Physical Basis of Nondestructive Evaluation on Composition in Cemented Carbides WC-Co
摘 要
γ相磁性分析法是基于WC-Co硬质合金的磁性源自合金中γ粘结相的磁性, 通过理论计算结合试验数据分析得到了γ相比饱和磁矩与γ相中钨和碳溶质质量分数的数值关系, 以及合金的比饱和磁矩和密度分别与合金的钴含量或碳含量的数值关系。结果表明: 钨和碳溶质分别降低和提高γ相的比饱和磁矩; 除石墨相区内比饱和磁矩与合金的钴含量存在正比关系外, WC-Co合金的比饱和磁矩和密度分别与合金的钴含量或碳含量间均不存在一一对应关系, 兼用合金的比饱和磁矩和密度测定值能确定WC-Co硬质合金材料成分的平均值。讨论了相关磁学测定量的物理意义。
Abstract
The numerical relationship of the specific saturation magnetic moment σγ of γ-phase with the wolfram solubility WγW and the carbon solubility WγC in γ-phase, and the numerical relationship of the specific saturation magnetic moment σ, the density ρ of WC-Co alloy with the cobalt content WCo or the carbon content WC in the alloy were deduced by means of theoretical analysis and experimental datum calculation based on the magnetism of the alloy was of the γ-phase magnetism origin i.e. the γ-phase magnetism analytics method. The results showed that, the specific saturation magnetic moment σγ of γ-phase could be raised by carbon solute and reduced by wolfram solute respectively. There was no one to one correspondence of the specific saturation magnetic moment σ (or the saturation magnetization MS) and the density ρ with the cobalt content WCo or carbon content WC in WC-Co alloy respectively, except for the direct proportion relationship of σ with WCo in graphite composition region. The composition average value in WC-Co alloy could be decided exactly with both the measured specific saturation magnetic moment σ and the density ρ values of the alloy.The physical meaning of the related magnetic measurands were discussed.
中图分类号 TG113.22+5 TF125.3
所属栏目 试验与研究
基金项目
收稿日期 2012/11/7
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备注刘寿荣(1939-), 男, 教授级高级工程师。
引用该论文: LIU Shou-rong. Physical Basis of Nondestructive Evaluation on Composition in Cemented Carbides WC-Co[J]. Physical Testing and Chemical Analysis part A:Physical Testing, 2013, 49(9): 568~575
刘寿荣. 无损鉴定WC-Co硬质合金成分的物理基础[J]. 理化检验-物理分册, 2013, 49(9): 568~575
被引情况:
【1】刘寿荣, "无损鉴定WC-Co硬质合金显微结构参数的物理基础",理化检验-物理分册 50, 796-799(2014)
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参考文献
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【2】PENRICE T W. Some characteristics of the binder phase in cemented carbides[J].Int J of R & HM,1997,15(3):113-121.
【3】LIU Shou-rong. Magnetism property of binder in WC-Co cemented carbides[J].Transaction of Nonferrous Metals Society of China,1992,2(3): 83-86.
【4】刘寿荣.WC-Co(Ni,Fe)硬质合金比磁饱和的标记、单位和换算[J].理化检验-物理分册, 2010,46(7): 427-431.
【5】刘寿荣,郝建民, 易毅刚.硬质合金η相的X射线定量测定[J].材料研究学报, 1996,10(5): 505-508.
【6】NATL Bur. Joint Committee on Powder Diffraction Stands (JCPDS)[DB].Philadelphia:ICDD,1965: 15-806.
【7】ALMOND E A, ROEBUCK B. The origin of WC substructure and the effect of processing on microstructure of WC/Co hardmetals[C]//Proceed 10th Plansee Seminar, Metallwerk Plansee, Reutte, Austria:[s.n.],1981:659-672.
【8】FANG Z, EASON W J. Nondestructive evaluation of WC-Co composites with magnetic properties[J].The Int J of Powder Met,1993,29(3): 259-265.
【9】EXNER H E, GURLAND J. A review of parameters influencing some mechanical properties of tungsten carbide cobalt alloys[J].Powder Met,1970,13(1): 13-31.
【10】深津 保.无磁硬质合金[R].天津:天津硬质合金研究所, 1997.
【11】郝建民, 王利杰.钴相变的X射线研究[J].金属学报, 1994,30(1): 45-48.
【12】КУДРЯВЦЕВА В И, ЧАПАРОВА И H. ВАРАКСИНА А В.Термообработка твёрдых сплавов WC-Co и изделии из иих[J].Порошковая Металлургия, 1987(5): 56-59.
【13】LIU Shou-rong, LIU Yi.β→α transformation of γ-phase in WC-Co cemented carbides[J].J Mater Sci Technol,1996,12(5): 398-400.
【14】AUGUST J S, KALISH S.Effect of composition on the fracture toughness of hard metals[J].Int J of R & HM,1983(June): 88-92.
【15】铃木寿, 林宏尔. WC-10Co超硬合金の抗折断强度と破坏の起源との关系[J].日本金属学会志,1974,18(1): 1013-1018.
【16】KIFFER R, SCHWARZKOPF P.硬质合金[M].王少刚, 译.北京: 冶金工业出版社, 1963:341.
【17】铃木寿, 林宏尔谷口泰郎.WC-Co超硬合金の高温抗折力におょぼす合金炭素量の影响[J].粉体ずょび粉末冶金, 1978, 25(3): 94-98.
【18】铃木寿, 昌山正孝梅田高照.炭素量の变化を考虑してのWC-10Co合金の性质と粒度との关系[J].日本金属学会志, 1965, 29(10): 974-979.
【19】吴冲浒.WC-Co硬质合金的磁饱和性能及其应用浅论[J].稀有金属与硬质合金, 1999(3): 45-51.
【20】刘寿荣.硬质合金顶锤的组织缺陷和质量评估[J].硬质合金, 1998,15(2):65-72.
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