医用Ti6Al4V合金表面改性研究进展
Research Progress in Surface Modification of Biomedical Ti6Al4V Alloy
摘 要
Ti6Al4V合金因具有优异的力学性能和良好的生物相容性而被广泛应用于人体硬组织替代物和修复物领域。由于合金本身耐摩擦磨损性差, 不具备生物活性等缺点, 因此对Ti6Al4V合金进行表面改性具有重要意义。本文介绍对Ti6Al4V合金进行改性的有效方法, 综述了其表面改性的研究进展, 展望了表面改性的发展趋势。
表面改性
研究进展
趋势
Ti6Al4V alloy
surface modification
research achievement
trend
Abstract
Ti6Al4V alloy is extensively applied in the field of the replacement and restoration for surgical implants owning to its excellent mechanical performance and good biocompatibility. However, because of the poor wear resistance, bio-activity and so on, it is really important to modify the surface of Ti6Al4V alloy. This paper introduces the effective methods to improve the properties, and summarizes the research achievement of surface modification. The development trend of surface modification is prospected.
中图分类号 TG178
所属栏目 专论
基金项目 国家自然科学基金项目(No.51175212)
收稿日期 2011/9/13
修改稿日期
网络出版日期
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引用该论文: XIA Mu-jian,ZHANG Yue,ZHOU Guang-hong,DING Hong-yan. Research Progress in Surface Modification of Biomedical Ti6Al4V Alloy[J]. Corrosion & Protection, 2012, 33(8): 645
被引情况:
【1】王娅婷,林乃明,唐宾, "钛及钛合金热氧化工艺的研究现状",腐蚀与防护 35, 965-970(2014)
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参考文献
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【2】Molinari A, Straffelini Q, Tesi B, et al. Dry sliding wear mechanism of the Ti6A14V alloy[J]. Wear, 1997, 208(1/2): 105-112.
【3】Rieu J, Pichat A, Rabbe L M, et al. Structural modification induced by ion implantation in metals and polymers used for orthopaedic prostheses[J]. Journal of Materials Science & Technology, 1992, 8(7): 589-593.
【4】Niinomi M. Biologically and mechanically biocompatible titanium alloys[J]. Materials Transactions, 2008, 49(10): 2170-2178.
【5】Tatiani A G Donato, Luciano H de Almeida, Renata A Nogueira, et al. Cytotoxicity study of some Ti alloys used as biomaterial[J]. Materials Science and Engineering C, 2009, 29(4): 1365-1369.
【6】刘恒全, 张勇, 强华, 等. 医用钛合金在体内的抗蚀性能及其影响因素[J]. 腐蚀与防护, 2007, 28(11): 595-597.
【7】Ping D H, Cui C Y, Yin F X, et al. TEM investigations on martensite in a Ti-Nb-based shape memory alloy[J]. Scripta Materialia, 2006, 54(7): 1305-1310.
【8】Chai Y W, Kim H Y, Hosoda H, et al. Self-accommodation in Ti-Nb-based shape memory alloy[J]. Acta Materialia, 2009, 57(14): 4054-4064.
【9】Hao Y L, Li S J, Sun S Y, et al. Elastic deformation behaviour of Ti-24Nb-4Zr-7.9Sn for biomedical applications[J]. Acta Biomater, 2007, 3(2): 277-286.
【10】Tane M, Akita S, Nakano T. Peculiar elastic behavior of Ti-Nb-Ta-Zr single crystals[J]. Acta Materialia, 2008, 56(12): 2856-2863.
【11】郭爱红, 崔文芳, 刘向宏, 等. 新型医用TiNbZrFe合金的组织和力学性能[J]. 材料与冶金学报, 2008, 7(4): 288-292.
【12】于志伟, 谈国强. 溶胶-凝胶法制备薄膜[J]. 陶瓷, 2006(10): 39-42.
【13】Ming-Fa Hsieh, Li-Hsiang Perng, Tsung-Shune Chin. Hydroxyapatite coating on Ti6Al4V alloy using a sol-gel derived precursor[J]. Materials Chemistry and Physics, 2002, 74(3): 245-250.
【14】刘颖, 张文光. 钛合金表面TiO2图案化薄膜的溶胶凝胶法制备及其性能研究[J]. 医用生物力学, 2010, 25(1): 21-25.
【15】洪海云, 陈贻炽, 朱立群. 钛基体上氧化铝膜层的耐高温和耐腐蚀性能研究[J]. 材料保护, 2005, 38(6): 18-20.
【16】黄立业, 徐可为, 吕坚, 等. 生物医用类金刚石薄膜的力学性能评价[J]. 稀有金属材料与工程[J]. 2001, 30(5): 357-360.
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【18】林东洋, 赵玉涛, 甘俊旗, 等. 钛合金表面磁控溅射制备HA/YSZ梯度涂层[J]. 材料工程, 2008(5): 34-38.
【19】Zhao Y T, Zhang Z, Dai Q X, et al. Microstructure and bond strength of HA(+ZrO2+Y2O3)/Ti6Al4V composite coatings fabricated by RF magnetron sputtering[J]. Surface and Coatings Technology, 2006, 200(1/4): 5354-5363.
【20】Long J D, Xu S, Cai J W, et al. Structure, bonding state and in-vitro study of Ca-P-Ti film deposited on Ti6Al4V by RF magnetron sputtering[J]. Materials Science and Engineering: C, 2002, 20(1/2): 175-180.
【21】王亚明, 蒋百灵, 雷廷权, 等. Na2SiO3系溶液Ti6A14V微弧氧化陶瓷膜的结构与力学性能[J]. 稀有金属材料与工程, 2004, 33(5): 502-506.
【22】Vangolu Y, Alsaran A, Yildirim O S. Wear properties of micro arc oxidized and hydrothermally treated Ti6Al4V alloy in simulated body fluid[J]. Wear, 2011, 271(9/10): 2322-2327.
【23】王庆良, 葛世荣, 史兴岭. 钛合金微弧氧化陶瓷层的结构研究[J]. 中国矿业大学学报, 2008, 37(4): 462-466.
【24】邓迟, 张亚平, 高家诚. 激光熔覆生物陶瓷涂层和界面的研究[J]. 应用激光, 2006, 26(1): 21-22.
【25】朱维东, 田博, 高雷电. 钛合金表面沉积AlTiN涂层的生物摩擦磨损特性研究[J]. 现代生物医学进展, 2008, 8(2): 267-269.
【26】王钧石, 晏永华, 陈桂容. 钛合金等离子体源离子注入表面改性[J]. 稀有金属, 2006, 30(5): 582-585.
【27】冷崇燕, 张旭, 周荣, 等. Ta离子注入Ti6Al4V合金耐磨性研究[J]. 稀有金属材料与工程, 2008, 37(3): 556-560.
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