GC-MS Determination of 5 Aromatic Components in Tobacco
摘 要
用气相色谱-质谱法测定了烟叶中2-甲基四氢呋喃-3-酮(面包酮)、β-二氢大马酮、橙花基丙酮、β-紫罗兰酮和β-芳樟醇等5种致香成分的含量,以萘为内标物,采用内标校正曲线法进行分析。用DB-5MS石英毛细管柱、流量为1 mL·min-1、程序升温(50 ℃~250 ℃)进行分析。采用电子轰击电离源(180 ℃,70 eV)和选择离子监测,5种致香成分及内标的选择离子(m/z)为43,177,43,177,128和71。上述致香成分的线性范围分别为0.15~50,1.2~55,1.8~75,0.8~60,0.8~60 mg·L-1,回收率为95.3%~106.6%。
Abstract
Contents of 5 aromatic components, i.e., 2-methyl-tetrahydrofuran-3-one, β-damascone, nerylacetone, β-ionone and β-linalool, in tobacco were determined by GC-MS. Naphthalene was used as internal standard and the internal standard calibration curve was used in the determination. Quartz capillary chromatographic column DB-5MS was used for separation of the analytes with programmed temperature elevation from 50 ℃ to 250 ℃, with flow-rate of 1 mL·min-1. Electron bombardment ionization (180 ℃, 70 eV) and SIM mode were adopted in MS, with the selected ions for the 5 components of (m/z) 43, 177, 43, 177, 128, 71. Ranges of linearity of the 5 components were found between 0.15-50, 1.2-55, 1.8-75, 0.8-60, 0.8-60 mg·L-1 respectively. Tests for recovery were made by addition of standard solutions of the 5 components to a tobacco sample, values of recovery found were in the range of 95.3%-106.6%.
中图分类号 O652.6
所属栏目
基金项目 中国烟草总公司科技重大专项(110200902008);云南中烟工业公司项目(2009JC03)资助
收稿日期 2010/6/14
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备注刘巍(1972-),男,云南昆明人,高级工程师,主要从事烟草和烟气化学研究。
引用该论文: LIU Wei,CUI Zhu-wen,KONG Wei-song,JIN Yong-can,WANG Lan,CHEN Yong-kuan. GC-MS Determination of 5 Aromatic Components in Tobacco[J]. Physical Testing and Chemical Analysis part B:Chemical Analysis, 2011, 47(9): 1095~1097
刘巍,崔柱文,孔维松,金永灿,王岚,陈永宽. 气相色谱-质谱法测定烟叶中5种致香成分[J]. 理化检验-化学分册, 2011, 47(9): 1095~1097
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参考文献
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