Corrosion Inhibition of a Mixture Containing Imidazoline on Carbon Steel in Citric Acid Solution
摘 要
采用失重法、极化曲线法研究了咪唑啉与KI的复配缓蚀剂在4%(质量浓度, 下同)柠檬酸溶液中对碳钢的缓蚀协同作用。结果表明, 复配缓蚀剂可有效抑制45#碳钢在柠檬酸溶液中的腐蚀, 当缓蚀剂总浓度为0.4%时, 咪唑啉和KI浓度比为3∶1时缓蚀效果最好。极化曲线表明该复配缓蚀剂为混合型缓蚀剂。
Abstract
The mixture of imidazoline and potassium iodide as a corrosion inhibitor for carbon steel in 4% (wt) citric acid solution was investigated by weight loss test and polarization curve methods. Results show that the combined inhibitor strongly inhibits the corrosion of 45# carbon steel in citric acid solution and the mixture with the mass ratio undecyl-N-carboxymethyl-hydroxyethy imidzoline (UHCI) :KI of 3:1 has the best corrosion inhibition at a total concentration of 0.4%. The polarization curves indicate that the combined inhibitor behaves as a mixed type inhibitor.
中图分类号 TG174.42
所属栏目 试验研究
基金项目 上海市科委项目(10DZ2252400); 2011年上海市联盟计划; 上海热交换系统节能工程技术研究中心开放基金(09SERC03)
收稿日期 2012/1/11
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备注廖强强, 教授, 博士,
引用该论文: CHEN Ya-qiong,LIAO Qiang-qiang,DONG Wan-tian,GE Hong-hua,HOU Rui-gang. Corrosion Inhibition of a Mixture Containing Imidazoline on Carbon Steel in Citric Acid Solution[J]. Corrosion & Protection, 2012, 33(12): 1055
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参考文献
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【2】Peter C Okafor, Zheng Y G. Synergistic inhibition behaviour of methylbenzyl quaternary imidazoline derivative and iodide ions on mild steel in H2SO4 solutions[J]. Corrosion Science, 2009, 51(4): 850-859.
【3】张军, 胡松青, 王勇, 等. 1-(2-羟乙基)-2-烷基-咪唑啉缓蚀剂缓蚀机理的理论研究[J]. 化学学报, 2008, 66(22): 2469-2475.
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