聚丙烯发泡成型技术的研究进展
Research Progress in Foaming and Molding Process of Polypropylene
摘 要
绿色环保的聚丙烯(PP)泡沫材料具有优异的物化、力学性能和易再生、易分解等环境友好特性, 其研发受到国内外的广泛关注。主要综述了近十年来用于制备PP泡沫材料的发泡成型工艺发展情况, 以及PP发泡效果和物理、力学性能的影响因素, 并对该领域今后的研究方向进行了展望。
发泡
制备技术
成型工艺
polypropylene (PP)
foam
preparation technology
molding process
Abstract
The green and environmental polypropylene (PP) foam material receives extensive interests at home and abroad because of its outstanding physical, chemical and mechanical properties as well as the environmental-friendly feature such as easy reused and decomposed and so on. The development of foaming and molding processes for fabricating PP foam materials and the effect factors of PP foamed effect, physical and mechanical properties are also summarized. The research orientation of the field in the future is also suggested.
中图分类号 TQ328.9
所属栏目 综述
基金项目 江苏省自然科学基金资助项目(BK2009379); 安徽理工大学青年教师科学研究基金资助项目
收稿日期 2011/7/20
修改稿日期 2012/3/21
网络出版日期
作者单位点击查看
备注杨继年(1981-), 男, 江苏东台人, 讲师, 博士。
引用该论文: YANG Ji-nian,XU Ai-qin. Research Progress in Foaming and Molding Process of Polypropylene[J]. Materials for mechancial engineering, 2012, 36(8): 1～5
杨继年,许爱琴. 聚丙烯发泡成型技术的研究进展[J]. 机械工程材料, 2012, 36(8): 1～5
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参考文献
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【2】刘培生.多孔材料引论[M].北京:清华大学出版社, 2004.
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【25】李迎春, 谭能超, 韩朝昱, 等.发泡工艺对交联发泡PP板材性能的影响[J].工程塑料应用, 2003, 31(7):25-27.
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【27】张雯, 林剑英, 王月香, 等.一步法交联模压发泡聚丙烯的力学性能[J].高分子材料科学与工程, 2011, 27(6):118-121.
【28】HAN D H, JANG J H, KIM H Y, et al. Manufacturing and foaming of high melt viscosity of polypropylene by using electron beam radiation technology[J].Polymer Engineering and Science, 2006, 46(4):431-437.
【29】大卫伊夫斯. 泡沫塑料手册[M].周南桥, 彭响方, 谢小莉, 等译.北京:化学工业出版社, 2006.
【30】ZHANG Z X, ZHANG S L, XIN Z X, et al. Polypropylene/waste ground rubber tire powder foams: a study of the relationship between processing and structure using supercritical carbon dioxide[J].E-Polymers, 2007, 132:1-12.
【31】ANTUNES M, REALINHO V, VELASCO J I. Study of the influence of the pressure drop rate on the foaming behavior and dynamic-mechanical properties of CO2 dissolution microcellular polypropylene foams[J].Journal of Cellular Plastics, 2010, 46(6):551-571.
【32】SPITAEL P, MACOSKO C W. Strain hardening in polypropylenes and its role in extrusion foaming[J].Polymer Engineering and Science, 2004, 44(11):2090-2100.
【33】RACHTANAPUN P, SELKE S E M, MATUANA L M. Effect of the high-density polyethylene melt index on the microcellular foaming of high-density polyethylene/polypropylene blends[J].Journal of Applied Polymer Science, 2004, 93(1):364-371.
【34】ZHAI W T, WANG H Y, YU J, et al. Foaming behavior of polypropylene/polystyrene blends enhanced by improved interfacial compatibility[J].Journal of Polymer Science, 2008, 46(16):1641-1651.
【35】XIN C L, HE Y D, LI Q C, et al. Crystallization behavior and foaming properties of polypropylene containing ultra-high molecular weight polyethylene under supercritical carbondioxide[J].Journal of Applied Polymer Science, 2011, 119(3):1275-1286.
【36】HUANG H X, XU H F. Preparation of microcellular polypropylene/polystyrene blend foams with tunable cell structure[J].Polymers for Advanced Technologies, 2011, 22(6):822-829.
【37】KAEWMESRI W, RACHTANAPUN P, PUMCHUSAK J. Effect of solvent plasticization on polypropylene microcellular foaming process and foam characteristics[J].Journal of Applied Polymer Science, 2008, 107(1):63-70.
【38】KIM S G, LEUNG S N, PARK C B, et al. The effect of dispersed elastomer particle size on heterogeneous nucleation of TPO with N2foaming[J].Chemical Engineering Science, 2011, 66(16):3675-3686.
【39】ZHANG P, WANG X J, YANG Y, et al. Bubble growth in the microcellular foaming of CO2/polypropylene solutions[J].Journal of Applied Polymer Science, 2010, 118(4):1949-1955.
【2】刘培生.多孔材料引论[M].北京:清华大学出版社, 2004.
【3】张旭锋, 王澜, 景森, 等.化学交联聚丙烯的性能及其发泡研究[J].中国塑料, 2005, 19(11):36-40.
【4】NAGUIB H E, PARK C B. A study on the onset surface melt fracture of polypropylene materials with foaming additives[J].Journal of Applied Polymer Science, 2008, 109(6):3571-3577.
【5】NAM G J, YOO J H, LEE J W. Effect of long-chain branches of polypropylene on rheological properties and foam-extrusion performances[J].Journal of Applied Polymer Science, 2005, 96(5):1793-1800.
【6】杨淑静, 宋国君, 杨超.硅烷接枝交联法制备发泡用高熔体粘度聚丙烯[J].塑料工业, 2006, 34(增1):95-97.
【7】信春玲, 洪粲, 何亚东.聚丙烯的流变性能及发泡性能研究[J].塑料, 2007, 36(1):51-55.
【8】JAHANI Y, BARIKANI M. Rheological and mechanical study of polypropylene ternary blends for foam application[J].Iranian Polymer Journal, 2005, 14(4):361-370.
【9】李立星, 张卫勤, 芦成, 等.聚丙烯挤出发泡材料的研究[J].现代塑料加工应用, 2008, 20(1):22-25.
【10】王向东, 刘本刚, 陈士宏, 等.聚丙烯挤出发泡中的关键技术—加工设备和成型工艺研究[J].中国塑料, 2006, 20(4):20-24.
【11】LEE P C, KAEWMESR W, WANG J, et al. Effect of die geometry on foaming behaviors of high-melt-strength polypropylene with CO2[J].Journal of Applied Polymer Science, 2008, 109(5):3122-3132.
【12】ZEPEDA S C, GONZALEZ N R, RODRIGUE D. Effects of postextrusion conditions on the morphology of foamed high-density polyethylene/polypropylene blends[J].Journal of Applied Polymer Science, 2007, 106(2):1215-1227.
【13】HWANG J J, ADACHI T, KUWABARA T, et al. Laminate model expressing mechanical properties of polypropylene foams having non-uniform cell-shape distributions[J].Materials Science and Engineering A, 2008, 487(1/2):369-376.
【14】张纯, 罗筑, 于杰, 等.二次开模注射成型微孔发泡PP工艺及其性能研究[J].中国塑料, 2005, 19(8):67-70.
【15】GUO M C, HEUZEY M C, CARREAU P J. Cell structure and dynamic properties of injection molded polypropylene foams[J].Polymer Engineering and Science, 2007, 47(7):1070-1081.
【16】廖永灵, 何力, 李良, 等.温度对微孔发泡PP材料冲击性能的影响[J].塑料工业, 2007, 35(11):46-48.
【17】何颖, 周丽, 龚维, 等.微孔发泡聚丙烯(PP)的性能的研究[J].现代机械, 2006, 24(3):67-68.
【18】POP-ILIEV R, LIU F, LIU G B, et al. Rotational foam molding of polypropylene with control of melt strength[J].Advances in Polymer Technology, 2003, 22(4):280-296.
【19】POP-ILIEV R. Processing of integral-skin cellular polymeric composites in rapid rotational foam molding[J].Acta Physica Polonica A, 2011, 120(2):292-297.
【20】NAKAI S, TAKI K, TSUJIMURA I, et al. Numerical simulation of a polypropylene foam bead expansion process[J].Polymer Engineering and Science, 2008, 48(1):107-115.
【21】ZHAI W T, KIM Y W, PARK C B. Steam-chest molding of expanded polypropylene foams-Part Ⅰ:DSC simulation of bead foam processing[J].Industrial & Engineering Chemistry Research, 2010, 49(20):9822-9829.
【22】ZHAI W T, KIM Y W, JUNG D W, et al. Steam-chest molding of expanded polypropylene foams-Part Ⅱ: mechanism of interbead bonding[J].Industrial & Engineering Chemistry Research, 2011, 50(9):5523-5531.
【23】BOUIX R, VIOT P, LATAILLADE J L. Polypropylene foam behaviour under dynamic loadings: strain rate, density and microstructure effects[J].International Journal of Impact Engineering, 2009, 36(2):329-342.
【24】VIOT P. Hydrostatic compression on polypropylene foam[J].International Journal of Impact Engineering, 2009, 36(7):975-989.
【25】李迎春, 谭能超, 韩朝昱, 等.发泡工艺对交联发泡PP板材性能的影响[J].工程塑料应用, 2003, 31(7):25-27.
【26】LIU H, CHUAI C Z, IQBAL M, et al. Improving foam ability of polypropylene by crosslinking[J].Journal of Applied Polymer Science, 2011, 122:973-980.
【27】张雯, 林剑英, 王月香, 等.一步法交联模压发泡聚丙烯的力学性能[J].高分子材料科学与工程, 2011, 27(6):118-121.
【28】HAN D H, JANG J H, KIM H Y, et al. Manufacturing and foaming of high melt viscosity of polypropylene by using electron beam radiation technology[J].Polymer Engineering and Science, 2006, 46(4):431-437.
【29】大卫伊夫斯. 泡沫塑料手册[M].周南桥, 彭响方, 谢小莉, 等译.北京:化学工业出版社, 2006.
【30】ZHANG Z X, ZHANG S L, XIN Z X, et al. Polypropylene/waste ground rubber tire powder foams: a study of the relationship between processing and structure using supercritical carbon dioxide[J].E-Polymers, 2007, 132:1-12.
【31】ANTUNES M, REALINHO V, VELASCO J I. Study of the influence of the pressure drop rate on the foaming behavior and dynamic-mechanical properties of CO2 dissolution microcellular polypropylene foams[J].Journal of Cellular Plastics, 2010, 46(6):551-571.
【32】SPITAEL P, MACOSKO C W. Strain hardening in polypropylenes and its role in extrusion foaming[J].Polymer Engineering and Science, 2004, 44(11):2090-2100.
【33】RACHTANAPUN P, SELKE S E M, MATUANA L M. Effect of the high-density polyethylene melt index on the microcellular foaming of high-density polyethylene/polypropylene blends[J].Journal of Applied Polymer Science, 2004, 93(1):364-371.
【34】ZHAI W T, WANG H Y, YU J, et al. Foaming behavior of polypropylene/polystyrene blends enhanced by improved interfacial compatibility[J].Journal of Polymer Science, 2008, 46(16):1641-1651.
【35】XIN C L, HE Y D, LI Q C, et al. Crystallization behavior and foaming properties of polypropylene containing ultra-high molecular weight polyethylene under supercritical carbondioxide[J].Journal of Applied Polymer Science, 2011, 119(3):1275-1286.
【36】HUANG H X, XU H F. Preparation of microcellular polypropylene/polystyrene blend foams with tunable cell structure[J].Polymers for Advanced Technologies, 2011, 22(6):822-829.
【37】KAEWMESRI W, RACHTANAPUN P, PUMCHUSAK J. Effect of solvent plasticization on polypropylene microcellular foaming process and foam characteristics[J].Journal of Applied Polymer Science, 2008, 107(1):63-70.
【38】KIM S G, LEUNG S N, PARK C B, et al. The effect of dispersed elastomer particle size on heterogeneous nucleation of TPO with N2foaming[J].Chemical Engineering Science, 2011, 66(16):3675-3686.
【39】ZHANG P, WANG X J, YANG Y, et al. Bubble growth in the microcellular foaming of CO2/polypropylene solutions[J].Journal of Applied Polymer Science, 2010, 118(4):1949-1955.
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