油淬Ni64Al36合金的逆马氏体相变
Reverse Martensitic Transformation in Oil-Quenched Ni64Al36 Alloy
摘 要
用内耗试验、差示扫描量热和X射线衍射分析等方法对油淬和炉冷的Ni64Al36(原子分数)合金从室温到400 ℃的逆马氏体相变过程进行了研究。结果表明: 在加热过程中油淬Ni64Al36合金在220 ℃出现一个内耗峰, 冷却时内耗峰的温度移到160 ℃, 而炉冷Ni64Al36合金无内耗峰出现;油淬Ni64Al36合金的内耗峰峰位不随振动频率而变化, 但峰高随频率的减小和升温速率的提高而增大;油淬Ni64Al36合金在冷却和加热时出现的两个内耗峰分别是由γ→L10马氏体转变及其逆马氏体转变引起的;在室温到400 ℃有限次数热循环范围内, 热循环次数对油淬Ni64Al36合金正、逆马氏体转变的影响很小。
Ni64Al36合金
马氏体相变
内耗
oil-quenching
Ni64Al36 alloy
martensitic transformation
internal friction
Abstract
The reverse martensitic transformations of oil-quenched and furnace-cooled Ni64Al36 (at%) alloys at temperature from room temperature to 400 ℃ were studied by internal friction measurement, differential scanning calorimetry (DSC) and X-ray diffractometry (XRD). The results show that there was an internal friction peak appeared at temperature about 220 ℃ during heating for the oil-quenched Ni64Al36 alloy, and it moved to 160 ℃ in cooling process. But the furnace-cooled Ni64Al36 alloy did not have any internal friction peak. The peak-height increased with decreasing vibration frequency and increasing heating rate. The internal friction peaks of the oil-quenched Ni64Al36 alloy during heating and cooling were attributable to γ→L10 martensitic transformation and its reverse process respectively. The influence of the thermal cycle times on martensitic transformation and its reverse process was not observed in the limited thermal cycles from room temperature to 400 ℃ for oil-quenched Ni64Al36 alloy.
中图分类号 TG111.5
所属栏目 新材料新工艺
基金项目 江苏省高校科研成果产业化推进项目(JHZD2012-48);苏州市科技计划项目(SGZ2012058, SGZ2013128);苏州市职业大学校级项目(2013SZDYJ05)
收稿日期 2014/2/28
修改稿日期 2014/10/17
网络出版日期
作者单位点击查看
备注周正存(1962-), 男, 安徽舒城人, 教授。
引用该论文: ZHOU Zheng-cun,DU Jie,ZHANG Yi-ping,GU Su-yi,YANG Hong,YAN Yong-jian. Reverse Martensitic Transformation in Oil-Quenched Ni64Al36 Alloy[J]. Materials for mechancial engineering, 2014, 38(12): 46～49
周正存,杜洁,张义平,顾苏怡,杨洪,严勇健. 油淬Ni64Al36合金的逆马氏体相变[J]. 机械工程材料, 2014, 38(12): 46～49
被引情况:
【1】徐然,罗丰华,王铸博, "不同温度淬火后Co39Ni34Al27形状记忆合金的组织与性能",机械工程材料 40, 62-66(2016)
共有人对该论文发表了看法，其中：
人认为该论文很差
人认为该论文较差
人认为该论文一般
人认为该论文较好
人认为该论文很好
参考文献
【1】CHRSKA T, LAEK J, CHRSKA P. Resistometric investigation of phase transformations in NiAl alloys［J］.Mater Sci Eng: A,1998,244:263-272.
【2】ONO N, TSUKAHARA A, KAINUMA R, et al. The properties of two-phase Ni-Al-Fe shape memory alloys in the virgin and shape-memory-alloy-cycled states［J］.Mater Sci Eng: A,1999,273/275:420-424.
【3】GEORGE E P, LIU C T, HORTON J A, et al. Characterization, processing, and alloy design of NiAl-based shape memory alloys［J］.Materials Characterization,1997,39:665-686.
【4】FINLAYSON T R, KELLY G L, SMITH T F. The effects of stress on the martensitic transformation in Ni-Al［J］.Mater Sci Eng: A,1999,273/275:366-369.
【5】SANATI M, ALBERS R C, PINSKI F J. ω-phase formation in NiAl and Ni2Al alloys［J］.J Phys Condens Matter,2001,13:5387-5398.
【6】TKALCEC I, MARI D. Internal friction in martensitic, ferritic and bainitic carbon steel;cold work effects［J］.Mater Sci Eng: A,2004,370:213-217.
【7】周正存, 杜洁, 杨洪, 等.化学成分对Ni-Al基合金相变内耗的影响［J］.材料热处理学报,2013,34(12):59-62.
【8】周正存, 顾苏怡.不同热处理的Fe-25Cr-5Al合金的磁学-力学滞后阻尼［J］.金属热处理, 2008,33(8):50-53.
【9】ZHOU Z C. The influence of Al content on the relaxation peaks in quenched Fe-Al alloys ［J］.Mater Sci Eng: A,2006,442:82-85.
【10】SUGIMOTO K, MORI T, SHIODE S. Effect of composition on the internal friction and Young's modulus in amma-phase Mn-Cu alloys［J］.Metal Science Journal,1973,7:103-108.
【11】DELORME J F AND GOBIN P. Review: phase transition［J］.Metaux Corrosion Industrie,1973,573/574:3-32.
【12】MASSALSKI T B, MURRAY J L, BENNETT L H, et al. Binary alloy phase diagrams［M］.Metals Park,OH: American Society for Metals,1986.
【13】ENAMI K, NAGASAWA A, NENNO S. On the premartensitic transformation in the. Ni-Al β1 alloy［J］.Scripta Metall,1978,12:223-226.
【14】MARTYNOV V V, ENAMI K, KHANDROS L G, et al. Stress-induced martensitic-transformation and a new 7-layer martensite phase in the 63.1 Ni-Al alloy［J］.J Phys C4,1982,43:659-660.
【15】ENAMI K, NENNO S. Memory effect in Ni-36.8At. pct Al martensite［J］.Metal Trans,1971,2:1487-1490.
【16】NAGASAWA A, ENAMI K, ISHINO Y, et al. Reversible shape memory effect［J］.Scripta Metull,1974,8:1055-1060.
【17】KIM Y D, WAYMAN C M. Shape memory effect in powder-metallurgy NiAl alloys［J］.Scripta Metall,1990,24:245-250.
【18】左舜贵,金学军,金明江.高温形状记忆合金的研究进展［J］.机械工程材料,2014,38(1):1-5.
【19】吴春勇, 吴从跃, 王啸, 等. 淬火温度对铜铝镍形状记忆合金组织、性能以及相变点的影响［J］.机械工程材料,2014,38(2):28-31.
【2】ONO N, TSUKAHARA A, KAINUMA R, et al. The properties of two-phase Ni-Al-Fe shape memory alloys in the virgin and shape-memory-alloy-cycled states［J］.Mater Sci Eng: A,1999,273/275:420-424.
【3】GEORGE E P, LIU C T, HORTON J A, et al. Characterization, processing, and alloy design of NiAl-based shape memory alloys［J］.Materials Characterization,1997,39:665-686.
【4】FINLAYSON T R, KELLY G L, SMITH T F. The effects of stress on the martensitic transformation in Ni-Al［J］.Mater Sci Eng: A,1999,273/275:366-369.
【5】SANATI M, ALBERS R C, PINSKI F J. ω-phase formation in NiAl and Ni2Al alloys［J］.J Phys Condens Matter,2001,13:5387-5398.
【6】TKALCEC I, MARI D. Internal friction in martensitic, ferritic and bainitic carbon steel;cold work effects［J］.Mater Sci Eng: A,2004,370:213-217.
【7】周正存, 杜洁, 杨洪, 等.化学成分对Ni-Al基合金相变内耗的影响［J］.材料热处理学报,2013,34(12):59-62.
【8】周正存, 顾苏怡.不同热处理的Fe-25Cr-5Al合金的磁学-力学滞后阻尼［J］.金属热处理, 2008,33(8):50-53.
【9】ZHOU Z C. The influence of Al content on the relaxation peaks in quenched Fe-Al alloys ［J］.Mater Sci Eng: A,2006,442:82-85.
【10】SUGIMOTO K, MORI T, SHIODE S. Effect of composition on the internal friction and Young's modulus in amma-phase Mn-Cu alloys［J］.Metal Science Journal,1973,7:103-108.
【11】DELORME J F AND GOBIN P. Review: phase transition［J］.Metaux Corrosion Industrie,1973,573/574:3-32.
【12】MASSALSKI T B, MURRAY J L, BENNETT L H, et al. Binary alloy phase diagrams［M］.Metals Park,OH: American Society for Metals,1986.
【13】ENAMI K, NAGASAWA A, NENNO S. On the premartensitic transformation in the. Ni-Al β1 alloy［J］.Scripta Metall,1978,12:223-226.
【14】MARTYNOV V V, ENAMI K, KHANDROS L G, et al. Stress-induced martensitic-transformation and a new 7-layer martensite phase in the 63.1 Ni-Al alloy［J］.J Phys C4,1982,43:659-660.
【15】ENAMI K, NENNO S. Memory effect in Ni-36.8At. pct Al martensite［J］.Metal Trans,1971,2:1487-1490.
【16】NAGASAWA A, ENAMI K, ISHINO Y, et al. Reversible shape memory effect［J］.Scripta Metull,1974,8:1055-1060.
【17】KIM Y D, WAYMAN C M. Shape memory effect in powder-metallurgy NiAl alloys［J］.Scripta Metall,1990,24:245-250.
【18】左舜贵,金学军,金明江.高温形状记忆合金的研究进展［J］.机械工程材料,2014,38(1):1-5.
【19】吴春勇, 吴从跃, 王啸, 等. 淬火温度对铜铝镍形状记忆合金组织、性能以及相变点的影响［J］.机械工程材料,2014,38(2):28-31.
相关信息
