中的应用[J]. 腐蚀科学与防护技术, 2001, 13(3):180-181.
【10】王先友, 蒋汉赢, 郭炳昆. 非晶态铬镀层结构及其耐蚀性[J]. 中南工业大学学报, 1995, 6(26): 826-829.
相关信息