ICP-AES Determination of Potassium, Sodium, Calcium, Magnesium and Sulfate in Carnallite
摘 要
样品用蒸馏水溶解,电感耦合等离子体原子发射光谱法同时测定光卤石中钾、钠、钙、镁和硫酸根。选择波长为766.5,330.2,317.9,279.8,181.9 nm 5条谱线依次作为测定钾、钠、钙、镁和硫的分析线。钾、钠、钙、镁和硫的方法检出限(3s)依次为0.8,1.6,0.8,0.8,2.4 mg·L-1。应用此法测定了光卤石样品中5种元素的含量,回收率在97.2%~102.1%之间,相对标准偏差(n=10)小于3.5%。
Abstract
Sample of carnallite was dissolved in distilled water, an aliquot of the sample solution was taken and used for ICP-AES determination of contents of K, Na, Ca, Mg and SO42-. Spectral lines with wavelengths of 766.5, 330.2, 317.9, 279.8 and 181.9 nm were selected as analytical lines for the determination of K, Na, Ca, Mg and S respectively. Detection limits (3s) found were (mg·L-1) 0.8 (K), 1.6 (Na), 0.8 (Ca), 0.8 (Mg) and 2.4 (S). The proposed method was used in the analysis of sample of carnallite, giving values of recovery of the 5 elements in the range of 97.2%-102.1%and values of RSD′s (n=10) less than 3.5%.
中图分类号 O657.31
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收稿日期 2010/8/17
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备注靳芳(1973-),女,青海乐都人,工程师,主要从事盐样及卤水样的分析。
引用该论文: JIN Fang,WANG Hong-bin,WANG Ying. ICP-AES Determination of Potassium, Sodium, Calcium, Magnesium and Sulfate in Carnallite[J]. Physical Testing and Chemical Analysis part B:Chemical Analysis, 2011, 47(10): 1198~1199
靳芳,王洪彬,王英. 电感耦合等离子体原子发射光谱法测定光卤石矿中钾、钠、钙、镁和硫酸根[J]. 理化检验-化学分册, 2011, 47(10): 1198~1199
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参考文献
【1】翁润生.矿物与岩石辞典[M].北京:化学工业出版社, 2007,4:105.
【2】潘海燕,姚振琴.ICP-OES测定降水中钾、钠、钙、镁、金属离子[J].仪器仪表与分析监测, 2009,3:45-46.
【3】阳国运,唐裴颖.电感耦合等离子体发射光谱法测定地表水和地下水中的硫酸根[J].岩矿测试, 2009,28(2):176-178.
【4】肖昭荣,童成举,董迈青.ICP-AES测定钾石盐中的硫酸根离子[J].光谱实验室, 2009,26(2):294-296.
【2】潘海燕,姚振琴.ICP-OES测定降水中钾、钠、钙、镁、金属离子[J].仪器仪表与分析监测, 2009,3:45-46.
【3】阳国运,唐裴颖.电感耦合等离子体发射光谱法测定地表水和地下水中的硫酸根[J].岩矿测试, 2009,28(2):176-178.
【4】肖昭荣,童成举,董迈青.ICP-AES测定钾石盐中的硫酸根离子[J].光谱实验室, 2009,26(2):294-296.
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