碱性锌酸盐体系中Zn-Ni合金镀层的电沉积行为
Electroplating Behavior of Zn-Ni Alloys in an Alkaline Electrolyte
摘 要
采用循环伏安技术、计时安培技术和扫描电镜技术研究了碱性锌酸盐体系中Zn-Ni合金镀层在A3钢表面的电沉积行为。结果表明，在Zn-Ni合金镀层共沉积之前，富镍层优先在A3钢表面沉积; 镀液中Zn2+的阴极还原阻碍了Ni2+的阴极还原反应，而Ni2+则促进了Zn2+的电沉积过程; Zn-Ni合金镀层的电沉积过程遵循扩散控制下的二维(2D)成核/生长机制。
共沉积
电沉积
Zn-Ni alloy coating
co-deposition
electrodeposition
Abstract
The electroplating behavior of Zn-Ni alloys in an alkaline electrolyte was investigated using cyclic voltammetry (CV), chronoamperometry (CHR), scanning electron microscopy (SEM) and energy dispersive spectrometer (EDS) techniques. The results show that a layer of Ni-enriched deposits preferentially formed on A3 steel substrate during the initial electroplating stage of Zn-Ni alloy. The Zn2+ ions in the solution inhibited the reduction of Ni2+ ions, while Ni2+ ions accelerated the reduction reaction of Ni2+ ions. The initial deposition process of Zn-Ni alloy follows the mechanism of 2D nucleation/growth under mass transfer control.
中图分类号 TG174.4
所属栏目 试验研究
基金项目 国家自然科学基金(21073162; 21273199); 绿色化学合成技术国家重点实验室培育基地开放研究基金(GCTKF2012013)
收稿日期 2013/7/11
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联系人作者郦智斌(li0438@126.com)
备注郦智斌,高级工程师,硕士,
引用该论文: LI Zhi-bin,LU Wen-shan,ZHANG Zhao. Electroplating Behavior of Zn-Ni Alloys in an Alkaline Electrolyte[J]. Corrosion & Protection, 2013, 34(10): 874
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参考文献
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【3】Wright D A. Zn-Ni electroplate as a replacement for cadmium on high-strength steels[J]. Plating and Surface Finishing,1994,81(7):18-21.
【4】Sheela G,Malathy Pushpavanam,Pushpavanam S. Zinc-nickel alloy electrodeposits for water electrolysis[J]. International Journal of Hydrogen Energy,2002,27:627-633.
【5】Hu Chi Chang,Tsay Cheng Hsiang,Allen Bai. Optimization of the hydrogen evolution activity on zinc-nickel deposits using experimental strategies[J]. Electrochimica Acta,2003,48:907-918.
【6】Ramin M A Tehrani,Sulaiman Ab Ghani. Voltammetric analysis of uric acid by zinc-nickel nanoalloy coated composite graphite[J]. Sensors and Actuators B,2010,145:20-24.
【7】沈品华,屠振密. 电镀锌及锌合金[M]. 北京:机械工业出版社,2001.
【8】鹿文姗, 徐天凤, 陈宇,等. 碱性电镀锌镍合金的研究[J]. 中国腐蚀与防护学报,2012,32(6):443-448.
【9】Mendoza Huizar L H,Robles J,Palomar Pardave M. Nucleation and growth of cobalt onto different substrates. Part I: Underpotential deposition onto a gold electrode[J]. Journal of Electroanalytical Chemistry,2002,521:95-106.
【10】Randles J E B. A cathode ray polarograph Part II. The current-voltage curves[J]. Trans Faraday Soc,1948,44:327-337.
【11】Li Y G,Chrzanowski W,Lasiu A. Nucleation and crystal growth in gold electrode position from acid solution. Part I: Soft cold[J]. Journal of Applird Electoochemistry,1996,26:843-852.
【12】Marlon T C,Allan J J. Control of nucleation and crystal growth kinetics of MOF-5 on functionalized gold surface[J]. Microporous and Mesoporous Materials, 2013,175:107-115.
【13】Li Y G,Lasia A. Nucleation and crystal growth in gold electrodeposition from acid solution,Part II:Hard cold[J]. Journal of Applied Electrochemistry,1996,26:853-863.
【14】Lin Z B,Xie B G,Chen J S. Nucleation mechanism of silver during electrodeposition on a glassy carbon electrode from a cyanide-free bath with 2-hydroxypyridine as a complexing agent[J]. Journal of Electroanalytical Chemistry,2009,633:207-211.
【15】Yang Z N,Zhang Z,Zhang J Q. Electrodeposition of decorative and protective Zn-Fe coating onto low-carbon steel substrate[J]. Surface and Coatings Technology,2006,200:4810-4815.
【16】Margarita Miranda Hernandez,Manuel Palomar Pardave,Nikola Batina. Identification of different silver nucleation processes on vitreous carbon surfaces from an ammonia electrolytic bath[J]. Journal of Electroanalytical Chemistry,1998,443:81-93.
【17】Mendoza Huizar L H,Robles J,Palomar Pardave M. Nucleation and growth of cobalt onto different substrates. Part II: The upd-opd transition onto a gold electrode[J]. Journal of Electroanalytical Chemistry,2003,545:39-45.
【18】Maria Grzeszczuk,Jerzy Kalenik,Anna Kepas Suwara. Phase boundaries in layer-by-layer electrodeposited polypyrrole resulted from 2D-3D growths of polymer sublayers[J]. Journal of Electroanalytical Chemistry,2009,626:47-58.
【19】Saeza V,Marchante E,Diez M I,et al. A study of the lead dioxide electrocrystallization mechanism on glassy carbon electrodes. Part I:Experimental conditions for kinetic control[J]. Materials Chemistry and Physics,2011,125:46-54.
【20】Margarita Miranda Hernandeza,Ignacio Gonzalezb. Effect of potential on the early stages of nucleation and growth during silver electrocrystallization in ammonium medium on vitreous carbon[J]. Journal of the Electrochemical Society,2004,151(3):220-228.
【21】Marcin Chmielewski,Maria Grzeszczuk,Jerzy Kalenik. Evaluation of the potential dependence of 2D-3D growth rates and structures of polypyrrole films in aqueous solutions of hexafluorates[J]. Journal of Electroanalytical Chemistry,2010,647:169-180.
【22】Ballesterosa J C,Chainet E,Ozilb P. Electrochemical studies of Zn underpotential/overpotential deposition on a nickel electrode from non-cyanide alkaline solution containing glycine[J]. Electrochimica Acta,2011,56:5443-5451.
【23】Holzle M H,Retter U,Kolb D M. The kinetics of changes in Cu adlayers on Au(111)[J]. Electroanal Chem,1994,371:101-109.
【24】Armstrong R D,Harrison J A. Two-dimensional nucleation in electro crystallization[J]. Electrochem Soc,1969,116(3):328-331.
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