低氧分压预处理对镍基合金028耐蚀性的影响
Influence of Oxidation Pretreatment at Low Oxygen Partial Pressure on Corrosion Resistance of Nickel Base Alloy 028
摘 要
对镍基合金Alloy028 在900 ℃进行低氧分压预处理10 h, 金相观察和硬度测试结果表明, 预处理后析出物减少, 组织得到细化, 硬度明显提高。SEM、EDS及XRD分析比较试样表面微观形貌与结构特征表明, 预处理后钝化膜形成元素Cr在表面发生富集, 且部分形成由Cr2O3和NiCr2O4组成的氧化膜。极化曲线测试表明, 预处理后合金的自腐蚀电位从-0.37 V正移至-0.25 V(SCE), 腐蚀电流密度比空白试样显著降低。电化学阻抗测试表明, 预处理试样的电荷转移电阻比空白试样提高一个数量级, 膜电阻提高2倍多。
表面预处理
低氧分压
氧化膜
极化曲线
电化学阻抗谱
nickel based alloy
surface pretreatment
low oxygen partial pressure
oxide film
polarization curve
electrochemical impedance spectroscopy (EIS)
Abstract
The pretreatment of nickel base alloy 028 at low oxygen partial pressure was carried out at 900℃ for 10h. After the pretreatment, the microstructure of the nickel alloy 028 sample was refined, precipitation along with its boundaries decreased and its hardness increased. The Cr2O3 and NiCr2O4 oxide films with continuously compact structural feature were formed primarily on the sample surface. They were examined by SEM, EDS and XRD. The polarization curve of the sample after the pretreatment indicated that its corrosion potential moved from -0.25V to -0.37 V(SCE), and corrosion current density obviously reduced compared with those of the control sample. The measurements of EIS showed that the charge transfer resistance after pretreatment rose by an order of magnitude and the film resistance reached 2 times or more compared with those of the control sample.
中图分类号 TG174, TB383
所属栏目 试验研究
基金项目
收稿日期 2012/2/29
修改稿日期
网络出版日期
作者单位点击查看
备注陈立强, 讲师, 博士,
引用该论文: CHEN Li-qiang,Han Yu-qiong,ZHENG Shu-qi,CHEN Chang-feng. Influence of Oxidation Pretreatment at Low Oxygen Partial Pressure on Corrosion Resistance of Nickel Base Alloy 028[J]. Corrosion & Protection, 2013, 34(1): 22
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参考文献
【1】Hibner E L, Puckett B C, Patchell J K.Comparison of corrosion resistance of nickel-base alloys for octg's mechanical tubing in severe sour service conditions[C]//Houston TX, USA:NACE 2005, Paper No.05101, 1-15.
【2】何生厚.普光高含H2S、CO2气田开发技术难题及对策[J].天然气工业, 2008, 28(4):82-86.
【3】沈琛.川东北超深高酸性气田勘探开发工程技术[J].中国工程科学, 2010, 12(10)29-34.
【4】沈琛, 张忠铧, 张春霞.高酸性腐蚀气田用BG2250-125镍基合金油管开发[J].中国工程科学, 2010, 12(10)35-38.
【5】Barbucci A, Cerisola G, Cabot P L.Effect of cold-working in the passive behavior of 304 stainless steel in sulfate media[J].J Electrochem Soc, 2002, 149(12):534-542.
【6】Stefanov P, Stoychev D, Stoycheva M, et al.XPS and sem studies of chromium oxide films chemically formed on stainless steel 316L[J].Mater Chem And Phy, 2000, 65(2):212-215.
【7】Kamachi-Mudali U, Reynders B, Stratmann M.Behaviour of Fe-N model alloys[J].Corros Sci, 1999, 41(1):179-189.
【8】Dean M H, Stimming U.The electronic properties of disordered passive films[J].Corros Sci, 1989, 29(2):199-211.
【9】Pardo M C, Merino A E, Coy F.Pitting corrosion behaviour of austenitic stainless steels- combining effects of Mn and Mo additions[J].Corrosion Science, 2008, 50:1796-1806.
【10】Marcus P, Maurice V, Strehblow H H.Localized corrosion (pitting):A model of passivity breakdown including the role of the oxide layer nanostructure[J].Corr Sci, 2008, 50:2698-2704.
【11】Sikora E, Macdonald D D.Nature of the passive film on nickel[J]. Electrochimica Acta, 2002, 48(1):69-77.
【12】陈长风, 范成武, 郑树启, 等.高温高压H2S/CO2 G3镍基合金表面的XPS分析[J], 中国有色金属学报, 2010, 18(11):2050-2055.
【13】Pan Y M, Dunn D S, Cragnlolino G A.Grain-boundary chemistry and intergranular corrosion in alloy 825[J].Metallurgical and Materials Transactions A, 2000(4):1163-1173.
【14】陈长风, 姜瑞景, 张国安, 等.镍基合金管材高温高压H2S/CO2环境中局部腐蚀研究[J].稀有金属材料与工程, 2010, 39(3): 427-432.
【15】Young D J.High temperature oxidation and corrosion of metals[J].Science, 2008:438-439.
【16】朱日彰, 何业东, 齐慧滨.高温腐蚀及耐高温腐蚀材料[M].上海:上海科学技术出版社, 1995, 160-193.
【17】Mineaki Matsumoto.The effect of pre-oxidation atmosphere on oxidation behavior and thermal cycle life of thermal barrier coatings[J]. Materials Science and Engineering A, 2006(441): 119-125.
【18】Pan J, Leygraf C, Jargelius-Pettersso R F A.Characterization of high-temperature oxide films on stainless steels by electrochemical impedance spectroscopy[J].Oxid Met, 1998, 50(5/6):431-455.
【19】Mikkelsen L, Linderoth S.High temperature oxidation of Fe-Cr alloy in O2-H2-H2O atmospheres:Microstructure and kinetics[J].Materials Science and Engineering A, 2003, 361(1):198-212.
【20】Salgadom F, Sabionia, Huntzam Eta L.High temperature oxidation behavior of the aisi430a and aisi430e stainless steels in Ar/H2/H2O atmosphere[J].Materials research, 2008, 11(2):227-232.
【21】Horsley G, Cairns J.The inhibition of carbon deposition on stainless steel by prior selective oxidation[J].Applied Surface Sci, 1984, 18(3):273-286.
【22】邵明增, 崔立山, 郑雁军, 等.用低氧分压法在35Cr45Ni合金表面制备防结焦氧化膜[J].中国石油大学学报(自然科学版), 2010, 34(4):127-135.
【2】何生厚.普光高含H2S、CO2气田开发技术难题及对策[J].天然气工业, 2008, 28(4):82-86.
【3】沈琛.川东北超深高酸性气田勘探开发工程技术[J].中国工程科学, 2010, 12(10)29-34.
【4】沈琛, 张忠铧, 张春霞.高酸性腐蚀气田用BG2250-125镍基合金油管开发[J].中国工程科学, 2010, 12(10)35-38.
【5】Barbucci A, Cerisola G, Cabot P L.Effect of cold-working in the passive behavior of 304 stainless steel in sulfate media[J].J Electrochem Soc, 2002, 149(12):534-542.
【6】Stefanov P, Stoychev D, Stoycheva M, et al.XPS and sem studies of chromium oxide films chemically formed on stainless steel 316L[J].Mater Chem And Phy, 2000, 65(2):212-215.
【7】Kamachi-Mudali U, Reynders B, Stratmann M.Behaviour of Fe-N model alloys[J].Corros Sci, 1999, 41(1):179-189.
【8】Dean M H, Stimming U.The electronic properties of disordered passive films[J].Corros Sci, 1989, 29(2):199-211.
【9】Pardo M C, Merino A E, Coy F.Pitting corrosion behaviour of austenitic stainless steels- combining effects of Mn and Mo additions[J].Corrosion Science, 2008, 50:1796-1806.
【10】Marcus P, Maurice V, Strehblow H H.Localized corrosion (pitting):A model of passivity breakdown including the role of the oxide layer nanostructure[J].Corr Sci, 2008, 50:2698-2704.
【11】Sikora E, Macdonald D D.Nature of the passive film on nickel[J]. Electrochimica Acta, 2002, 48(1):69-77.
【12】陈长风, 范成武, 郑树启, 等.高温高压H2S/CO2 G3镍基合金表面的XPS分析[J], 中国有色金属学报, 2010, 18(11):2050-2055.
【13】Pan Y M, Dunn D S, Cragnlolino G A.Grain-boundary chemistry and intergranular corrosion in alloy 825[J].Metallurgical and Materials Transactions A, 2000(4):1163-1173.
【14】陈长风, 姜瑞景, 张国安, 等.镍基合金管材高温高压H2S/CO2环境中局部腐蚀研究[J].稀有金属材料与工程, 2010, 39(3): 427-432.
【15】Young D J.High temperature oxidation and corrosion of metals[J].Science, 2008:438-439.
【16】朱日彰, 何业东, 齐慧滨.高温腐蚀及耐高温腐蚀材料[M].上海:上海科学技术出版社, 1995, 160-193.
【17】Mineaki Matsumoto.The effect of pre-oxidation atmosphere on oxidation behavior and thermal cycle life of thermal barrier coatings[J]. Materials Science and Engineering A, 2006(441): 119-125.
【18】Pan J, Leygraf C, Jargelius-Pettersso R F A.Characterization of high-temperature oxide films on stainless steels by electrochemical impedance spectroscopy[J].Oxid Met, 1998, 50(5/6):431-455.
【19】Mikkelsen L, Linderoth S.High temperature oxidation of Fe-Cr alloy in O2-H2-H2O atmospheres:Microstructure and kinetics[J].Materials Science and Engineering A, 2003, 361(1):198-212.
【20】Salgadom F, Sabionia, Huntzam Eta L.High temperature oxidation behavior of the aisi430a and aisi430e stainless steels in Ar/H2/H2O atmosphere[J].Materials research, 2008, 11(2):227-232.
【21】Horsley G, Cairns J.The inhibition of carbon deposition on stainless steel by prior selective oxidation[J].Applied Surface Sci, 1984, 18(3):273-286.
【22】邵明增, 崔立山, 郑雁军, 等.用低氧分压法在35Cr45Ni合金表面制备防结焦氧化膜[J].中国石油大学学报(自然科学版), 2010, 34(4):127-135.
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