Preparation and Properties of Transparent Conducting Copper Nanowires Film
摘 要
用水合肼还原硝酸铜溶液的方法, 合成出高长径比的单晶铜纳米线, 用X射线粉末衍射仪、扫描电镜、透射电镜等对产物进行了分析, 研究了原料配比、水合肼加料方式等工艺因素对反应产物的影响; 用孔径为0.45 μm的注射式过滤膜滤出铜线并接触转移到透明商用手机贴膜表面制成铜纳米线膜, 用紫外-可见光谱仪和四探针表面电阻仪分别测试其可见光透射率和表面电阻。结果表明: 80 ℃时, 制备的铜纳米线长度大于40 μm, 直径小于100 nm; 铜纳米线膜的可见光透射率为50%, 平均方块电阻为26 Ω。
Abstract
The copper nanowires with high aspect ratio were prepared by chemical reduced Cu(NO3)2 solution with hydrazine hydrate. It was characterized through X-ray diffraction, scanning electron microscopy, transmission electron microscopy. The effect of reaction conditions on the product, such as the ratio of raw materials, the feeding mode of hydrazine hydrate, was investigated. The copper nanowires was filtered out by the syringe filter membrane with 0.45 μm pore diameter, and was transfered to a commercial optical film of mobile telephone to prepare the copper nanowires film. The luminousness and surface resistance of copper nanowires were measured by the ultraviolet spectrograph and the 4-points probe sheet resistance instrument. Results show that the obtained copper nanowires were single crystal with the length greater than 40 μm and the diameter less than 100 nm. The obtained conducting copper nanowire film shows 50% visiable light transmittance and the average surface resistance was 26 Ω.
中图分类号 TB383
所属栏目 新材料 新工艺
基金项目
收稿日期 2011/12/22
修改稿日期 2012/10/15
网络出版日期
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备注杨光(1978-), 男, 重庆人, 实验师, 硕士。
引用该论文: YANG Guang,ZHOU Wei-bin,WANG Qiang. Preparation and Properties of Transparent Conducting Copper Nanowires Film[J]. Materials for mechancial engineering, 2012, 36(12): 89~93
杨光,周伟斌,王强. 铜纳米线透明导电膜的制备与性能[J]. 机械工程材料, 2012, 36(12): 89~93
被引情况:
【1】王梦慧,易叶帆,鲍恩成,饶项炜,李晓涵,刘劲松,李子全, "铜层厚度及退火温度对ZnS/Cu/ZnS复合薄膜显微结构与性能的影响",机械工程材料 40, 47-51(2016)
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参考文献
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【2】AARON R, RATHMELL, BENJAMIN J W.The synthesis and coating of long, thin copper nanowires to make flexible, transparent conducting filmson plastic substrates[J].Advanced Materials, 2011, 23:4798-4803.
【3】KAEMPGEN M, DUESBERG G, ROTH S.Transparent and flexible carbon nanotube/polypyrrole and carbon nanotube/polyaniline pH sensors [J].App Surf Sci,2005,252:425-432.
【4】ZHOU Y C, MA L L, ZHOU J, et al. High contrast organic light-emitting devices with improved electrical characteristics[J].Appl Phys Lett,2006,88(23):233505-233507.
【5】SUKANTA D, HIGGINS T M, et al. Silver nanowire networks as flexible, transparent, conducting films: extremely high DC to optical conductivity ratios[J].ACS Nano,2009, 3(7):1767-1774.
【6】SUZETTE M K. Mineral commodity summaries 2009 [M].Washington:United States Government Printing Office,2009: 148-150.
【7】刘晓磊, 何建平, 周建华, 等.模板法电化学沉积超长铜纳米线制备及其性能[J].稀有金属材料与工程, 2007,36(12):2228-2231.
【8】张颖, 阎子峰.铜纳米线的制备、特性及应用(下)[J].石油化工, 2009, 38(10): 1031-1036.
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