燃料油与典型渤海原油指纹特征差异性初探
Preliminary Study on Difference of Fingerprint Characteristics Between Fuel Oil and Typical Crude Oil from Bohai Sea
摘 要
试验选3种燃料油和典型渤海原油SZ36-1进行了特征信息和指纹特征的比较研究。结果表明：燃料油和典型原油之间,nC17/姥鲛烷、nC18/植烷特征比值的差异性较为显著;多环芳烃含量的差异并不能体现燃料油和典型原油的本质特性;所选取的33个生物标志物特征比值中69.70%体现了燃料油之间的相似性,其中30.30%的特征比值进一步体现了燃料油与典型原油的差异性,可作为燃料油和原油油种鉴别的重点筛查指标。
典型原油
生物标志物
指纹
差异性
Fuel oil
Typical crude oil
Biomarker
Fingerprint
Difference
Abstract
The characteristic information and fingerprints between 3 kinds of fuel oil and the typical oil SZ36-1 from Bohai Sea were discussed. As shown by the results of GC-MS study, remarkable differences of characteristic ratios of nC17/Pr and nC18/Ph were found between the 3 fuel oil and the typical Bohai crude oil; the differences of contents of PAH′s in the oil did not reflect their essential specificities. The characteristic rations of 33 biomarker in the oil were selected for comparison and similarity among the 3 fuel oil were shown by 69.70% of the ratio values, while differences between the fuel oil and typical crude oil were shown by 30.30% of the ratio values. Therefore, these characteristic targets could be applied to the identification of fuel oil and crude oil.
中图分类号 O65
所属栏目 试验与研究
基金项目 国家海洋局近岸海域生态环境重点实验室开放研究基金项目(200908);国家海洋局第一海洋研究所基本科研业务费专项(2010G14)
收稿日期 2012/2/10
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备注白红妍(1988-),女,河南平顶山人,硕士研究生,主要从事海洋溢油指纹鉴别技术研究。
引用该论文: BAI Hong-yan,HAN Bin,ZHENG Li,YANG Dong-fang,WANG Xiao-ru. Preliminary Study on Difference of Fingerprint Characteristics Between Fuel Oil and Typical Crude Oil from Bohai Sea[J]. Physical Testing and Chemical Analysis part B:Chemical Analysis, 2013, 49(3): 260～265
白红妍,韩彬,郑立,杨东方,王小如. 燃料油与典型渤海原油指纹特征差异性初探[J]. 理化检验－化学分册, 2013, 49(3): 260～265
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参考文献
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【3】倪张林,马启敏,程海鸥.重质燃料油中主要芳烃在自然条件下的风化规律［J］.油气田环境保护, 2007,17(4):37-39.
【4】程海鸥,马启敏,肖晓彤.船舶燃料油中主要多环芳烃的短期风化特性［J］.环境化学, 2009,28(5):661-665.
【5】FERNDEZ-VARELA R, ANDRADE J M, MUNIATEGUI S, et al. The comparison of two heavy fuel oils in composition and weathering pattern, based on IR, GC-FID and GC-MS analyses: Application to the prestige wreackage［J］. Water research, 2009,43(4):1015-1026.
【6】EZRA S, FEINSTEIN S, PELLY I, et al. Weathering of fuel oil spill on the east Mediterranean coast,Ashdod, Israel［J］. Organic Geochemistry, 2000,31(12):1733-1741.
【7】GB/T 21247-2007海面溢油鉴别系统规范［S］.
【8】徐恒振.Fuzzy相关分析鉴别海面溢油［J］.海洋环境科学, 1995,14(1):55-58.
【9】韩彬,曹磊,郑立,等.金刚烷类风化规律及其在油源鉴别中的应用［J］.深圳大学学报:理工版, 2011,28(4):362-367.
【10】PRINCE R C, ELNENDORF D L, LUTE J R, et al. 17α(H),21β(H)-Hopane as a conserved internalmarker for estimatingthe biodegradation of crude oil［J］. Environmental Science and Technology, 1994,28(1):142-145.
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