活泼金属表面缓蚀自组装膜研究进展
Progress in Research of Self-assembled Monolayers for Corrosion Inhibition on Active Metal Surfaces
摘 要
金属表面缓蚀自组装膜技术是近年来发展起来的新型防腐蚀技术, 其研究对象已逐渐由惰性金属(金、铂等)转化为常用活性金属及合金材料。本文综述了常用活性金属表面缓蚀自组装膜技术的研究现状, 重点介绍了铜、铁、铝等金属材料表面涉及的缓蚀自组装体系, 并对该领域研究中存在的主要问题进行了总结。
缓蚀
活泼金属
self-assembled monolayer
corrosion inhibition
active metal
Abstract
Constructing self-assembled monolayers on metal surfaces for corrosion inhibition is a new kind of anticorrosion method developed in recent years. The research objects changed gradually from inert metals (such as gold and platinum) to common active metals and their alloys. In this paper, the progress in the research of self-assembled monolayers for corrosion inhibition on common active metals is reviewed, with emphasis on the mainly involved assembling systems for Cu, Fe and Al. And the main problems in this field are also summarized.
中图分类号 TG174 TG179
所属栏目 专论
基金项目 国家自然科学基金(No.51001045); 湖北省自然科学基金(No.2009CDB347)
收稿日期 2011/7/18
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联系人作者屈钧娥(qje@hubu.edu.cn)
备注屈钧娥, 讲师, 博士,
引用该论文: QU Jun-e,CHEN Geng,WANG Hai-ren,JIANG Yan,LI Wen-wei. Progress in Research of Self-assembled Monolayers for Corrosion Inhibition on Active Metal Surfaces[J]. Corrosion & Protection, 2012, 33(5): 357
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参考文献
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【2】崔维真. 成膜时间对十八硫醇ODT在铜表面自组装成膜的影响[J]. 沧州师范专科学校学报, 2004, 20(1):48-49.
【3】Fonder G, Laffineur F, Delhalle J, et al. Alkanethiol-oxidized copper interface:the critical influence of concentration[J]. J Colloid Interface Sci, 2008, 326(2):333-338.
【4】Sung M M, Sung K, Kim C G, et al. Self-assembled monolayers of alkanethiols on oxidized copper surfaces[J]. J Phys Chem B, 2000, 4: 2273-2277.
【5】Quan Z, Wu X, Zhao S, et al. Self-assembled monolayers of Schiff base on copper surface[J]. Corrosion, 2001, 57(3):195-201.
【6】全贞兰, 吴培强. 席夫碱自组装膜分子结构对Cu缓蚀性能的影响[J]. 青岛科技大学学报, 2005, 26(4): 283-286.
【7】Aramaki K. Protection of iron corrosion by ultrathin two-dimensionalpolymer film of an alkanethiol monolayer modified with alkylethoxysilanes[J]. Corrosion Science, 1999, 41(9):1715-1730.
【8】Taneichi D, Haneda R, Aramaki K. A novel modification of an alkanethiol self-assembled monolayer with alkylisocyanates to prepare protective films against copper corrosion[J]. Corrosion Science, 2001, 43(8):1589-1600.
【9】Guo W J, Chen S H, Huang B D, et al. Protection of self-assembled monolayers formed from triethyl phosphate and mixed self-assembled monolayers from triethyl phosphate and cetyltrimethyl ammonium bromide for copper against corrosion[J]. Electrochimica Acta, 2006, 52(1): 108-113.
【10】孔令平, 全贞兰. 植酸和钼酸钠自组装膜对铜表面的缓蚀作用[J]. 青岛科技大学学报, 2010, 31(2): 133-136.
【11】Volmer M, Reynders B, Stratmann M. Anbindungsverhalten organischer monomere auf eisenoberfl chen und korrosion der durch die anbindung chemisch modifizierten oberflchen[J]. Werkst Korros, 1991, 42(1):19-34.
【12】王静, 李德刚, 于先进, 等. 十二烷基硫醇在Fe表面自组装成膜及对其的腐蚀保护[J]. 中国腐蚀与防护学报, 2010, 30(3):207-212.
【13】Shustak G, Domb A J, Mandler D. Prepare and characterization of n-alkanoic acid self-assembled monolayers adsorbed on 316L stainless steel[J]. Langmuir, 2004, 20(18):7499-7506.
【14】Aramaki K, Shimura T. Protection of passivated iron against corrosion in a 0.1 M NaNO3 solution by coverage with an ultrathin polymer coating of carboxylate SAM[J]. Corrosion Science, 2009, 51(9):1887-1893.
【15】Aramaki K, Shimura T. An ultrathin polymer coating of carboxylate self-assembled monolayer adsorbed on passivated iron to prevent iron corrosion in 0.1 M Na2SO4 [J]. Corrosion Science, 2010, 52(1):1-6.
【16】Ramachandran S. Self-assembled monolayer mechanism for corrosion inhibition of iron by imidazolines[J]. Langmuir, 1996, 12(26):6419-6428.
【17】刘秀玉. 铁、不锈钢表面自组装膜的表征及其电化学研究[D]. 山东大学硕士学位论文, 2007:234-237.
【18】Raman A, Dubey M, Gouzman I. Formation of self-assembled monolayer s of alkylphosphonic acid on the native oxide surface of SS316L[J]. Langmuir, 2006, 22:6469-6472.
【19】郭文娟. 铜、铁表面组装磷酸酯类缓蚀功能分子膜实验技术的研究[D]. 山东大学硕士学位论文, 2007.
【20】Shimura T, Aramaki K. Additional modification to two-dimensional polymer films of a hydroxymethylbenzene self-assembled monolayer with alkyltriethoxysilanes for enhancing the protective abilities against iron corrosion[J]. Corrosion Science, 2008, 50(2):596-604.
【21】Nozawa K, Aramaki K. One-and two-dimensional polymer films of modified alkanethiol monolayers for preventing iron from corrosion[J]. Corrosion Science, 1999, 41(1):57-73.
【22】张哲. 贵金属纳米粒子及咪唑类化合物在铁表面自组装膜的研究[D]. 山东大学硕士学位论文, 2009.
【23】冯媛媛, 陈慎豪, 周娟娟, 等. 铁表面自组装缓蚀功能膜的电化学阻抗谱研究[J]. 电化学, 2008, 14(3): 343-346.
【24】Hintze P E, Calle L M. Electrochemical properties and corrosion protection of organosilane self-assembled monolayers on aluminum 2024-T3[J]. Electrochimica Acta, 2006, 51(8):1761-1766.
【25】郭增昌, 王云芳, 王汝敏. 铝合金表面自组装膜层的表征及耐蚀性研究[J]. 材料保护, 2007, 40(7):1-4.
【26】Frignani A, Zucchi F, Trabanelli G, et al. Protective action towards aluminium corrosion by silanes with a long aliphatic chain[J]. Corrosion Science, 2006, 48(8):2258-2273.
【27】Liakos I L, Newman R C, McAlpine E, et al. Study of the resistance of SAMs on aluminium to acidic and basic solutions using dynamic contact angle measurement[J]. Langmuir, 2007, 23:995-999.
【28】Reis F M, DeMelo H G, Costa I. EIS investigation on Al 5052 alloy surface preparation for self-assembling monolayer[J]. Electrochimica Acta, 2006, 51:1780-1788.
【29】王海人, 屈钧娥, 张强, 等. 膦酸自组装膜在铝合金表面的吸附及缓蚀行为[J]. 表面技术, 2011(1): 40-43.
【30】Foster T T, Alexander M R, Leggett G J, et al. Friction force microscopy of alkylphosphonic acid and carboxylic acids adsorbed on the native oxide of aluminum[J]. Langmuir, 2006, 22:9254.
【31】徐斌, 满瑞林, 倪网东, 等. 铝表面自组装分子及缓蚀剂复合膜的制备及耐蚀性能[J]. 腐蚀与防护, 2007, 28(10): 499-502.
【32】雍止一, 刘娅莉, 李智. 咪唑啉自组装单分子膜在镁合金AZ91D表面的防腐蚀研究[J]. 腐蚀科学与防护技术, 2006, 18(2):79-82.
【33】Liu Y L, Yu Z F, Zhou S X, et al. Self-assembled monolayers on magnesium alloy surfaces from carboxylate ions[J]. Appl Surf Sci, 2006, 252(10):3818-3827.
【34】Berger F, Delhalle J, Mekhalif Z. Self-assembled bilayers based on organothiol and organotrimethoxysilane on zinc platform[J]. Applied Surface Science, 2010, 256(23):7131-7137.
【35】乔建仙, 罗红群, 李明, 等. 尿酸自组装膜对镍缓蚀行为的影响[J]. 中国腐蚀与防护学报, 2009, 29(2):145-148.
【2】崔维真. 成膜时间对十八硫醇ODT在铜表面自组装成膜的影响[J]. 沧州师范专科学校学报, 2004, 20(1):48-49.
【3】Fonder G, Laffineur F, Delhalle J, et al. Alkanethiol-oxidized copper interface:the critical influence of concentration[J]. J Colloid Interface Sci, 2008, 326(2):333-338.
【4】Sung M M, Sung K, Kim C G, et al. Self-assembled monolayers of alkanethiols on oxidized copper surfaces[J]. J Phys Chem B, 2000, 4: 2273-2277.
【5】Quan Z, Wu X, Zhao S, et al. Self-assembled monolayers of Schiff base on copper surface[J]. Corrosion, 2001, 57(3):195-201.
【6】全贞兰, 吴培强. 席夫碱自组装膜分子结构对Cu缓蚀性能的影响[J]. 青岛科技大学学报, 2005, 26(4): 283-286.
【7】Aramaki K. Protection of iron corrosion by ultrathin two-dimensionalpolymer film of an alkanethiol monolayer modified with alkylethoxysilanes[J]. Corrosion Science, 1999, 41(9):1715-1730.
【8】Taneichi D, Haneda R, Aramaki K. A novel modification of an alkanethiol self-assembled monolayer with alkylisocyanates to prepare protective films against copper corrosion[J]. Corrosion Science, 2001, 43(8):1589-1600.
【9】Guo W J, Chen S H, Huang B D, et al. Protection of self-assembled monolayers formed from triethyl phosphate and mixed self-assembled monolayers from triethyl phosphate and cetyltrimethyl ammonium bromide for copper against corrosion[J]. Electrochimica Acta, 2006, 52(1): 108-113.
【10】孔令平, 全贞兰. 植酸和钼酸钠自组装膜对铜表面的缓蚀作用[J]. 青岛科技大学学报, 2010, 31(2): 133-136.
【11】Volmer M, Reynders B, Stratmann M. Anbindungsverhalten organischer monomere auf eisenoberfl chen und korrosion der durch die anbindung chemisch modifizierten oberflchen[J]. Werkst Korros, 1991, 42(1):19-34.
【12】王静, 李德刚, 于先进, 等. 十二烷基硫醇在Fe表面自组装成膜及对其的腐蚀保护[J]. 中国腐蚀与防护学报, 2010, 30(3):207-212.
【13】Shustak G, Domb A J, Mandler D. Prepare and characterization of n-alkanoic acid self-assembled monolayers adsorbed on 316L stainless steel[J]. Langmuir, 2004, 20(18):7499-7506.
【14】Aramaki K, Shimura T. Protection of passivated iron against corrosion in a 0.1 M NaNO3 solution by coverage with an ultrathin polymer coating of carboxylate SAM[J]. Corrosion Science, 2009, 51(9):1887-1893.
【15】Aramaki K, Shimura T. An ultrathin polymer coating of carboxylate self-assembled monolayer adsorbed on passivated iron to prevent iron corrosion in 0.1 M Na2SO4 [J]. Corrosion Science, 2010, 52(1):1-6.
【16】Ramachandran S. Self-assembled monolayer mechanism for corrosion inhibition of iron by imidazolines[J]. Langmuir, 1996, 12(26):6419-6428.
【17】刘秀玉. 铁、不锈钢表面自组装膜的表征及其电化学研究[D]. 山东大学硕士学位论文, 2007:234-237.
【18】Raman A, Dubey M, Gouzman I. Formation of self-assembled monolayer s of alkylphosphonic acid on the native oxide surface of SS316L[J]. Langmuir, 2006, 22:6469-6472.
【19】郭文娟. 铜、铁表面组装磷酸酯类缓蚀功能分子膜实验技术的研究[D]. 山东大学硕士学位论文, 2007.
【20】Shimura T, Aramaki K. Additional modification to two-dimensional polymer films of a hydroxymethylbenzene self-assembled monolayer with alkyltriethoxysilanes for enhancing the protective abilities against iron corrosion[J]. Corrosion Science, 2008, 50(2):596-604.
【21】Nozawa K, Aramaki K. One-and two-dimensional polymer films of modified alkanethiol monolayers for preventing iron from corrosion[J]. Corrosion Science, 1999, 41(1):57-73.
【22】张哲. 贵金属纳米粒子及咪唑类化合物在铁表面自组装膜的研究[D]. 山东大学硕士学位论文, 2009.
【23】冯媛媛, 陈慎豪, 周娟娟, 等. 铁表面自组装缓蚀功能膜的电化学阻抗谱研究[J]. 电化学, 2008, 14(3): 343-346.
【24】Hintze P E, Calle L M. Electrochemical properties and corrosion protection of organosilane self-assembled monolayers on aluminum 2024-T3[J]. Electrochimica Acta, 2006, 51(8):1761-1766.
【25】郭增昌, 王云芳, 王汝敏. 铝合金表面自组装膜层的表征及耐蚀性研究[J]. 材料保护, 2007, 40(7):1-4.
【26】Frignani A, Zucchi F, Trabanelli G, et al. Protective action towards aluminium corrosion by silanes with a long aliphatic chain[J]. Corrosion Science, 2006, 48(8):2258-2273.
【27】Liakos I L, Newman R C, McAlpine E, et al. Study of the resistance of SAMs on aluminium to acidic and basic solutions using dynamic contact angle measurement[J]. Langmuir, 2007, 23:995-999.
【28】Reis F M, DeMelo H G, Costa I. EIS investigation on Al 5052 alloy surface preparation for self-assembling monolayer[J]. Electrochimica Acta, 2006, 51:1780-1788.
【29】王海人, 屈钧娥, 张强, 等. 膦酸自组装膜在铝合金表面的吸附及缓蚀行为[J]. 表面技术, 2011(1): 40-43.
【30】Foster T T, Alexander M R, Leggett G J, et al. Friction force microscopy of alkylphosphonic acid and carboxylic acids adsorbed on the native oxide of aluminum[J]. Langmuir, 2006, 22:9254.
【31】徐斌, 满瑞林, 倪网东, 等. 铝表面自组装分子及缓蚀剂复合膜的制备及耐蚀性能[J]. 腐蚀与防护, 2007, 28(10): 499-502.
【32】雍止一, 刘娅莉, 李智. 咪唑啉自组装单分子膜在镁合金AZ91D表面的防腐蚀研究[J]. 腐蚀科学与防护技术, 2006, 18(2):79-82.
【33】Liu Y L, Yu Z F, Zhou S X, et al. Self-assembled monolayers on magnesium alloy surfaces from carboxylate ions[J]. Appl Surf Sci, 2006, 252(10):3818-3827.
【34】Berger F, Delhalle J, Mekhalif Z. Self-assembled bilayers based on organothiol and organotrimethoxysilane on zinc platform[J]. Applied Surface Science, 2010, 256(23):7131-7137.
【35】乔建仙, 罗红群, 李明, 等. 尿酸自组装膜对镍缓蚀行为的影响[J]. 中国腐蚀与防护学报, 2009, 29(2):145-148.
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