气相色谱-质谱法分析树苔浸膏的成分
GC-MS Analysis of Treemoss Concrete for Its Components
摘 要
采用分子蒸馏法对树苔浸膏进行分级分离,用气相色谱-质谱法对各级馏分进行定性和定量分析。结果表明:三级馏分共鉴定出55种成分,主要成分是苔黑酚单甲醚、分歧扁枝衣素单甲醚、扁枝衣酸乙酯、柔扁枝衣酸甲酯、β-苔黑酚羧酸甲酯、赤星衣酸乙酯、苔黑酚羧酸乙酯、柔扁枝衣酸乙酯、棕榈酸乙酯、油酸乙酯、亚麻酸乙酯和亚油酸乙酯。
分子蒸馏
化学成分
Treemoss concrete
Molecular distillation
Chemical components
Abstract
Sample of treemoss concrete was graded by molecular distillation, and the graded distillates were introduced into the instrument and analyzed qualitatively and quantitatively. The results showed that 55 compounds in 3 grades of distillates were indentified, and the main compounds found were the following: 3-methoxy-5-methylphenol, divarinol monomethyl ether, ethyl everninate, methyl divaricatinate, benzoic acid, 2,4-dihydroxy-3,6-dimethyl-methyl ester, ethyl hematommate, ethyl 2,4-dihydroxy-6-methylbenzoate, ethyl divaricatinate, ethyl palmitate, ethyl oleate, linolenic acid ethyl ester and linoleic acid ethyl ester.
中图分类号 O657.63
所属栏目 工作简报
基金项目
收稿日期 2011/10/15
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备注朱怀远(1980-),男,江苏邳州人,工程师,硕士,研究方向为烟草化学。
引用该论文: ZHU Huai-yuan,ZHUANG Ya-dong,ZHANG Ying,WAN Min,LIU Xian-jun. GC-MS Analysis of Treemoss Concrete for Its Components[J]. Physical Testing and Chemical Analysis part B:Chemical Analysis, 2012, 48(11): 1326～1330
朱怀远,庄亚东,张映,万敏,刘献军. 气相色谱-质谱法分析树苔浸膏的成分[J]. 理化检验－化学分册, 2012, 48(11): 1326～1330
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参考文献
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【2】刘强,冒德寿,侯春,等.树苔浸膏、净油香味成分分析及其在卷烟中的应用［J］.烟草科技, 2005(3):18-21.
【3】ROELOF T H, NICOLAI P, PIET C T, et al. Qualitative analysis of the odoriferous fraction of oakmoss (Evernia prunastri)［J］. J Agric Food Chem, 1975,23(5):950-957.
【4】吴丹,宋国新,陈正夫,等.烟用浸膏的挥发性成分的SDE/GC-MS分析研究［J］.分析测试学报, 2005,24(6):369-371.
【5】祝顺琴,谈锋.分子蒸馏技术在天然产物分离中的应用［J］.精细化工, 2004,21(1):46-50.
【6】傅红,裘爱咏.分子蒸馏法制备鱼油多不饱和脂肪酸［J］.无锡轻工大学学报, 2002,21(6):617-621.
【7】马传国,王兴国,张根旺,等.分子蒸馏对高酸值花椒籽油脱酸的初步探讨［J］.中国油脂, 2001,26(3):50-52.
【8】陈立军,陈焕钦.分子蒸馏技术及其应用的研究进展［J］.香精香料化妆品, 2004(5):22-26.
【9】TERRY I A, STEVEN C C. Purification of meadow foam monoestolide from the polyestolide industrial［J］. Crops and Products Volume, 2004,19(2):113-118.
【10】VANDENDOOL H, KRATZ P D. A generalization of the retention index system including linear temperature programmed gas-liquid partition chromatography［J］. J Chromatogr, 1963,8:463-471.
【11】SANCHEZ M L, BATS J P, MOULINES J. Thermal hydrolysis of the main depsides and depsidones contained in the lichen used in perfumery［J］. Riv Ital EPPOS, 1997(2):101-109.
【12】SURBURG H, PANTEN J. Common fragrance and flavor materials: preparation properties, and uses［M］. 5th ed. Weinheim: Wiley-VCH, 2006:177-181.
【13】JOULAIN D, TABACCHI R. Lichen extracts as raw materials in perfumery, Part 2: treemoss［J］. Flav Fragr J, 2009,24(3):105-116.
【14】TOLEDO M F J, CASTELLANO A G, ROSAS F E, et al. Identification and quantitation of allelochemicals from the lichen lethariella canariensis: phytotoxicity and antioxidative activity［J］. J Chem Ecol, 2003,29(9):2049-2071.
【15】孙汉董.地衣香料的研究进展［J］.香精香料化妆品, 1990(1):1-10.
【16】JOULAIN D, TABACCHI R. Lichen extracts as raw materials in perfumery, Part 1: oakmoss［J］. Flav Fragr J, 2009,24(2):49-61.
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