304不锈钢表面直流磁控溅射钛膜的耐蚀性
Corrosion-resistance of Ti Coating Prepared on 304 Stainless Steel Substrate by DC Magnetron Sputtering
摘 要
采用直流磁控溅射的方法在304不锈钢表面上制备金属钛薄膜, 溅射5 min后, 通过扫描电镜(SEM)观察薄膜厚度为15 μm。对比研究了304不锈钢镀膜前和镀膜后在FeCl3溶液中的腐蚀速率, 通过显微镜观察两者在腐蚀之后的组织形貌, 结果表明,通过在表面制备金属膜的方法(镀膜时间至少5 min)可以有效提高304不锈钢在氯离子环境下的耐腐蚀性能。
直流磁控溅射
氯离子
腐蚀速率
304 stainless steel
DC magnetron sputtering
chloride ion
corrosion rate
Abstract
A Ti thin film on the surface of 304 stainless steel was prepared by DC magnetron sputtering. The film thickness could have 15 μm after sputtering for 5 min. The corrosion rate in FeCl3 environment was compared and studied between 304 stainless steel before coating and after coating. The microstructure morphology after corrosion was observed by microscopic examination. The corrosion resistance of 304 stainless steel in chloride environment was effectively improved by the Ti thin film on the surface of 304 stainless steel prepared by DC magnetron sputtering for at least 5 min.
中图分类号 TG174.444
所属栏目 应用技术
基金项目 江苏省精密与微细制造技术重点实验室开放基金(JSPM200705); 扬州大学科技创新基金(No.200809)
收稿日期 2011/8/7
修改稿日期
网络出版日期
作者单位点击查看
备注陈荣发,教授,博士,
引用该论文: PAN Yi,CHEN Rong-fa,ZHANG Xian-liang,LIU Tao,WU Long,YANG Hua,LI Qing-qing. Corrosion-resistance of Ti Coating Prepared on 304 Stainless Steel Substrate by DC Magnetron Sputtering[J]. Corrosion & Protection, 2012, 33(6): 525
共有人对该论文发表了看法，其中：
人认为该论文很差
人认为该论文较差
人认为该论文一般
人认为该论文较好
人认为该论文很好
参考文献
【1】赵晶晶, 黄莉, 胡学文. 热力机组炉内氯离子的腐蚀机理及其防止对策[J]. 腐蚀与防护, 2004, 25(2): 65-68.
【2】吕国诚, 许淳淳, 程海东. 304不锈钢应力腐蚀的临界氯离子浓度[J]. 化工进展, 2008,27(8): 1284-1287.
【3】Rossi S, Fedrizzi L, Leoni M, et al. (Ti,Cr)N and Ti/TiN PVD coatings on 304 stainless steel substrates:wear-corrosion behaviour[J]. Thin Solid Films,1999,350: 161-167.
【4】Liu C L, Lin G Q, Yang D Z, et al. In vitro corrosion behavior of multilayered Ti/TiN coating on biomedical AISI 316L stainless steel[J]. Surface ﹠ Coatings Technology, 2006,200: 4011-4016.
【5】肖正伟, 曾振欧, 赵国鹏, 等. 304不锈钢上纳米TiO2涂层的制备与防腐性能研究[J]. 电镀与涂饰, 2007,26(7): 35-38.
【6】李涛. 磁控溅射锑镱薄膜的制备与表面形貌的研究[D]. 杭州: 浙江大学硕士学位论文, 2010.
【7】李久青, 杜翠薇. 腐蚀试验方法及检测技术[M]. 中国石化出版社, 2007: 17-18, 90-91.
【8】Karimi M V,Sinha S K,Kothari D C, et al. Effect of ion implantation on corrosion resistance and high temperature oxidation resistance of Ti deposited 316 stainless steel[J]. Surface ﹠ Coatings Technology,2002: 158-159,609-614.
【2】吕国诚, 许淳淳, 程海东. 304不锈钢应力腐蚀的临界氯离子浓度[J]. 化工进展, 2008,27(8): 1284-1287.
【3】Rossi S, Fedrizzi L, Leoni M, et al. (Ti,Cr)N and Ti/TiN PVD coatings on 304 stainless steel substrates:wear-corrosion behaviour[J]. Thin Solid Films,1999,350: 161-167.
【4】Liu C L, Lin G Q, Yang D Z, et al. In vitro corrosion behavior of multilayered Ti/TiN coating on biomedical AISI 316L stainless steel[J]. Surface ﹠ Coatings Technology, 2006,200: 4011-4016.
【5】肖正伟, 曾振欧, 赵国鹏, 等. 304不锈钢上纳米TiO2涂层的制备与防腐性能研究[J]. 电镀与涂饰, 2007,26(7): 35-38.
【6】李涛. 磁控溅射锑镱薄膜的制备与表面形貌的研究[D]. 杭州: 浙江大学硕士学位论文, 2010.
【7】李久青, 杜翠薇. 腐蚀试验方法及检测技术[M]. 中国石化出版社, 2007: 17-18, 90-91.
【8】Karimi M V,Sinha S K,Kothari D C, et al. Effect of ion implantation on corrosion resistance and high temperature oxidation resistance of Ti deposited 316 stainless steel[J]. Surface ﹠ Coatings Technology,2002: 158-159,609-614.
相关信息
