Combined Strengthened Layer of Al/TiB2 on Magnesium Alloy Surface by Laser Cladding and Its Properties
摘 要
以Al-TiB2复合粉体为强化层原料(其中铝为粘结剂), 采用Nd: YAG激光在镁钆系镁合金表面进行激光熔覆强化处理, 考察了TiB2含量对强化层组织、耐磨性及其与基体相容性的影响。结果表明: 强化层中铝元素与基体中的钆、钇等元素发生了原位反应, 生成了高温硬质相Al2Gd和Al2Y等金属间化合物, 且引入的强化相TiB2未发生分解, 与原位合成的金属间化合物及基体相容性良好, 但分布特点和结构差异显著; 当复合粉体中TiB2质量分数低于70%时, 强化层组织细小均匀; 强化层显微硬度随着TiB2含量的增加而增大, 比基体硬度提高4~6倍, 耐磨性能得到显著改善。
Abstract
A pulsed Nd: YAG laser was employed to strengthen the surface of Mg-Gd magnesium alloy with raw material of Al-TiB2 composite micro powders (Al powders as the binders) by cladding. The effects of TiB2 content on the microstructure and abrasive resistance of the strengthened layer, the compatibility between the strengthened layer and substrate were investigated. The results show that the in situ reaction generated between Al from the strengthened layer and elements of Gd, Y in Mg alloy substrate, and the intermetallic compounds such as Al2Gd and Al2Y were in-situ generated. Meanwhile, it was not found the decomposition of the strengthening phase TiB2. The compatibility among matrix, intermetallic compounds by in-situ synthesis and introduced strengthening phase TiB2 was fairly excellent. However, their characteristics of distribution and structures were different significantly. The strengthened layer had fine and uniform microstructure when the TiB2 content in composite powders was less than 70wt%. The overall microhardness of the strengthened layer increased with increasing of TiB2 content and improved up to 4-6 times compared with the substrate. Furthermore, the wear resistance improved dramatically.
中图分类号 TG178 TG146.2
所属栏目 材料性能及其应用
基金项目
收稿日期 2012/5/2
修改稿日期 2013/5/11
网络出版日期
作者单位点击查看
备注王继娜(1982-), 女, 河南洛阳人, 讲师, 博士。
引用该论文: WANG Ji-na,XU Kai-dong. Combined Strengthened Layer of Al/TiB2 on Magnesium Alloy Surface by Laser Cladding and Its Properties[J]. Materials for mechancial engineering, 2013, 37(8): 45~49
王继娜,徐开东. 镁合金表面激光熔覆Al/TiB2复合强化层及其性能[J]. 机械工程材料, 2013, 37(8): 45~49
被引情况:
【1】刘守法,夏祥春,王晋鹏, "搅拌摩擦加工工艺制备ZrO2颗粒增强镁基复合材料的组织与力学性能",机械工程材料 40, 35-38(2016)
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【2】张雄, 董选普, 陈东风. 镁合金表面铝合金化层组织及性能研究[J].功能材料, 2011, 42(5): 928-932.
【3】LU K, LU J. Surface nanocrystallization (SNC) of metallic materials presentation of the concept behind a new approach[J].Journal of Materials Science and Technology, 1999, 15(3): 193-197.
【4】叶宏, 王宾, 龙刚, 等. AZ31镁合金表面Al合金化层的制备与性能研究[J].表面技术, 2010, 39(1): 20-22.
【5】陈长军, 常庆明, 张敏, 等. ZM5镁合金表面激光Al合金化行为的研究[J].应用激光, 2007, 27(4): 261-268.
【6】HAZRA M, MONDAL A K, KUMAR S, et al. Laser surface cladding of MRI 153M magnesium alloy with (Al+Al2O3)[J].Surface & Coatings Technology, 2009, 203: 2292-2299.
【7】陈长军, 张敏, 常庆明, 等. 镁合金表面激光熔覆纳米三氧化二铝[J].中国激光, 2008, 35(11): 1752-1755.
【8】刘帅, 殷锦捷, 张娈, 等. 激光合金化对AZ91D镁合金力学性能的影响[J].热加工工艺, 2009, 38(2): 35-37.
【9】MAJUMDAR D J, MANNA I. Mechanical properties of a laser-surface-alloyed magnesium-based alloy (AZ91) with nickel[J].Scripta Materialia, 2010, 62: 579-581.
【10】李达, 钱鸣, 金昌, 等.AZ91D镁合金Al-Si粉末激光合金化及腐蚀性能[J].中国激光, 2008, 35(9): 1395-1400.
【11】MAJUMDAR D J, CHANDRA B R, GALUN R, et al. Mechanical properties of a laser-surface-alloyed magnesium-based alloy (AZ91) with nickel[J].Composites Science and Technology, 2003, 63(6): 771-778.
【12】MAJUMDAR D J, MAIWALD T, GALUN R, et al. Laser surface alloying of an Mg alloy with Al+Mn to improve corrosion resistance[J].Lasers in Engineering, 2002, 12(3): 147-169.
【13】DU B S, ZOU Z D, WANG X H, et al. Laser cladding of in situ TiB2/Fe composite coating on steel[J].Applied Surface Science, 2008, 254: 6489-6494.
【14】XU J, LIU W J. Wear characteristic of in situ synthetic TiB2 particulate-reinforced Al matrix composite formed by laser cladding[J].Wear, 2006, 260: 486-492.
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