FAAS Determination of Metal Elements in Crops Grown in Coal Gangue Soil
摘 要
采用干灰化法消化样品,火焰原子吸收光谱法测定了煤矸石土种植植物中的钙、镁、铜、锌、铁、锰等6种金属元素的含量。6种元素均在一定的质量浓度范围内与其吸光度呈线性关系,方法的检出限(3s)在0.002~0.017 mg·L-1之间。回收率在96.8%~106.1%之间,相对标准偏差(n=6)在0.17%~4.25%之间。方法用于煤矸石土和沙土上种植的玉米、蚕豆和豌豆中6种金属元素含量的测定,结果表明:煤矸石土上种植粮食中6种元素的含量均高于沙土上种植的, 矸石土壤种植的蚕豆中镁含量较高,豌豆中铁和锰含量较高。
Abstract
The sample of crops grown in coal gangue soil was treated by dry ashing method, and the contents of 6 elements, including Ca, Mg, Cu, Zn, Fe and Mn, were determined by FAAS. Linear relationships between values of absorption and mass concentration of 6 elements were obtained in the definite ranges, with detection limits (3s) in the range of 0.002-0.017 mg·L-1. Values of recovery and RSD′s (n=6) found were in the ranges of 96.8%-106.1% and 0.17%-4.25% respectively. The proposed method was applied to the determination of the 6 elements in corn, horsebean and pea grown in coal gangue soil and sandy soil, and the result indicated that the contents of 6 elements in crops grown in coal gangue soil were higher than those grown in sandy soil. Relatively higher contents of Mg were found in broad-bean, and of Fe as well as Mn were found in pea, which were grown in coal gangue soil.
中图分类号 O657.31
所属栏目 工作简报
基金项目 绵阳师范学院科研基金(hx2010-2011-11)
收稿日期 2011/2/11
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备注李松(1970-),四川筠连人,副教授,主要研究方向为分析化学及催化化学。
引用该论文: LI Song,LI Guo-lan,LI Lin-bo,YANG Tao,XU Yan-jun. FAAS Determination of Metal Elements in Crops Grown in Coal Gangue Soil[J]. Physical Testing and Chemical Analysis part B:Chemical Analysis, 2012, 48(3): 325~327
李松,黎国兰,李林波,杨涛,许艳君. 火焰原子吸收光谱法测定煤矸石土种植的农作物中金属元素含量[J]. 理化检验-化学分册, 2012, 48(3): 325~327
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参考文献
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