Effect of Tempering at 200 ℃ on Electrochemical Behavior of X80 Steel in NaHCO3 Solution
摘 要
采用热处理炉对X80管线钢进行200 ℃回火30 min, 通过动电位极化, 电化学阻抗谱等技术研究了回火前后X80钢在NaHCO3溶液中的腐蚀电化学行为。结果表明, 回火前后X80在NaHCO3溶液中的腐蚀都是阴极控制腐蚀类型, 但低温回火后X80钢的自腐蚀电位从回火前的-0.739 V降低为-0.877 V(SCE), 并且维钝电流也从回火前的5.48 μA·cm-2升高到17.82 μA·cm-2; 电化学阻抗谱测试表明, 低温回火后的钝化膜比回火前X80钢钝化膜疏松, 这与金相显微镜观察结果相吻合。
Abstract
X80 pipeline steel was tempered for 30min at 200 ℃ with a heat treatment furnace, and then the electrochemical behavior of X80 steel before and after tempering in the solution of NaHCO3 was studied by the method of potentiodynamic polarization , electrochemical impedance spectroscopy and so on. The results showed that the corrosion was the type of cathodiz control. The corrosion potential of the X80 steel was reduced from -0.75 V before tempering to -0.80 V (SCE) after tempereing, and the passive current increased from 5.48 μA·cm-2 before tempering to 17.82 μA·cm-2 after tempered; AC impedance measurements show that the passive film of tempered X80 steel was loose, which is consistent with the observations of atomic force microscopy.
中图分类号 TG174
所属栏目 试验研究
基金项目 国家自然科学基金(51174171)
收稿日期 2012/6/19
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备注王霞, 教授, 博士,
引用该论文: WANG Xia,SUN Yu-wei,LUO Min-quan. Effect of Tempering at 200 ℃ on Electrochemical Behavior of X80 Steel in NaHCO3 Solution[J]. Corrosion & Protection, 2013, 34(5): 385
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