负载氧化铟纳米颗粒多壁碳纳米管的制备与表征
Preparation and Characterization for Multi-walled Carbon Nanotubes Loading Indium Oxide Nanoparticles
摘 要
在NaOH溶液活化、混合酸(浓硫酸和浓硝酸混合)处理多壁碳纳米管(MWNTs)的基础上, 利用共沉淀法和后续热处理制备了多壁碳纳米管/氧化铟复合粉体, 并使用X射线衍射仪和电子显微镜表征了复合粉体的物相和形貌。结果表明: NaOH和混合酸处理能在多壁碳纳米管表面引入丰富的羟基和羧基等官能团, 且大大提高了碳纳米管的比表面积; 煅烧多壁碳纳米管/氢氧化铟前驱体后, 能够得到负载纳米氧化铟的多壁碳纳米管, 其中450 ℃煅烧的效果最好, 粒径为20~30 nm的纳米氧化铟颗粒均匀覆盖在碳纳米管表面上。
氧化铟
负载
纳米颗粒
carbon nanotube
indium oxide
loading
nanoparticle
Abstract
Based on multi-walled carbon nanotubes (MWNTs) treated by NaOH solution and mixture acid of concentratedsulfuricacid and concentrated nitric acid, MWNTs/indium oxide composite powders were prepared by co-deposition method and followed heat treatment, and phase and morphology were characterized by X-ray diffraction and electron microscopy. The results show that there are many oxygenated functional groups on MWNTs surface after it was treated by NaOH solution and mixture acid, and specific surface area of MWNTs was increased significantly. Furthermore, MWNTs could load indium oxide nanoparticles after the MWNTs/indium hydroxide precursor was calcined and the effect was best after the precursor was calcined at 450 ℃, and indium oxide nanoparticles with diameter of 20-30 nm were coated on MWNTs surface.
中图分类号 TB331
所属栏目 纳米材料
基金项目 湖南省自然科学基金资助项目(08JJ3100, 09JJ3095); 中国博士后科学基金资助项目(200801340, 20070420820); 湖南省教育厅科学研究基金资助项目(09A001)
收稿日期 2011/12/6
修改稿日期 2012/9/18
网络出版日期
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备注谢小缔(1989-), 女, 湖南娄底人, 硕士研究生。
引用该论文: XIE Xiao-di,CHEN Chuan-sheng,SONG Miao,KUANG Jia-cai,LU Li-jian,CAO Shi-yi,ZHAO Guang-jun,MEI Ya-ping,QIU Chen-yi. Preparation and Characterization for Multi-walled Carbon Nanotubes Loading Indium Oxide Nanoparticles[J]. Materials for mechancial engineering, 2013, 37(1): 81～84
谢小缔,陈传盛,宋淼,匡加才,陆立坚,曹时义,赵光俊,梅亚平,裘晨依. 负载氧化铟纳米颗粒多壁碳纳米管的制备与表征[J]. 机械工程材料, 2013, 37(1): 81～84
被引情况:
【1】吕宝华,李玉珍,黄健,任晓娟, "锡掺杂量对In2O3粉体光学性能和形貌的影响",机械工程材料 39, 49-51(2015)
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参考文献
【1】KAROUSIS N, TAGMATARCHIS N. Current progress on the chemical modification of carbon nanotubes[J].Chem Rev, 2010, 110(9): 5366-5397.
【2】WOAN K, PYRGIOTAKIS G, SIGMUND W. Photocatalytic carbon nanotube-TiO2 composites[J].Advanced Materials, 2009, 21(21): 2233-2239.
【3】WANG Z Y, SHI Z J, GU Z N. Synthesis of single-walled carbon nanotube/metal nanoparticle hybrid materials from potassium-filled nanotubes[J].Carbon, 2010, 48(2): 443-446.
【4】ANG L M, HOR T S A, XU G Q, et al. Decoration of actived carbon nanotubes with copper and nickel[J].Carbon, 2000, 38(3): 363-372.
【5】ANG L M, ANDY HOR T S, XU G Q, et al. Electroless plating of metals onto carbon nanotubes activated by a single-step activation method[J].Chem Mater, 1999, 11(8): 2115-2118.
【6】ARAI S, ENDO M, KANEKO N. Ni-deposited multi-walled carbon nanotubes by electrodeposition[J].Carbon, 2004, 42(3): 641-644.
【7】LIM J K, YUN W S, YOON M H, et al. Selective thiolation of single-walled carbon nanotubes[J].Synthetic Metals, 2003, 139(2): 521-527.
【8】CHEN C S, CHEN X H, YI B, et al. Zinc oxide nanoparticle decorated multi-walled carbon nanotubes and their properties[J].Acta Materialia, 2006, 54: 5401-5407.
【9】BI S, SU X J, HOU G L, et al. Microstructural characterization of alumina-coated multi-walled carbon nanotubes synthesized by hydrothermal crystallization[J]. Physica B: Condensed Matter, 2010, 405(16): 3312-3315.
【10】PARK K C, MAHIKO T, MORIMOTO S, et al. Hydrophobicity-induced selective covering of carbon nanotubes with sol-gel sheaths achieved by ultrasound assistance[J].Applied Surface Science, 2008, 254(22): 7438-7445.
【11】江奇, 卢晓英, 赵勇, 等. 活化条件对活性碳纳米管比表面积的影响[J].物理化学学报, 2006, 22(1): 43-47.
【12】PIERO E R, AZAS P, CACCIAGUERRA T, et al. KOH and NaOH activation mechanisms of multiwalled carbon nanotubes with different structural organisation[J].Carbon, 2005, 43(4): 786-795.
【2】WOAN K, PYRGIOTAKIS G, SIGMUND W. Photocatalytic carbon nanotube-TiO2 composites[J].Advanced Materials, 2009, 21(21): 2233-2239.
【3】WANG Z Y, SHI Z J, GU Z N. Synthesis of single-walled carbon nanotube/metal nanoparticle hybrid materials from potassium-filled nanotubes[J].Carbon, 2010, 48(2): 443-446.
【4】ANG L M, HOR T S A, XU G Q, et al. Decoration of actived carbon nanotubes with copper and nickel[J].Carbon, 2000, 38(3): 363-372.
【5】ANG L M, ANDY HOR T S, XU G Q, et al. Electroless plating of metals onto carbon nanotubes activated by a single-step activation method[J].Chem Mater, 1999, 11(8): 2115-2118.
【6】ARAI S, ENDO M, KANEKO N. Ni-deposited multi-walled carbon nanotubes by electrodeposition[J].Carbon, 2004, 42(3): 641-644.
【7】LIM J K, YUN W S, YOON M H, et al. Selective thiolation of single-walled carbon nanotubes[J].Synthetic Metals, 2003, 139(2): 521-527.
【8】CHEN C S, CHEN X H, YI B, et al. Zinc oxide nanoparticle decorated multi-walled carbon nanotubes and their properties[J].Acta Materialia, 2006, 54: 5401-5407.
【9】BI S, SU X J, HOU G L, et al. Microstructural characterization of alumina-coated multi-walled carbon nanotubes synthesized by hydrothermal crystallization[J]. Physica B: Condensed Matter, 2010, 405(16): 3312-3315.
【10】PARK K C, MAHIKO T, MORIMOTO S, et al. Hydrophobicity-induced selective covering of carbon nanotubes with sol-gel sheaths achieved by ultrasound assistance[J].Applied Surface Science, 2008, 254(22): 7438-7445.
【11】江奇, 卢晓英, 赵勇, 等. 活化条件对活性碳纳米管比表面积的影响[J].物理化学学报, 2006, 22(1): 43-47.
【12】PIERO E R, AZAS P, CACCIAGUERRA T, et al. KOH and NaOH activation mechanisms of multiwalled carbon nanotubes with different structural organisation[J].Carbon, 2005, 43(4): 786-795.
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