镁金属提炼和精炼工艺的研究进展
Research Progress in Magnesium Production and Refining Processes
摘 要
主要综述了电解法(DOW、Farben、Magnola三种工艺)和热还原法(Pidgeon、Bolzano、Magnetherm三种工艺)提炼镁的工艺原理、流程及特点, 并进行了评述; 对目前镁金属的三种精炼工艺进行了比较, 认为采用氧化镁泡沫陶瓷过滤器精炼镁金属是一种非常有前景的方法。
热还原法
镁
氧化镁泡沫陶瓷
electrolytic process
thermal reduction process
magnesium
MgO ceramic foam
Abstract
The principle, technology process and characteristics of magnesium production processes are mainly summarized and discussed simply, the production processes including electrolysis process (DOW, Farben and Magnola processes) and thermal reduction process (Pidgeon, Bolzano and Magnetherm processes). By comparing with three kind of refining processes of magnesium at present, it is concluded that refining magnesium metal using MgO ceramic foam filters will be a promising methods in future.
中图分类号 TG146.2
所属栏目 综述
基金项目 国家科技支撑计划项目(2008BAE63B02; 2008BAE63B01)
收稿日期 2012/11/22
修改稿日期 2013/9/21
网络出版日期
作者单位点击查看
备注张文政(1974-), 男, 辽宁大连人, 讲师, 博士。
引用该论文: ZHANG Wen-zheng,LIU Zheng,MAO Ping-li. Research Progress in Magnesium Production and Refining Processes[J]. Materials for mechancial engineering, 2013, 37(11): 12～16
张文政,刘正,毛萍莉. 镁金属提炼和精炼工艺的研究进展[J]. 机械工程材料, 2013, 37(11): 12～16
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参考文献
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【2】刘正, 张奎, 曾小勤.镁基轻质合金理论基础及其应用[M].北京: 机械工业出版社, 2002.
【3】GAO Feng, NIE Zuo-ren, WANG Zhi-hong, et al. Assessing environmental impact of magnesium production using Pidgeon process in China[J].Trans Nonferrous Met Soc China: English Edition, 2008, 18(3): 749-754.
【4】ELIEZER E, AGHIONE E, FROES F H. Magnesium science technology and applications[J].Advanced Performance Materials, 1998, 5(3): 201-212.
【5】WU Guo-hua, XIE Min, ZHAI Chun-quan, et al. Purification technology of AZ91 magnesium alloy wastes[J].Trans Nonferrous Met Soc China: English Edition, 2003, 13(6): 1260-1264.
【6】朱祖武, 曹黎华.国内皮江法炼镁技术的缺陷与改进途径[J].南昌高专学报, 2007(2): 92-94.
【7】GRJOTHEIN K, KVANDE H, LI Qing-feng, et al. Metal production by molten salt eletrolysis[M].Beijing: China University of Mining and Technology Press, 1998.
【8】SHARMA R A. Electrolytic production process for magnesium and its alloys: US, US5593566 [P].1997-01-14.
【9】于旭光, 邱竹贤.镁工业生产及应用的现状和展望[J].材料与冶金学报, 2003(9): 189-192.
【10】CAMERON A M. Advances in thermal reduction technology[J].Light Metals, 1997(8): 579-602.
【11】RAMAKRISHNAN S, KOLTUN P. Global warming impact of the magnesium produced in China using the Pidgeon process[J].Resouce, Conservation and Recycling, 2004, 42(1): 49-64.
【12】师昌绪, 李恒德, 王淀佐, 等.加速我国金属镁工业发展的建议[J].材料导报, 2001, 15(4): 5-6.
【13】ZUO Tie-yong, DU Wen-bo. The developing strategy of Chinese magnesium and magnesium alloy[J].Journal of Guangdong Non-Ferrous Metals, 2005, 15(2): 1-3.
【14】钟胜.氧化镁真空碳热还原研究[D].昆明: 昆明理工大学, 1999.
【15】伍上元, 周向阳, 李劼, 等.原镁直接熔炼生成镁合金压铸件的工艺进展[J].材料导报, 2003, 17 (3): 20-23.
【16】刘正, 张奎, 臧境淳, 等.粗镁精炼、合金化及连续铸造熔炼镁合金的方法: 中国, CN1524973A[P].2004-09-01.
【17】LIU Zheng, WANG Zhong-guang, WANG Yue, et al. Application and developing tendency of magnesium die casting alloys in automobile industry[J].Special Casting & Nonferrous Alloys, 1999, 19(5): 55-58.
【18】翟春泉, 丁文江, 徐小平.新型无公害镁合金熔剂的研制[J].特种铸造及有色合金, 1997(4): 48-50.
【19】ONG S K, KOH T H, NEE A Y C. Assessing the environmental impact of materials processing techniques using an analytical hierarchy process method[J].Journal of Materials Processing Technology, 2001, 113: 424-431.
【20】GAO Hong-tao, WU Guo-hua, DING Wen-jiang, et al. Purifying effect of new flux on magnesium alloy[J].Trans Nonferrous Met Soc China: English Edition, 2004, 14(3): 530-536.
【21】GAO Hong-tao , WU Guo-hua , FAN Yu, et al. Effects of purification fluxes containing boride on AZ91 alloy[J].Materials Science Forum, 2005, 25/30: 488-489.
【22】TIPHAINE D. State of the art in the refining and recycling of magnesium[J].Materials Science Forum, 2007, 546/549: 25-36.
【23】NI Hong-jun, SUN Bao-de, JIANG Hai-yan, et al. Effects of rotating impeller degassing on microstructure and mechanical properties of the A356 scraps[J].Materials Science and Engineering: A, 2003, 352: 294-299.
【24】MORDIKE B L, EBERT T. Magnesium properties application potential[J].Mater Sci Eng: A, 2001, 302: 37-45.
【25】WU Guo-hua, KANG Seung-hun, YOU Bong-sun. Effects of non-flux purification on the microstructure and mechanical properties of AZ31+xCa Mg alloy[J].Material Science Forum, 2007, 546/549: 217-220.
【26】乐启炽, 崔建忠, 赵晓红.镁合金熔体过滤净化工艺研究[J].特种铸造及有色合金, 2005, 25(6): 333-334.
【27】黄伯杰, 王薇薇, 王耀臣.泡沫陶瓷过滤技术在高标准镁合金铸件生产中的应用研究[J].特种铸造及有色合金, 1995(2): 19-21.
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