表面超疏水性处理在锅炉安全阀防腐蚀、防垢技术中的应用
Application of Super-hydrophobic Surface Modification to Anti-rust and Anti-scaling of Boiler Safety Valves
摘 要
介绍了表面超疏水特性的原理, 及其对锅炉安全阀表面防腐蚀、防垢的作用。介绍了几种可以对锅炉安全阀表面进行超疏水性处理技术。并指出了当前超疏水表面制备技术存在的问题和发展方向。
安全阀
防腐
除垢
super-hydrophobic surface
safety valve
anti-rust
anti-scaling
Abstract
This paper introduces the characteristics of the super-hydrophobic surface and its role in surface anti-corrosion and anti-scaling. Several techniques which could modify the boiler safety valve surface as a super-hydrophobic surface are illustrated. The problems and prospects of the super-hydrophobic surface preparation techniques are also discussed.
中图分类号 TG174 TG178
所属栏目 应用技术
基金项目
收稿日期 2011/12/23
修改稿日期
网络出版日期
作者单位点击查看
备注余爱枝,助理工程师,硕士,
引用该论文: YU Ai-zhi,LI Mao-dong,LIN Jin-mei,ZHANG Shu-kuan. Application of Super-hydrophobic Surface Modification to Anti-rust and Anti-scaling of Boiler Safety Valves[J]. Corrosion & Protection, 2012, 33(6): 528
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参考文献
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【21】李松梅,王勇干,刘建华,等. 铝合金表面超疏水涂层的制备及其耐蚀性能[J]. 物理化学学报,2007,23(10):1631-1636.
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【23】Shang H M,Takai O. Preparation of silicon oxide films having a water-repellentlayer[J]. Thin Solid Films,1998(16):54-59.
【24】张友法,余新泉,陈锋,等. 高速微米颗粒冲击法制备超疏水金属表面[J]. 金属制品,2010,36(3):31-35.
【25】胡彩花,王学魁,孙之南,等. 紫铜为基材用化学复合镀法制备Ni-P-聚四氟乙烯疏水性膜[J]. 化学工程,2009(1):25-30.
【2】Neinhuis C,Barthlott W. Characterization and distribution of water-repellent,self-cleaning plant surfaces[J]. Annals of Botany,1997,79(6):667-677.
【3】Marmur A. The lotus effect:Superhydrophobicity and metastability[J]. Langmuir,2004,20(9):3517-3519.
【4】Extrand C W. Model for contact angles and hysteresis on rough and ultraphobic surfaces[J]. Langmuir,2002,18(21):7991-7999.
【5】Wang H,Tang L M,Wu X M,et al. Brication and anti-frosting performance of super hydrophobic coating based on modified nano-sized calcium carbonate and ordinary polyacrylate[J]. Applied Surface Science,2007,253:8818-8824.
【6】翟锦,李欢军,李英顺,等. 碳纳米管阵列超双疏性质的发现[J]. 物理,2002,31(8):483-486.
【7】Onda T,Shibuichi S,Satoh N,et al. Super-water-repellent fractal surfaces[J]. Langmuir,1996,12:2125-2127.
【8】Veeramasuneni S,Drelich J,Miller J D,et al. Hydrophobicity of ion-plated PTFE coatings[J]. Prog.Org.Coat.,1997,31:265-270.
【9】Hozumi A,Takai O. Preparation of ultra water-repellent films by microwave plasma-enhanced CVD[J]. Thin Solid Films,1997,303:222-225.
【10】Wu W,Wang X,Liu X. Spray-coated fluorine-free superhydrophobic coatings with easy repairability and applicability[J]. Applied Materials and Interfaces,2009,1(8) :1656-1661.
【11】王浩,王昌松,陈颖,等. PTFE-PPS复合超疏水涂层的制备与表征[J]. 过程工程学报,2007,7(3):624-627.
【12】Xu Q F,Wang J N,Smith I H,et al. Superhydrophobic and transparent coatings based on removable polymeric spheres[J]. Journal of Materials Chemistry,2009,19(5):655-660.
【13】Xi W J,Qiao Z M,Zhu C L. The preparation of lotus-like super-hydrophobic copper surfaces by electroplating[J]. Applied Surface Science,2009,255(8):4836-4839.
【14】Wang S T,Feng L,Jiang L. One-step solution-immersion process for the fabrication of stable bionic superhydrophobic surfaces[J]. Advanced Materials,2006,18(6):767-770.
【15】潘立宁,董慧茹,毕鹏禹. SDBS/HCl化学刻蚀法制备具有纳米-微米混合结构的铝基超疏水表面[J]. 高等学校化学学报,2009,30(7):137l-l374.
【16】Qian B T,Shen Z Q. Fabrication of superhydrophobic surfaces by dislocation-selective chemical etching on aluminum,copper,and zinc substrates[J]. Langmuir,2005,21:9007-9009.
【17】李艳峰,于志家,于跃飞,等. 铝合金基体上超疏水表面的制备[J]. 高校化学工程学报,2008,22(1):6-10.
【18】Guo Z G,Zhou F,Hao J C,et al. Stable biomimetic superhydrophobic engineering materials[J]. Journal of the American Chemical Society,2005,127(45):15670-15671.
【19】李康宁,余新泉,周荃卉. 铝基超疏水表面的耐海水腐蚀性能研究[J]. 纳米科技,2008,5:43- 47.
【20】周荃卉,余新泉,张友法,等. 喷砂-阳极氧化-氟化处理构筑铝合金超疏水表面[J]. 高等学校化学学报,2010,31(3):456-462.
【21】李松梅,王勇干,刘建华,等. 铝合金表面超疏水涂层的制备及其耐蚀性能[J]. 物理化学学报,2007,23(10):1631-1636.
【22】Han J T,Zheng Y,Cho J H,et al. Stable superhydrophobic organic-inorganic hybrid films by electrostatic self-assembly[J]. Journal of Physical Chemistry Bulletin,2005,109(44):20773-20778.
【23】Shang H M,Takai O. Preparation of silicon oxide films having a water-repellentlayer[J]. Thin Solid Films,1998(16):54-59.
【24】张友法,余新泉,陈锋,等. 高速微米颗粒冲击法制备超疏水金属表面[J]. 金属制品,2010,36(3):31-35.
【25】胡彩花,王学魁,孙之南,等. 紫铜为基材用化学复合镀法制备Ni-P-聚四氟乙烯疏水性膜[J]. 化学工程,2009(1):25-30.
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