先进航空钛合金中温钎焊技术的研究进展
Research Progress in Low Temperature Brazing Technology for Advanced Aeronautical Titanium Alloys
摘 要
从中温钎焊用钎料和中温钎焊技术两方面介绍了钎焊温度在800 ℃以下钛合金钎焊技术的研究进展, 总结了微量元素对银基、铝基、钛-锆基中温钎料熔点及润湿性的影响, 以及中温钎焊工艺对钛合金钎焊接头性能的影响; 并指出了先进航空钛合金中温钎焊技术的发展方向。
中温钎焊
微量元素
纳米钎料
advanced aeronautical titanium alloy
low temperature brazing
microelements
nano brazing filler metal
Abstract
The research progress in titanium alloys brazing at the temperatures below 800 ℃ is introduced from brazing filler metals and technology. The effects of microelements on the melting point and wettability of low temperature filler metals, such as Ag-based, Al-based and Ti-Zr based filler metals, as well as the influence of low temperature brazing process parameters on the properties of welded joints of titanium alloy are summarized. The future development direction of brazing technology for advanced aeronautical titanium alloy is pointed out.
中图分类号 TG425 TG454
所属栏目 综述
基金项目 国家自然科学基金青年基金资助项目(50905003); 2010年度北京市属高等学校人才强教深化计划“创新人才建设计划项目”(009000543111516)
收稿日期 2012/9/24
修改稿日期 2013/8/26
网络出版日期
作者单位点击查看
备注陶博浩(1988-), 男, 山东平度人, 硕士研究生。
引用该论文: TAO Bo-hao,LI Hong,LI Zhuo-xin,GUO Fu. Research Progress in Low Temperature Brazing Technology for Advanced Aeronautical Titanium Alloys[J]. Materials for mechancial engineering, 2013, 37(11): 1～5
陶博浩,李红,栗卓新,郭福. 先进航空钛合金中温钎焊技术的研究进展[J]. 机械工程材料, 2013, 37(11): 1～5
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参考文献
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【19】SISAMOUTH L, HAMDI M, ARIGA T. Investigation of gap filler ability of Ag-Cu-In brazing filler metals[J].Journal of Alloy and Compounds, 2010, 504: 325-329.
【20】TROY W C. Development of low temperature brazing alloys for titanium honeycomb sandwich materials[R].Ohio: Directorate of Materials and Processes Aeronautical Systems Divisions, 1963.
【21】DONG Z H, FAN H Y. Effect of Ag-based brazing filler metals on Ti alloy[J].Rare Metal Material and Engineering, 2004, 32(3): 14-18.
【22】李玉龙, 杨瑾, 禹业晓.钛及钛合金钎焊特点及现状[J].金属铸锻焊技术, 2011, 40(9): 130-136.
【23】TAKEMOTO T, NAKAMURA H, OKAMOTO I. Strength of titanium brazed joint with aluminum filler metals[J].Transactions of Japan Welding Reasearch Institute, 1990, 19(1): 45-49.
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【25】SHAPIRO A E, FLOM Y A. New aluminum-based cold-rolled and composite braze foils for brazing titanium below 700 ℃[C]// Proceeding of the 5th International Brazing and Soldering Conference. Las Vegas: [s.n], 2012: 427-432.
【26】SHAPIRO A E, FLOM Y A. Characterization of low-melting brazing foils of Al-Mg, Al-Ag-Cu and Al-Cu-Si alloys designed for joining titanium[C]// Proceeding of 9th International Brazing and Soldering Conference. Aachen: [s.n], 2010: 13-16.
【27】LEE J G, CHOI Y H, LEE J K. Low-temperature brazing of titanium by the application of a Zr-Ti-Ni-Cu-Be bulk metallic glass(BMG) alloy as a filler[J].Intermetallics, 2010, 18: 70-73.
【28】熊华平, 李红, 毛唯, 等.国际钎焊技术最新进展[J].焊接学报, 2011, 32(5): 108-112.
【29】JANCZAK-RUSCH J, PIGOZZI G, LEHMERT B, et.al. Deposition and utilization of nano-multilayered brazing filler systems designed for melting point depression[C]// Proceeding of the 5th International Brazing and Soldering Conference. Las Vegas: [s.n], 2012: 162-168.
【30】JANCZAK-RUSCH J. Approach for Al brazing with nano filler metals[C]// 7th International Congress Al-Brazing. Dusseldorf: [s.n.], 2012.
【31】TILLMANN W. New developments toward low-temperature joining of light-alloys[D].Germany: Dortmund University of Technology, 2011.
【32】ELREFAEY A, TILLMANN W. Correlation between microstructure, mechanical properties, and brazing temperature of steel to titanium joint [J].Journal of Alloys and Compounds, 2009, 487: 639-640.
【33】ELREFAEY A, TILLMANN W. Effect of brazing parameter on microstructure and mechanical properties of titanium joints[J].Materials and Processing Technology, 2009, 209: 4842-4849.
【34】DU Y C, SHIUE R K. Infrared brazing of Ti-6Al-4V using two silver-based braze alloys[J].Journal of Materials Processing Technology, 2009, 209: 5161-5166.
【35】TILLMANN W, OSMANDA A M, WOJARSKI L. Diffusion brazing of Al-alloys for hybrid structures[J].Quarterly Journal of the Japan Welding Society, 2009, 27(2): 179-182.
【36】ELREFAEY A, WOJAISKI L, TILLMANN W. Recent development in brazing titanium and titanium/steel joints using filler metal deposited by PVD technique[C]// Proceeding of the 5th International Brazing and Soldering Conference. Las Vegas: [s.n], 2012: 369-374.
【37】TILLMANN W, ELREFAEY A, WOJARSKI L. TLP brazing of aluminum to steel using Cu, Ni and Ti interlayer[C]// Proceeding of the 5th International Brazing and Soldering Conference. Las Vegas: [s.n], 2012: 493-498.
【38】YAN J, MA Z, ZHAO W, et.al. microstructure and mechanical behavior of intermetallic compounds at the interface between titanium and titanium alloys by hot-dipping and ultrasonically brazing[C]// Proceeding of 9th International Brazing and Soldering Conference. Aachen; [s.n], 2010: 201-205.
【39】陶博浩, 李红, 栗卓新.超声辅助激光钎焊铝基钎料在钛基合金表面润湿铺展性能的研究[C]//第十七次全国焊接学术会议论文集.长沙: [出版者不详], 2012: 500-505.
【2】黄张洪, 曲恒磊, 邓超, 等.航空用钛及钛合金的发展及应用[J].材料导报, 2011, 25(1): 102-107.
【3】ULUTAN D, OZEL T. Machining induced surface integrity in titanium and nickel: A review[J].International Journal of Machine Tools & Manufacture, 2011, 51: 250-180.
【4】CHAU E T F, FRIEND C M, ALLEN D M, et.al. A technical and economic appraisal of shape memory alloys for aerospace applications[J].Material Science and Engineering: A, 2006, 438/440: 589-592.
【5】宋鹏, 朱颖, 郭伟, 等.TiNi形状记忆合金和TC4的激光焊接裂纹产生机理分析[C]//2011全国计算机辅助焊接工程学术研讨会论文集.大连: [出版者不详], 2011: 174-179.
【6】祝文卉, 刘佳涛, 曾维慷.钛合金线性摩擦焊工艺试验及焊接精度研究[C]//第16届全国焊接年会论文集.镇江: [出版者不详], 2011: 495-498.
【7】AKAMAN E, DEMIR A, CANEL T, et.al. Laser welding of Ti6Al4V titanium alloys[J].Journal of Materials Processing Technology, 2009, 209: 3705-3713.
【8】YUE X, HE P, FENG J C, et.al. Microstructure and interfacial reactions of vacuum brazing titanium alloy to stainless steel using an AgCuTi filler metal[J].Materials Characterization, 2008, 59(12): 1721-1727.
【9】LI W, MA T, ZHANG Y, et.al. Microstructure characterization and mechanical properties of linear friction welded Ti-6Al-4V alloy[J].Advanced Engineering Materials, 2008, 10(1/2): 89-92.
【10】QIN Y, YU Z. Brazing of C/C composites and TC4 with inserting Cu/Mo foils[C]// Proceeding of the 5th International Brazing and Soldering Conference. Las Vegas: [s.n], 2012: 291-295.
【11】SHAPIRO A E, FLOM Y A. Brazing of titanium at temperatures below 800 ℃: review and prospective applications[R].Columbus, Ohio: Titanium Brazing Inc, 2007.
【12】MAZUMDER J, STEEN W M. Microstructure and mechanical properties of laser welded Ti-6Al-4V[J].Metallurgical Transaction: A, 1982, 13: 865-871.
【13】GANJEH E, KHORSAND H, SARKHOSH H, et.al. Investigation on braze joint strength and microstructure of Ti-CP with Ag and Ti base filler alloy[C]//Proceeding of the 5th International Brazing and Soldering Conference. Las Vegas: [s.n], 2012: 480-486.
【14】SHIUE R K, WU S K, CHEN Y T. Infrared brazing of Ti50Al50 and Ti-6Al-4V using two Ti-based filler metals[J].Intermetallics, 2008, 16: 1083-1089.
【15】TASHI R S, MOUSAVI S A A A. Mechanical and microstructure investigation of dissimilar vacuum brazing of Ti-6Al-4V and 316L stainless steel using pure copper braze alloy[C]// The 63th Annual Assembly & International Conference of the International Institute of Welding. Istanbul: [s.n], 2010: 797-802.
【16】LAI Z M, XUE S B, HAN X P, et.al. Study on microstructure and property of brazed joint of AgCuZn-X(Ga, Sn, In, Ni) brazing alloy[J].Rare Metal Material and Engineering, 2010, 39(3): 397-400.
【17】薛松柏, 钱乙余, 胡晓萍.元素锡、铟在银基钎料中的作用及其机理[J].焊接, 1998(11): 28-31.
【18】张冠星, 龙伟民.微量元素Ce、Sb、Li对银基钎料润湿和抗氧化性能的影响[J].金属铸锻焊技术, 2011, 40(13): 4-6.
【19】SISAMOUTH L, HAMDI M, ARIGA T. Investigation of gap filler ability of Ag-Cu-In brazing filler metals[J].Journal of Alloy and Compounds, 2010, 504: 325-329.
【20】TROY W C. Development of low temperature brazing alloys for titanium honeycomb sandwich materials[R].Ohio: Directorate of Materials and Processes Aeronautical Systems Divisions, 1963.
【21】DONG Z H, FAN H Y. Effect of Ag-based brazing filler metals on Ti alloy[J].Rare Metal Material and Engineering, 2004, 32(3): 14-18.
【22】李玉龙, 杨瑾, 禹业晓.钛及钛合金钎焊特点及现状[J].金属铸锻焊技术, 2011, 40(9): 130-136.
【23】TAKEMOTO T, NAKAMURA H, OKAMOTO I. Strength of titanium brazed joint with aluminum filler metals[J].Transactions of Japan Welding Reasearch Institute, 1990, 19(1): 45-49.
【24】CHANG S Y, TSAO L C, LEI Y H, et.al. Brazing of 6061 aluminum alloy/Ti-6Al-4V using Al-Si-Cu-Ge filler metals[J]. Journal of Materials Processing Technology, 2012, 212: 8-14.
【25】SHAPIRO A E, FLOM Y A. New aluminum-based cold-rolled and composite braze foils for brazing titanium below 700 ℃[C]// Proceeding of the 5th International Brazing and Soldering Conference. Las Vegas: [s.n], 2012: 427-432.
【26】SHAPIRO A E, FLOM Y A. Characterization of low-melting brazing foils of Al-Mg, Al-Ag-Cu and Al-Cu-Si alloys designed for joining titanium[C]// Proceeding of 9th International Brazing and Soldering Conference. Aachen: [s.n], 2010: 13-16.
【27】LEE J G, CHOI Y H, LEE J K. Low-temperature brazing of titanium by the application of a Zr-Ti-Ni-Cu-Be bulk metallic glass(BMG) alloy as a filler[J].Intermetallics, 2010, 18: 70-73.
【28】熊华平, 李红, 毛唯, 等.国际钎焊技术最新进展[J].焊接学报, 2011, 32(5): 108-112.
【29】JANCZAK-RUSCH J, PIGOZZI G, LEHMERT B, et.al. Deposition and utilization of nano-multilayered brazing filler systems designed for melting point depression[C]// Proceeding of the 5th International Brazing and Soldering Conference. Las Vegas: [s.n], 2012: 162-168.
【30】JANCZAK-RUSCH J. Approach for Al brazing with nano filler metals[C]// 7th International Congress Al-Brazing. Dusseldorf: [s.n.], 2012.
【31】TILLMANN W. New developments toward low-temperature joining of light-alloys[D].Germany: Dortmund University of Technology, 2011.
【32】ELREFAEY A, TILLMANN W. Correlation between microstructure, mechanical properties, and brazing temperature of steel to titanium joint [J].Journal of Alloys and Compounds, 2009, 487: 639-640.
【33】ELREFAEY A, TILLMANN W. Effect of brazing parameter on microstructure and mechanical properties of titanium joints[J].Materials and Processing Technology, 2009, 209: 4842-4849.
【34】DU Y C, SHIUE R K. Infrared brazing of Ti-6Al-4V using two silver-based braze alloys[J].Journal of Materials Processing Technology, 2009, 209: 5161-5166.
【35】TILLMANN W, OSMANDA A M, WOJARSKI L. Diffusion brazing of Al-alloys for hybrid structures[J].Quarterly Journal of the Japan Welding Society, 2009, 27(2): 179-182.
【36】ELREFAEY A, WOJAISKI L, TILLMANN W. Recent development in brazing titanium and titanium/steel joints using filler metal deposited by PVD technique[C]// Proceeding of the 5th International Brazing and Soldering Conference. Las Vegas: [s.n], 2012: 369-374.
【37】TILLMANN W, ELREFAEY A, WOJARSKI L. TLP brazing of aluminum to steel using Cu, Ni and Ti interlayer[C]// Proceeding of the 5th International Brazing and Soldering Conference. Las Vegas: [s.n], 2012: 493-498.
【38】YAN J, MA Z, ZHAO W, et.al. microstructure and mechanical behavior of intermetallic compounds at the interface between titanium and titanium alloys by hot-dipping and ultrasonically brazing[C]// Proceeding of 9th International Brazing and Soldering Conference. Aachen; [s.n], 2010: 201-205.
【39】陶博浩, 李红, 栗卓新.超声辅助激光钎焊铝基钎料在钛基合金表面润湿铺展性能的研究[C]//第十七次全国焊接学术会议论文集.长沙: [出版者不详], 2012: 500-505.
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