Preparation and Performance of Plant Extractive Corrosion Inhibitors
摘 要
萃取土豆和香蕉皮中的有机成分复配制成缓蚀剂;采用失重法、极化曲线、电化学阻抗谱等方法研究了复配缓蚀剂在1mol?L-1盐酸体系中对A3碳钢的缓蚀性能;确定了缓蚀效率最高的提取物复配配方。结果表明,单一缓蚀剂和复配缓蚀剂都有一定的缓蚀性能;提取物对碳钢的缓蚀性能随浓度的增大而增大;当香蕉皮与土豆提取物复配缓蚀剂浓度为7.5mg?L-1(质量比为2)时,A3碳钢在1mol?L-1盐酸体系中的缓蚀效率达93.9%。
Abstract
An inhibitor was prepared by compound organic ingredients extracted from potato and banana skin.Thecorrosion inhibition on A3steel in 1 mol?L-1 HCl solution was investigated using weight-loss test,polarizationcurves and electrochemical impedance spectroscopy(EIS).The extracted compound formula with the highestinhibition efficiency was determined.The results show that both single and compound extracts have corrosioninhibition effects.The inhibition efficiency increased with increasing the inhibitor concentration.The inhibitionefficiency in 1mol?L-1 HCl solution reached 93.9%,when the concentration of banana skin and potato extracts witha mass ratio of 2 was 7.5 mg·L-1.
中图分类号 TG174.42
所属栏目 试验研究
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收稿日期 2013/1/16
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联系人作者郭英(gy310@163.com)
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引用该论文: GUO Ying,HOU Yuan-chun,FAN Bing-bing,DONG Yi-fan,FAN Qin-ying,BAI Shuang,AI Cong-cong. Preparation and Performance of Plant Extractive Corrosion Inhibitors[J]. Corrosion & Protection, 2013, 34(11): 1010
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参考文献
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【3】高国,梁成浩.气相缓蚀剂的研究现状及发展趋势[J].中国腐蚀与防护学报,2007,27:252-256.
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【5】蒋伟,龚敏,赵金平.天然植物绿色缓蚀剂的研究进展[J].腐蚀科学与防护技术,2007,19(4):278-279.
【6】王慧龙,郑家燊.环境友好缓蚀剂的研究进展[J].腐蚀科学与防护技术,2002,14(5):275-279.
【7】柳鑫华,孙彩云,王庆辉.天然海水中钼酸盐复合缓蚀剂对A3钢的缓蚀效果[J].材料保护,2010,43(9):59-61.
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【9】李向红,邓书端,付惠.滑竹叶提取物在盐酸介质中对铝的缓蚀性能[J].应用化学,2012,29:962-967.
【10】汪晓军,肖锦.改性天然高分子酸缓蚀剂的长效缓蚀性能研究[J]. 华南理工大学学报: 自然科学版, 1998,26(1):71-75.
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