Application of High Energy Polarized Energy Dispersion-XRFS to Analysis of Ancient Ceramics
摘 要
以国家地质标准样品制作工作曲线,用粉末压片法制样,高能偏振能量色散X射线荧光光谱法测定古陶瓷中包括15种稀土元素在内的56种元素,通过对6个陶瓷胎标准样品分析,结果表明:钪、钒、锰、铬、锌、镓、锗、铷、锶、钇、锆、铌、镉、锡、铯、钡、镧、铈、镨、钕、钆、钬、铒、铥、镱、镥、钍、铀等28种痕量元素测定值均在参考值的不确定度3~4倍范围,其他痕量元素如镍、铜、钼、锑、钐、铕、铽、铪、铅、铋等10种元素合格率为50%~83%。钠、镁、钾、钙、铁的氧化物和钛等6个项目均在允许误差范围内。氯、硫、磷的合格率均为66.6%。二氧化硅和三氧化二铝测定值和波长色散X射线荧光光谱熔融法测定结果相比,绝对误差分别在0.95%~4.46%和0.60%~1.66%之间。
Abstract
Fifty-six elements including 15 rare earth elements in ancient ceramics were determined by high energy polarized energy dispersion (HEPED)-XRFS. The sample was prepared by technique of pressed powder pellets using China national geological certified reference materials for preparation of working standard curves. The proposed method was applied to the analysis of 6 standard samples of ceramics body. As shown by the analytical results, the determined values of Sc, V, Mn, Cr, Zn, Ga, Ge, Rb, Sr, Y, Zr, Nb, Cd, Sn, Cs, Ba, La, Ce, Pr, Nd, Gd, Ho, Er, Tm, Yb, Lu, Th and U were in conformity with the certified values having their uncertainties in the range of 3 to 4 times of certainties of the certified values; among the determined values of the 10 trace elements, i.e., Ni, Cu, Mo, Sb, Sm, Eu, Tb, Hf, Pb and Bi, 50% to 83% were accepted; values of Ti and oxides of Na, Mg, K, Ca, Fe and Ti obtained were within the tolerances of these elements; 66.6% of the determined values of Cl, S and P were accepted; absolute errors between the determined values of SiO2 and Al2O3 found by this method and by WDXRFS method (with sample preparation by fusion) were in the ranges of 0.95%-4.46% and 0.60%-1.66% respectively.
中图分类号 O657.34
所属栏目 试验与研究
基金项目 国家重点基础研究发展计划973计划项目(2012CB720900)
收稿日期 2011/8/15
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备注盛成(1978-),女,浙江瑞安人,高级工程师,主要研究方向为荧光光谱分析。
引用该论文: SHENG Cheng,ZHUO Shang-jun,JI Ang,SHEN Ru-xiang. Application of High Energy Polarized Energy Dispersion-XRFS to Analysis of Ancient Ceramics[J]. Physical Testing and Chemical Analysis part B:Chemical Analysis, 2012, 48(6): 629~633
盛成,卓尚军,吉昂,申如香. 高能偏振能量色散X射线荧光光谱法分析古陶瓷[J]. 理化检验-化学分册, 2012, 48(6): 629~633
被引情况:
【1】王斌,张江峰,蒋小良,温健昌,钟康华, "碱熔-电感耦合等离子体原子发射光谱法测定陶瓷色釉料中的15种稀土元素",理化检验-化学分册 51, 707-709(2015)
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参考文献
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