Effect of Different Aging Treatmrnts on Mechanical Properties and Intergranular Corrosion Properties of Al-0.42Mg-0.50Si-0.99Cu Alloy
摘 要
设计了一种成分为Al-0.42Mg-0.50Si-0.99Cu的新型工业型材用铝合金, 通过光学显微镜、透射电镜及万能拉伸试验机等研究了不同时效制度对其组织、力学性能以及晶间腐蚀性能的影响。结果表明: 合金在T6欠时效时晶界无明显析出相; T6峰时效时晶界析出物细小连续分布, 晶间腐蚀严重; 随时效时间延长, Q′相增多并逐渐粗化, 晶界析出物粗大呈非连续分布; 双级时效时晶内析出了大量Q′相, 晶界析出相球化且析出相之间的间距增大, 呈断续分布, 无析出带(PFZ)变宽, 抗腐蚀能力增强; 合金在T6峰时效时强度最高, 但晶间腐蚀敏感性大; 双级时效可在强度损失不大的情况下明显提高其耐蚀性。
Abstract
A new type of Al-Mg-Si-Cu aluminum alloy was designed, and the alloy composition was Al-0.42Mg-0.50Si-0.99Cu. The effects of different aging treatments on microstructure, mechanical properties and corrosion behavior were studied by optical microscopy, transmission electron microscopy and means of conventional tensile test. The results show that no distinct grain boundary precipitates were observed in T6 under-aging state and the grain boundary precipitates are small and continuously distributed in T6 peak-aging state, and intergranular corrosion was serious. With the increase of aging time, Q′ phase increased and coarsened, the grain boundary precipitates were coarsened obviously and sparsely distributed. In double aging state, there are plenty of Q′ precipitates in matrix, grain boundaries precipitates were spheroidization, the spacing between precipitated phases increased, precipitated phaseand were continuously distributed and the PFZ was broaden. In T6 peak-aging state, the alloy had the most serious intergranular corrosion tendency and had the highest strength, however, the corrosion resistance was obviously improved while tensile strength was a little decrease in double aging state.
中图分类号 TG164.2
所属栏目 新材料新工艺
基金项目 国家“863”高新技术研究资助项目(2003AA332070); 长沙市科技成果产业化资金专项资助项目(K0902002-11)
收稿日期 2012/4/6
修改稿日期 2013/3/15
网络出版日期
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备注尹德艳(1964-), 女, 湖南靖州人, 高级工程师, 博士研究生。
引用该论文: YIN De-yan,YANG Fu-liang,HUANG Ke,MA Kai. Effect of Different Aging Treatmrnts on Mechanical Properties and Intergranular Corrosion Properties of Al-0.42Mg-0.50Si-0.99Cu Alloy[J]. Materials for mechancial engineering, 2013, 37(5): 36~40
尹德艳,杨伏良,黄珂,马凯. 不同时效制度对Al-0.42Mg-0.50Si-0.99Cu合金力学性能和晶间腐蚀性能的影响[J]. 机械工程材料, 2013, 37(5): 36~40
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参考文献
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【3】RENDINGS K-H. Aluminum structures used in aerospace[J].Materials Science Forum, 1997, 242: 11-24.
【4】UCHIDA H , YOSHIDA H, HIRA H , et al. Development of high strength Al-Mg-Si-Cu alloy for aircraft[J].Sumtomo Light Metal Technical Reports, 1997, 38(1): 37-42.
【5】BERGSMA S C. High strength Mg-Si type aluminum alloy: European, 95105316. 4[P].1995-10-05.
【6】BERGSMAS C, KASSNERM E. New aluminum alloy AA6069[J].Materials Science Forum , 1996 , 217/222: 1801-1806.
【7】金 曼, 邵光杰.添加元素Cu对Al-Mg-Si合金析出相行为的影响[J].材料热处理学报, 2009, 30(3): 67-70.
【8】刘亚妮, 陈江华, 尹美杰, 等.自然时效和Cu含量对AlMgSi(Cu)合金时效硬化行为的影响[J].电子显微学报, 2010, 29(3): 280-285.
【9】GABER A, GAFFAR M A, MOSTAFA M S, et al.Precipitation kinetics of Al-1.12 Mg2Si-0.35Si and Al-1.07 Mg2Si-0.33Cu alloys[J].Journal of Alloys and Compounds, 2007, 429: 167-175.
【10】SVENNINGSEN G, LARSEN M H, NORDLIEN J H, et al. Effect of thermomechanical history on intergranular corrosion of extruded AlMgSi(Cu) model alloy[J]Corros Sci, 2006, 48: 258-272.
【11】OSAKI S, KINOSHITA K, NAGANUMA D. Intergranular corrosion and SCC properties of Al-Mg-Si alloy sheets[J].Journal of Japan Institute of Light Metals, 2003, 53(4): 157-162.
【12】LANG G, CATLE AF. Influence of copper, manganese and chromium, addtions on the extrudability of A1MgSi-alloys[J].Light Met Age, 1978, 36(1): 26-28.
【13】WEATHERLY G C, PEROVIE A, MUKHOPADHYAY N K. The precipitation of the Q phase in an AA6111 alloy[J].Metallurgical and MaterialsTransactions A, 2001, 32(4): 213-218.
【14】WANG X, POOLE W J, ESMAEILI S, et al. Precipitation strengthening of the aluminum alloy AA6111[J].Metallurgical and Materials Transactions A, 2004, 34(11): 2913-2924.
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