Anti-corrosion Properties of Common Materials in Processing High Acid Crude Oil
摘 要
采用定点测厚、氢通量等腐蚀检测技术在2008-2010年对中石化四套加工高酸原油常减压装置进行了两年半的腐蚀监测,并将检测结果与API581中数据进行了对比。结果表明, 20#材质在220 ℃以上即腐蚀明显; 焦化装置高温进料线多为Cr5Mo,部分管道腐蚀减薄明显; 304/321材质在288 ℃以下腐蚀轻微,但用于高温、高流速的转油线则腐蚀严重; 316L材质抗高酸油腐蚀性能良好,即使是转油线也基本腐蚀轻微,腐蚀速率约0.1 mm/a,少部分监测点腐蚀速率为0.1~0.2 mm/a。
Abstract
Corrosion detection technologies such as fixed thickness measurement and hydrogen flux testing were used to monitor the corrosion of 4 atmospheric and racuum distiuation units from 2008 to 2010 for about two and a half years. The monitoring results were compared with the database of API 581. The results showed that material 20# had obvious corrosion when the temperature was over 220 ℃. In the high temperature feed line of coking unit made of material Cr5Mo mainly, some of the pipelines were thinned by corrosion significantly. Corrosion of pipelines with material 304/321 was slight when the temperature was below 288 ℃. Serious corrosion occurred on material 304/321 when used for higher temperature and high fluid velocity transfer line. Material 316L had good anti-corrosion capability in processing high acid crude oil, even the corrosion of transfer line was slight. The corrosion rate of transfer lines with material 316L was about 0.1 mm·a-1, and small part of which was 0.1~0.2 mm·a-1.
中图分类号 TG174.2 TE985.9
所属栏目 应用技术
基金项目
收稿日期 2013/3/24
修改稿日期
网络出版日期
作者单位点击查看
备注梁春雷,工程师,硕士,
引用该论文: LIANG Chun-lei,WANG Jian-jun,GAO Jun-feng,CHEN Xue-dong,AI Zhi-bin. Anti-corrosion Properties of Common Materials in Processing High Acid Crude Oil[J]. Corrosion & Protection, 2013, 34(8): 734
共有人对该论文发表了看法,其中:
人认为该论文很差
人认为该论文较差
人认为该论文一般
人认为该论文较好
人认为该论文很好
参考文献
【1】Slavcheva E,Shone B,Turnbull A. Review of naphthenic acid corrosion in oil refining[J]. British Corrosion Journal,1999,34(2): 125-131.
【2】Tebba S,Kane R D. Assessment of crude oil corrosivity[C]//Corrosion 98,Houston:NACE International,1998:578.
【3】Kane R D,Cayard M S. A comprehensive study on naphthenic acid corrosion[C]//Corrosion 2002,Houston:NACE International,2002:02555.
【4】Groysman A,Brodsky B,Pener J,et al. Low temperature naphthenic acid corrosion study[C]//Corrosion 2007,Houston:NACE International,2007:07569.
【5】Dettman H D,Li N,Luo J. Refinery corrosion,organic acid structure,and athabas bitumen[C]//Corrosion 2009,Houston:NACE International,2009:09336.
【6】梁春雷,陈学东,艾志斌,等. 环烷酸腐蚀机理及其影响因素研究综述[J]. 压力容器,2008,25(5):30-36.
【7】Dean F W H,Powell S W. Hydrogen flux and high temperature acid corrosion[C]//Corrosion 2006,Houston:NACE International,2006:06436.
【8】API 581-2008Risk-based inspection technology[S].
【2】Tebba S,Kane R D. Assessment of crude oil corrosivity[C]//Corrosion 98,Houston:NACE International,1998:578.
【3】Kane R D,Cayard M S. A comprehensive study on naphthenic acid corrosion[C]//Corrosion 2002,Houston:NACE International,2002:02555.
【4】Groysman A,Brodsky B,Pener J,et al. Low temperature naphthenic acid corrosion study[C]//Corrosion 2007,Houston:NACE International,2007:07569.
【5】Dettman H D,Li N,Luo J. Refinery corrosion,organic acid structure,and athabas bitumen[C]//Corrosion 2009,Houston:NACE International,2009:09336.
【6】梁春雷,陈学东,艾志斌,等. 环烷酸腐蚀机理及其影响因素研究综述[J]. 压力容器,2008,25(5):30-36.
【7】Dean F W H,Powell S W. Hydrogen flux and high temperature acid corrosion[C]//Corrosion 2006,Houston:NACE International,2006:06436.
【8】API 581-2008Risk-based inspection technology[S].
相关信息