镀锌钢板钝化工艺研究进展
Progress in Research of Passivation for Galvanized Steel
摘 要
镀锌处理是提高钢板耐蚀性能的主要方法, 但锌在多种环境中都易发生腐蚀, 为了提高镀锌钢板的表面质量, 减慢镀锌层的腐蚀速率, 延长其使用寿命, 镀锌层表面需钝化处理。本文综述了镀锌钢板钝化工艺的研究进展, 论述了常规钝化和无铬钝化的发展和研究现状, 重点介绍了无铬钝化的有机和无机处理工艺, 对不同处理工艺的优点及存在问题进行了简述, 并展望了镀锌钢板钝化技术的发展趋势。
钝化工艺
研究进展
galvanized steel
passivation technology
research progress
Abstract
Zinc plating is a main method for improving the corrosion resistance of steel plates. But in various environments, zinc is easy to be corroded. In order to increase the surface quality of galvanized steel, to slow down the corrosion rate of zinc coating and to, extend the service life, the passivation treatment is needed. In this paper, the progress in research of passivation for galvanized steel is summarized firstly. The development and current application of conventional passivation and chromium-free passivation are discussed secondly. Then the chromium-free passivation of organic and inorganic treatment processes are introduce. The advantages and existing problems of different treatment technologies are presented. The development tendency of passivation technology is also evaluated.
中图分类号 TG178
所属栏目 专论
基金项目
收稿日期 2011/12/5
修改稿日期
网络出版日期
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联系人作者刘小风(caoxxyu@126.com)
备注刘小风, 讲师, 硕士,
引用该论文: LIU Xiao-feng,CAO Xiao-yan. Progress in Research of Passivation for Galvanized Steel[J]. Corrosion & Protection, 2012, 33(11): 997
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参考文献
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【20】龙晋明, 韩夏云, 杨宁, 等. 锌和镀锌钢的稀土表面改性[J]. 稀土, 2003, 24(5): 52-56.
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【23】韩利华, 康 举, 张学丽. 镀锌板铈钼复合成膜工艺及其耐蚀性能[J]. 腐蚀与防护, 2010, 31(5): 376-379.
【24】梁永煌, 满瑞林, 吴文彪. 稀土铈盐、镧盐钝化镀锌钢板表面性能对比[J]. 腐蚀与防护, 2009, 30(12):892-895.
【25】Yang H F, Feng J, Liu Y L, et al. Electrochemical and surface enhanced Raman scattering spectroelectrochemical study of phytic acid on silver electrode[J]. Journal of Physical Chemistry B, 2004, 108(45):17412-17417.
【26】Liu J R, Guo Y N, Huang W D. Study on the corrosion resistance of phytic acid conversion coating for magnesium alloys[J]. Surface & Coatings Technology, 2006, 201(3):1536-1541.
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【28】朱传方, 胡腊生. 植酸在镀锌钝化中的应用[J]. 精细化工, 1995, 12(5): 54-58.
【29】Manov S, Lamazouere A M, Aries L. Electrochemicalstudy of zinc traded with a new organic chelating inhibitor[J]. Corrosion Science, 2000, 42(5):1235-1248.
【30】周金宝. 镀锌层无铬钝化工艺的新进展[J]. 电镀与环保, 1991, 11(5): 7.
【31】方景礼, 王济奎. 镀锌层表面H4PMo11VO40杂多酸转化膜的研究[J]. 表面技术, 1996, 25(4): 15-16.
【32】龚浩, 徐瑞芬. 有机钼酸盐MDTA对碳钢的缓蚀作用和机理[J]. 腐蚀与防护, 1999, 20(2): 62-65.
【33】Zhu D Q, Van Ooij W J. Corrosion protection of metal by water-based silane mixtures of bis-[trimethoxysilylpropyl]amine and vinyltriacetoxysilane[J]. Progress in Organic Coatings, 2004, 49(1):42-45.
【34】Zucchi F, Grassi V, Frignani A, et al. Inhibition of copper corrosion by silane coatings[J]. Corrosion Science, 2004, 46(11):2853-2865.
【35】Cabral A M, Duarte R G, Montemor M F, et al. A comparative study on the corrosion resistance of AA224-T3 substrates pre-treated with different silane solutions-composition of the films formd[J]. Progress in Organic Coatings, 2005, 54(4):322-331.
【36】Trabelsi W, Triki E, Dhouibi L, et al. The use of pre-treatments based on doped silane solutions for improved corrosion resistance of galvanized steel substrates[J]. Surface and Coatings Technology, 2006, 200(14):4240-4250.
【37】Bexell U, Gtehk T M. A corrosion study of hot-dip galvanized steel sheet pre-treated with gamma-mereaptopropyltrimethoxy silane[J]. Surface and Coatings Technology, 2007, 201(8):4734-4742.
【38】吴海江, 卢锦堂. 热镀锌钢板表面硅烷膜的制备工艺与耐蚀性能[J]. 机械工程材料, 2009, 33(7): 52-55, 60.
【39】徐斌, 满瑞林, 曹晓燕, 等. 镀锌钢板的硅烷表面改性[J]. 腐蚀科学与防护技术, 2008, 20(2): 130-134.
【40】易德莲, 王静, 李宇鹏, 等. 镀锌板的复合钝化[J]. 腐蚀与防护, 2010, 32(2): 142-145.
【2】彭玉田. 新型镀锌钝化工艺[J]. 电镀与涂饰, 2004, 23(6): 15-16.
【3】卢燕平, 屈祖玉. 镀锌层低铬钝化膜的改性与耐蚀性研究[J]. 材料保护, 2003, 36(4): 35-37.
【4】曾振欧, 邹锦光, 赵国鹏, 等. 镀锌层三价铬与六价铬钝化膜的性能[J]. 华南理工大学学报(自然科学版), 2007, 35(5): 104-108.
【5】任艳萍, 陈锦红. 镀锌层三价铬钝化膜腐蚀行为的研究[J]. 材料保护, 2007, 40(2): 7-10.
【6】Lin B L, Lu J T, Kong G. Effect of molybdate post-sealing on the corrosion resistance of zinc phosphate coatings on hot-dip galvanized steel[J]. Corrosion Science, 2008, 50(4):962-967.
【7】Lin B L, Lu J T, Kong G, et al. Growth and corrosion resistance of molybdate modified zinc phosphate conversion coatings on hot-dip galvanized steel[J]. Transactions of Nonferrous Metals Society of China, 2007, 17:755-761.
【8】卢锦堂, 孔纲. 热镀Zn层钼酸盐钝化工艺[J]. 腐蚀科学与防护技术, 2001, 13(1): 46-48.
【9】Tang P T, Bech-Nielsen G, Moller P. Molybdate based passivation of zinc[J]. Transactions of the Institute of Metal Finishing, 1997, 75(4):144-148.
【10】宫丽, 卢琳, 卢燕平. 薄型无铬有机复合涂层钢板耐蚀性的研究[J]. 材料保护, 2008, 41(2): 68-71.
【11】Cowieson D R, Scholefield A R. Passivation of tin-zinc alloy[J]. Transactions of the Institute of Metal Finishing, 1985, 63(2):56-58.
【12】钱余海, 戴毅刚, 陈红星. 镀锌(合金)钢板无/低铬钝化技术研究状况[J]. 腐蚀科学与防护技术, 2004, 16(4): 222-225.
【13】张静双, 夏保佳, 屠振密. 锡-锌合金镀层的无铬和低铬钝化[J]. 电镀与精饰, 2002, 24(3): 88-92.
【14】周全保. 镀锌层无铬钝化新工艺-硅酸盐处理[J]. 腐蚀与防护, 1991, 12(1): 33-35.
【15】Hara M, Ichino R, Okido M, et al. Corrosion protection property of colloidal silicate film on galvanized steel[J]. Surface & Coatings Technology, 2003, 169:679-681.
【16】Xu Y Y, Lin B L. Effect of silicate pretreatment, post-sealing and additives on corrosion resistance of phosphated galvanized steel[J]. Transactions of Nonferrous Metals Society of China, 2007, 17(6):1248-1253.
【17】韩克平, 叶向荣. 镀锌层表面硅酸盐防腐膜的研究[J]. 腐蚀科学与防护技术, 1997, 9(2): 167-170.
【18】Hinton B R W, Wilson L. The corrosion inhibition of zinc with cerous chloride[J]. Corrosion Science, 1989, 29(8):967-985.
【19】Roman L, Bilidariu M, Cristescu C. Study of conversion coating on zinc of deposition obtained from low pollution solutions[J]. Transactions of the Institute of Metal Finishing, 1997, 75(5):171-176.
【20】龙晋明, 韩夏云, 杨宁, 等. 锌和镀锌钢的稀土表面改性[J]. 稀土, 2003, 24(5): 52-56.
【21】许乔瑜, 曾秋红. 稀土在锌镀层中的应用及研究进展[J]. 腐蚀与防护, 2009, 30(1): 19-21.
【22】彭天兰, 满瑞林, 徐斌. 镀锌钢板表面耐腐蚀稀土镧盐转化膜的制备[J]. 涂料工业, 2008, 31(11): 51-53, 58.
【23】韩利华, 康 举, 张学丽. 镀锌板铈钼复合成膜工艺及其耐蚀性能[J]. 腐蚀与防护, 2010, 31(5): 376-379.
【24】梁永煌, 满瑞林, 吴文彪. 稀土铈盐、镧盐钝化镀锌钢板表面性能对比[J]. 腐蚀与防护, 2009, 30(12):892-895.
【25】Yang H F, Feng J, Liu Y L, et al. Electrochemical and surface enhanced Raman scattering spectroelectrochemical study of phytic acid on silver electrode[J]. Journal of Physical Chemistry B, 2004, 108(45):17412-17417.
【26】Liu J R, Guo Y N, Huang W D. Study on the corrosion resistance of phytic acid conversion coating for magnesium alloys[J]. Surface & Coatings Technology, 2006, 201(3):1536-1541.
【27】Xing W T, You B, Wu L M. The microstructure and anticorrosion performance of phytic acid-catalyzed polysilsesquioxane coatings[J]. Journal of Sol-Gel Science and Technology, 2007, 42(2):187-195.
【28】朱传方, 胡腊生. 植酸在镀锌钝化中的应用[J]. 精细化工, 1995, 12(5): 54-58.
【29】Manov S, Lamazouere A M, Aries L. Electrochemicalstudy of zinc traded with a new organic chelating inhibitor[J]. Corrosion Science, 2000, 42(5):1235-1248.
【30】周金宝. 镀锌层无铬钝化工艺的新进展[J]. 电镀与环保, 1991, 11(5): 7.
【31】方景礼, 王济奎. 镀锌层表面H4PMo11VO40杂多酸转化膜的研究[J]. 表面技术, 1996, 25(4): 15-16.
【32】龚浩, 徐瑞芬. 有机钼酸盐MDTA对碳钢的缓蚀作用和机理[J]. 腐蚀与防护, 1999, 20(2): 62-65.
【33】Zhu D Q, Van Ooij W J. Corrosion protection of metal by water-based silane mixtures of bis-[trimethoxysilylpropyl]amine and vinyltriacetoxysilane[J]. Progress in Organic Coatings, 2004, 49(1):42-45.
【34】Zucchi F, Grassi V, Frignani A, et al. Inhibition of copper corrosion by silane coatings[J]. Corrosion Science, 2004, 46(11):2853-2865.
【35】Cabral A M, Duarte R G, Montemor M F, et al. A comparative study on the corrosion resistance of AA224-T3 substrates pre-treated with different silane solutions-composition of the films formd[J]. Progress in Organic Coatings, 2005, 54(4):322-331.
【36】Trabelsi W, Triki E, Dhouibi L, et al. The use of pre-treatments based on doped silane solutions for improved corrosion resistance of galvanized steel substrates[J]. Surface and Coatings Technology, 2006, 200(14):4240-4250.
【37】Bexell U, Gtehk T M. A corrosion study of hot-dip galvanized steel sheet pre-treated with gamma-mereaptopropyltrimethoxy silane[J]. Surface and Coatings Technology, 2007, 201(8):4734-4742.
【38】吴海江, 卢锦堂. 热镀锌钢板表面硅烷膜的制备工艺与耐蚀性能[J]. 机械工程材料, 2009, 33(7): 52-55, 60.
【39】徐斌, 满瑞林, 曹晓燕, 等. 镀锌钢板的硅烷表面改性[J]. 腐蚀科学与防护技术, 2008, 20(2): 130-134.
【40】易德莲, 王静, 李宇鹏, 等. 镀锌板的复合钝化[J]. 腐蚀与防护, 2010, 32(2): 142-145.
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