膨胀石墨-活性炭负载CeO2/TiO2复合材料的制备及其处理苯酚的性能
Preparation of Composite of CeO2/TiO2 Supported by Expanded Graphite-Activated Carbon and Its Treatment Ability to Phenol
摘 要
采用沉淀工艺制了CT(CeO2/TiO2)催化剂粉, 以膨胀石墨基炭/炭复合材料(EGC)为基体, 将CT粉以碳膜包覆的形式引入EGC表面, 制得了EGC负载CT催化剂粉的CT/EGC复合材料, 研究了其对苯酚的处理性能。结果表明: 铈钛物质的量比为0.002的CT催化剂粉处理苯酚的效果最好; CT/EGC处理苯酚溶液时, CT粉的光催化能力与EGC的吸附作用存在协同效应, 提高了复合材料对苯酚的处理效果。
光催化
TiO2
苯酚
expanded graphite based carbon/carbon composite
photo catalysis
TiO2
phenol
Abstract
CT catalyst powders (CeO2/TiO2) had been prepared with precipitation process. Taking expanded graphite based carbon/carbon composite (EGC) as matrix, CT powders were introduced on the EGC surface in the form of carbon-coated, and then CT/EGC composites of CT catalyst powders supported by EGC were obtained, and the property for treating phenol of the composite was studied. The results show that the treatment effect was best when the ratio of amount-of-substrance between Ce and Ti in CT catalyst powders was 0.002. Synergetic effect between CT photo catalytic performance and EGC adsorption was found when CT/EGC was used to treat the phenol solution, which enhanced the treatment effect of the composite towards phenol.
中图分类号 TQ165
所属栏目
基金项目 国家自然科学基金资助项目(21071107); 江苏省自然科学基金资助项目(BK2009534);常州市工业攻关项目(CE20090023)
收稿日期 2010/11/7
修改稿日期 2011/7/17
网络出版日期
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备注苗峙(1985-), 男, 江苏镇江人, 硕士研究生。
引用该论文: MIAO Zhi,CHEN Zhi-gang,LIU Cheng-bao,CHEN Feng,FU Meng,CHEN Hong. Preparation of Composite of CeO2/TiO2 Supported by Expanded Graphite-Activated Carbon and Its Treatment Ability to Phenol[J]. Materials for mechancial engineering, 2011, 35(11): 54～57
苗峙,陈志刚,刘成宝,陈丰,付猛,陈红. 膨胀石墨-活性炭负载CeO2/TiO2复合材料的制备及其处理苯酚的性能[J]. 机械工程材料, 2011, 35(11): 54～57
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参考文献
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