铝合金表面溶胶-凝胶防腐蚀膜层研究进展及展望
Progress and Perspectives of Sol-gel Anti-corrosion Coatings on Aluminum Alloy
摘 要
铝及其合金具有低密度、高比强度等优点,在很多行业被广泛使用。然而,由于其耐蚀性一般,很大程度上限制了它的应用。提高其耐蚀性的有效手段之一就是采用溶胶-凝胶技术在铝合金表面制备防腐蚀膜层,该技术具有操作简单、节能环保等优点,有望取代对环境不友好的铬酸盐处理技术。对铝合金表面溶胶-凝胶氧化物、有机、有机改性硅酸盐、含掺杂物有机改性硅酸盐复合等防腐蚀膜层的研究进展进行了综述,并展望了未来可能的研究方向。
溶胶-凝胶
防腐蚀
膜层
aluminum alloy
sol-gel
anti-corrosion
coating
Abstract
Aluminum and its alloys have many excellent properties, such as the low density and high strength/weight ratio, and so on. They are widely used in many industries. However, poor resistance to corrosion limits their application. One of the effective ways to improve their corrosion resistance is preparation of anti-corrosion coatings on aluminum alloys by sol-gel technology, which has advantages of simple operation, environmental protection and so on. It is expected to replace the conventional harmful chromate treatment technology. In this paper, sol-gel anti-corrosion coatings on aluminum alloys, such as oxides, organic coatings, ormosil coatings, dopant-containing ormosil coatings are reviewed. The challenges for industrial productions and future research on sol-gel corrosion protective coatings are also briefly discussed.
中图分类号 TG174.4
所属栏目 专论
基金项目 国家自然科学基金(50701006;51271031); 中央高校基本科研业务费专项资金(FRF-SD-12-027A)
收稿日期 2013/3/1
修改稿日期
网络出版日期
作者单位点击查看
联系人作者吴俊升(wugs76@163.com)
备注吴俊升(1976-),副教授,博士,从事材料化学表面改进研究,
引用该论文: PAN Xiao-ming,WU Jun-sheng,XIAO Kui,LI Xiao-gang. Progress and Perspectives of Sol-gel Anti-corrosion Coatings on Aluminum Alloy[J]. Corrosion & Protection, 2013, 34(12): 1045
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参考文献
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【25】JERMAN I, OREL B, KOVAC J, et al. A structural and corrosion study of triethoxysilyl and perfluorooctyl functionalized polyhedral silsesquioxanenanocompositefilms on AA2024 alloy[J]. Thin Solid Films,2010,518(10):2710-2721.
【26】JERMAN I, SVEGL F, OREL B, et al. Influence of amino functionalised POSS additive on the corrosion properties of(3-glycidoxypropyl)trimethoxysilane coatings on AA2024 alloy[J]. Progress in Organic Coatings, 2011,72(3):334-342.
【27】LAI Y S, WANG G P, WU K H, et al. Structural and electrochemical properties of polyurethanes/polyhedral oligomericsilsesquioxanes (PU/POSS) hybrid coatings on aluminum alloys[J]. Materials Chemistry and Physics,2009,117(1):91-98.
【28】OSBORNE J H, DU Y J, DAMRON M, et al. Inorganic/organic hybrid coatings for aircraft alumi-num alloy substrates[J]. Progress in Organic Coatings,2001,41(4):226-232.
【29】ZANDIZAND R, ERSHADLANGROUDI A, RAHIMI A. Organic-inorganic hybrid coatings for corros-ionprotection of 1050 aluminum alloy[J]. Journal of Non-Crystalline Solids,2005, 351(14/15):1307-1311.
【30】TAVANDASHTI N P, SANJABI S, SHAHRABI T. Corrosion protection evaluation of silica/epoxy hybrid nanocomposite coatings to AA2024[J]. Progress in Organic Coatings,2009,65(2):182-186.
【31】APARICIO M, PELLICE S A, DURAN A, et al. Effects of Ce-containing sol-gel coatings reinforced with SiO2 nanoparticles on the protection of AA2024[J]. Corrosion Science,2008,50(5):1283-1291.
【32】ZAHARESCU M, PREDOANA L, BARAU A, et al. SiO2 based hybrid inorganic-organic films doped with TiO2-CeO2 nanoparticles for corrosion protection of AA2024 and Mg-AZ31B alloys[J]. Corrosion Science,2009,51(9):1998-2005.
【33】LVAREZ D, COLLAZO A, HERNNDEZ M, et al. Characterization of hybrid sol-gel coatings doped with hydrotalcite-like compounds to improve corrosion resistance of AA2024-T3 alloys[J]. Progress in Organic Coatings,2010,67(2):152-160.
【34】DALMORO V, ARMELIN E, ALEMN C, et al. Phosphonic acid/silica-based films:A potential treatment for corrosion protection[J]. Corrosion Science,2012,60:173-180.
【35】AKID R, GOBARA M, WANG H. Corrosion protection performance of novel hybrid polyaniline/sol-gel coatings on an aluminium 2024 alloy in neutral, alkaline and acidic solutions[J]. ElectrochimicaActa,2011,56(5):2483-2492.
【36】王为军,杭建忠,施利毅,等.纳米Al2O3/有机-无机杂化复合铝合金涂层的耐腐蚀性能研究[J]. 涂料工业,2010,40(8):8-12.
【37】李恒,李澄.纳米TiO2复合涂层的制备及其对LY12铝合金的防护性能影响[J] .燕山大学学报,2011,35(1):57-61.
【38】TAVANDASHTI N P, SANJABI S. Corrosion study of hybrid sol-gel coatings containing boehmite nanoparticles loaded with cerium nitrate corrosion inhibitor[J]. Progress in Organic Coatings,2010,69(4):384-391.
【39】ROSERO N N C, PELLICE S A , CASTRO Y. Improved corrosion resistance of AA2024 alloys through hybrid organic-inorganic sol-gel coatings produced from sols with controlled polymerization[J]. Surface & Coatings Technology,2009,203(13):1897-1903.
【40】YASAKAU K A, ZHELUDKEVICH M L, KARAVAI O V, et al. Influence of inhibitor addition on the corrosion protection performance of sol-gel coatings on AA2024[J]. Progress in Organic Coat ings,2008,63(3):352-361.
【41】COLLAZO A, COVELO A, NVOA X R, et al. Corrosion protection performance of sol-gel coatings doped with red mud applied on AA2024-T3[J]. Progress in Organic Coatings,2012,74(2):334-342.
【42】WITTMAR A, WITTMAR M, UIRICH A, et al. Hybrid sol-gel coatings doped with transition metal ions for the protection of AA2024-T3[J]. Journal of sol-Gel Science and Technology,2012,61(3):600-612.
【43】RAMS J, UREA A, LPEZ M D, et al. Characterisation of multilayered sol-gel silica coatings on aluminium-SiC composites[J]. Surface & Coatings Technology,2006,201(6):3715-3722.
【44】ROSERO N N C, PAUSSA L, ANDREATTA F, et al. Optimization of hybrid sol-gel coatings by combination of layers with complementary properties for corrosion protection of AA2024[J]. Progress in Organic Coatings,2010,69(2):167-174.
【45】MEKERIDIS E D, KARTSONAKIS I A ,KORDAS G C. Multilayer organic-inorganiccoating incorporating TiO2 nanocontainers loaded with inhibitors for corrosion protection of AA2024-T3[J]. Progress in Organic Coatings,2012,73(2/3):142-148.
【46】KARTSONAKIS I A, KOUMOULOS E P, BALASKAS A C, et al. Hybrid organic-inorganic multilayer coatings including nanocontainers for corrosion protection of metal alloys[J]. Corrosion Science,2012,57:56-66.
【2】HAMDY A S, BUTT D P. Environmentally compliant silica conversion coatings prepared by sol-gel method for aluminum alloys[J]. Surface & Coatings Technology,2006,201(1/2):401-407.
【3】VREUGDENHIL A J, BALBYSHEV V N, DONLEY M S. Nanostructured silicon sol-gel surface treatments for Al 2024-T3 protection[J]. Journal of Coatings Technology,2001,73(915):35-43.
【4】KHRAMOV A N, BALBYSHEV V N, VOEVODIN N N, et al.Nanostructured sol-gel derived conversion coatings based on epoxyand amino-silanes[J]. Progress in Organic Coatings,2003,47(3/4):207-213.
【5】VOEVODIN N N, BALBYSHEV V N, KHOBAIB M, et al. Nanostructured coatings approach for corrosion protection[J]. Progress in Organic Coatings,2003,47(3/4):416-423.
【6】VOEVODIN N N, KURBZIEL J W, MANTZ R, et al. Corrosion protection for aerospace aluminum alloys by modified self-assembled nanophase particle(MSNAP)sol-gel[J]. Surface & Coatings Technology,2006,201(3/4):1080-1084.
【7】LPEZ A J, URE A A, RAMS J, et al. Laser densification of sol-gel silica coatings on aluminium matrix composites for corrosion and hardness improvement[J]. Surface & Coatings Technology,2009,203(10/11):1474-1480.
【8】ALTUBE A, IMAZ N, DIEZ J A, et al. Influence of deposition conditions on the protective behavior of tetraethyl orthosilicate sol-gel films on AA5754 aluminum alloy[J]. Progress in Organic Coatings,2012,74(2):281-287.
【9】VOEVODIN N N, GREBASCH N T, SOTO W S, et al. An organically modified zirconate film as a corrosion-resistant treatment for aluminum 2024-T3[J]. Progress in Organic Coatings,2001,41(4):287-293.
【10】CUSM A, KACIULIS S, MEZZI A, et al. Zirconia primers for corrosion resistant coatings[J]. Surface & Coatings Technology,2007,201(12):5822-5828.
【11】ANDREATTA F, ALIIGHIERI P, PAUSSA L, et al. Electrochemical behaviour of ZrO2 sol-gel pre-treatments on AA6060 aluminiumalloy[J]. ElectrochimicaActa,2007,52(27):7545-7555.
【12】PAUSSA L, BRAVIN D, ANDREATTA F, et al. ZrO2 sol-gel pre-treatments doped with cerium nitrate for the corrosion protection of AA6060[J]. Progress in Organic Coatings,2012,74(2):311-319.
【13】HINTON B R W, ARNOTT D R, RYAN N E.The inhibition of aluminium alloy corrosion by cerouscations[J]. Metals Forum,1984,7(4):211-217.
【14】Hamdy A S. Advanced nano-particles anti-corrosion ceria based sol-gel coatings for aluminum alloys[J]. Materials Letters,2006,60(21/22):2633-2637.
【15】HASANNEJAD H, ALIOFKHAZRAEI M, SHANAGHOI A, et al. Nanostructural and electrochemical characteristics of cerium oxide thin films deposited on AA5083-H321 aluminum alloy substrates by dip immersion and sol-gel methods[J]. Thin Solid Films,2009,517(17):4792-4799.
【16】HASSANNEJAD H,SHAHRABI T,ALIOFKHAZRAEI M. Study of sol-gel process for preparing cerium nano-oxide films on AA7020-T6 Al alloy[J]. Surface Engineering,2009,25(5):393-402.
【17】MIKHAILOVSKII Y N, BERDZENISHVILI G A. Influence of pH on electrochemical and corrosion behavior of aluminum in media containing oxo anions of the oxidizing type[J]. Prot Met (USSR),1986,21(6):758-762.
【18】COOK R L, TAYLOR S R. Pigment-derived inhibitors for aluminum alloy 2024-T3[J]. Corrosion, 2000,56(3):321-333.
【19】HAMDY A S, BUTT D P. Novel anti-corrosion nano-sized vanadia-based thin films prepared by sol-gel method for aluminum alloys[J]. Journal of Materials Processing Technology,2007,181(1/3):76-80.
【20】王禹慧,赵景茂,左禹.铝合金耐蚀膜的制备及其性能研究[J].腐蚀与防护,2005,26(20):432-435.
【21】CHANG C C, WANG C C, WU C W, et al. Using TOF-SIMS and EIS to evaluate green pre- treatment reagent: Corrosion protection of aluminum alloy by silica/zirconium/cerium hybrid coating[J]. Applied Surface Science,2008,255(4):1531-1533.
【22】HASSANNEJAD H, SHAHRABI T, MALEKMOHAMMADI F, et al. Effect of cerium doping on corrosion resistance of amorphous silica-titanium sol-gel coating[J]. Current Applied Physics,2010,10(4):1022-1028.
【23】PEZ M A, GONZALEZ E, PAVEZ J, et al. A silanol-based nanocomposite coating for protection of AA2024 aluminiumalloy[J]. Electrochimica Acta,2011,56(22):7586-7595.
【24】JERMAN I, OREL B, KOVAC J, et al. A structural and corrosion study of triethoxysilylfunctiona- lized POSS coatings on AA2024 alloy[J]. Langmuir,2008,24(9):5029-5037.
【25】JERMAN I, OREL B, KOVAC J, et al. A structural and corrosion study of triethoxysilyl and perfluorooctyl functionalized polyhedral silsesquioxanenanocompositefilms on AA2024 alloy[J]. Thin Solid Films,2010,518(10):2710-2721.
【26】JERMAN I, SVEGL F, OREL B, et al. Influence of amino functionalised POSS additive on the corrosion properties of(3-glycidoxypropyl)trimethoxysilane coatings on AA2024 alloy[J]. Progress in Organic Coatings, 2011,72(3):334-342.
【27】LAI Y S, WANG G P, WU K H, et al. Structural and electrochemical properties of polyurethanes/polyhedral oligomericsilsesquioxanes (PU/POSS) hybrid coatings on aluminum alloys[J]. Materials Chemistry and Physics,2009,117(1):91-98.
【28】OSBORNE J H, DU Y J, DAMRON M, et al. Inorganic/organic hybrid coatings for aircraft alumi-num alloy substrates[J]. Progress in Organic Coatings,2001,41(4):226-232.
【29】ZANDIZAND R, ERSHADLANGROUDI A, RAHIMI A. Organic-inorganic hybrid coatings for corros-ionprotection of 1050 aluminum alloy[J]. Journal of Non-Crystalline Solids,2005, 351(14/15):1307-1311.
【30】TAVANDASHTI N P, SANJABI S, SHAHRABI T. Corrosion protection evaluation of silica/epoxy hybrid nanocomposite coatings to AA2024[J]. Progress in Organic Coatings,2009,65(2):182-186.
【31】APARICIO M, PELLICE S A, DURAN A, et al. Effects of Ce-containing sol-gel coatings reinforced with SiO2 nanoparticles on the protection of AA2024[J]. Corrosion Science,2008,50(5):1283-1291.
【32】ZAHARESCU M, PREDOANA L, BARAU A, et al. SiO2 based hybrid inorganic-organic films doped with TiO2-CeO2 nanoparticles for corrosion protection of AA2024 and Mg-AZ31B alloys[J]. Corrosion Science,2009,51(9):1998-2005.
【33】LVAREZ D, COLLAZO A, HERNNDEZ M, et al. Characterization of hybrid sol-gel coatings doped with hydrotalcite-like compounds to improve corrosion resistance of AA2024-T3 alloys[J]. Progress in Organic Coatings,2010,67(2):152-160.
【34】DALMORO V, ARMELIN E, ALEMN C, et al. Phosphonic acid/silica-based films:A potential treatment for corrosion protection[J]. Corrosion Science,2012,60:173-180.
【35】AKID R, GOBARA M, WANG H. Corrosion protection performance of novel hybrid polyaniline/sol-gel coatings on an aluminium 2024 alloy in neutral, alkaline and acidic solutions[J]. ElectrochimicaActa,2011,56(5):2483-2492.
【36】王为军,杭建忠,施利毅,等.纳米Al2O3/有机-无机杂化复合铝合金涂层的耐腐蚀性能研究[J]. 涂料工业,2010,40(8):8-12.
【37】李恒,李澄.纳米TiO2复合涂层的制备及其对LY12铝合金的防护性能影响[J] .燕山大学学报,2011,35(1):57-61.
【38】TAVANDASHTI N P, SANJABI S. Corrosion study of hybrid sol-gel coatings containing boehmite nanoparticles loaded with cerium nitrate corrosion inhibitor[J]. Progress in Organic Coatings,2010,69(4):384-391.
【39】ROSERO N N C, PELLICE S A , CASTRO Y. Improved corrosion resistance of AA2024 alloys through hybrid organic-inorganic sol-gel coatings produced from sols with controlled polymerization[J]. Surface & Coatings Technology,2009,203(13):1897-1903.
【40】YASAKAU K A, ZHELUDKEVICH M L, KARAVAI O V, et al. Influence of inhibitor addition on the corrosion protection performance of sol-gel coatings on AA2024[J]. Progress in Organic Coat ings,2008,63(3):352-361.
【41】COLLAZO A, COVELO A, NVOA X R, et al. Corrosion protection performance of sol-gel coatings doped with red mud applied on AA2024-T3[J]. Progress in Organic Coatings,2012,74(2):334-342.
【42】WITTMAR A, WITTMAR M, UIRICH A, et al. Hybrid sol-gel coatings doped with transition metal ions for the protection of AA2024-T3[J]. Journal of sol-Gel Science and Technology,2012,61(3):600-612.
【43】RAMS J, UREA A, LPEZ M D, et al. Characterisation of multilayered sol-gel silica coatings on aluminium-SiC composites[J]. Surface & Coatings Technology,2006,201(6):3715-3722.
【44】ROSERO N N C, PAUSSA L, ANDREATTA F, et al. Optimization of hybrid sol-gel coatings by combination of layers with complementary properties for corrosion protection of AA2024[J]. Progress in Organic Coatings,2010,69(2):167-174.
【45】MEKERIDIS E D, KARTSONAKIS I A ,KORDAS G C. Multilayer organic-inorganiccoating incorporating TiO2 nanocontainers loaded with inhibitors for corrosion protection of AA2024-T3[J]. Progress in Organic Coatings,2012,73(2/3):142-148.
【46】KARTSONAKIS I A, KOUMOULOS E P, BALASKAS A C, et al. Hybrid organic-inorganic multilayer coatings including nanocontainers for corrosion protection of metal alloys[J]. Corrosion Science,2012,57:56-66.
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