盐酸溶液中石墨烯量子点对碳钢的缓蚀性能
Inhibition Behavior of Graphene Quantum Dots for Carbon Steel in HCl Solution
摘 要
采用电化学氧化方法一步制备了水溶性石墨烯量子点(GQDs),并用透射电子显微镜(HR-TEM)、红外光谱(FT-IR)、塔菲尔极化曲线(Tafel)和电化学阻抗谱(EIS)进行了表征和测试.结果表明,石墨烯量子点对碳钢在1 mol/L盐酸介质中具有良好的缓蚀效果,其作用效果为混合型.
电化学方法
碳钢
盐酸
缓蚀
graphene quantum dot
electrochemical method
carbon steel
HCl
corrosion inhibition
Abstract
Water-soluble graphene quantum dots (GQDs) were prepared by one-step electro-oxidation.The GQDs were characterized by transmission electron microscopy (TEM),fourier transform infrared spectroscopy (FT-IR),polarization curves (Tafel) and electrochemical impedance spectroscopy (EIS).The results showed that the GQDs exhibited good inhibition effect on carbon steel and acted as mixed-type inhibitors in 1 mol/L HCl solution.
中图分类号 TG174.42
所属栏目 缓蚀剂专题
基金项目
收稿日期 2014/5/20
修改稿日期
网络出版日期
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备注周桃玉(1963-),教授,博士,从事腐蚀与防护环境分析与电化学研究.
引用该论文: LIU Qing,ZHOU Tao-yu. Inhibition Behavior of Graphene Quantum Dots for Carbon Steel in HCl Solution[J]. Corrosion & Protection, 2015, 36(2): 152
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【3】胡吉明,王钾,张鉴清,等.一种金属表面缓蚀剂的负载方法及用途CN201110187831.0[P].2011-12-7.
【4】周国华.WMCNTs/AZ31复合材料电化学腐蚀研究[J].中国腐蚀与防护学报,2013,33(5):430-434.
【5】何毅,海鹏,李飞洋,等.多壁碳纳米管改性环氧涂层的防腐蚀性能[J].腐蚀与防护,2013,34(7):590-592.
【6】ATTA A M,EL-MAHDY G A,AL-LOHEDAN H A.Corrosion inhibition efficiency of modified silver nanoparticles for carbon Steel in 1 M HCl[J].International Journal of Electrochemical Science,2013,8(4):4873-4885.
【7】HABIBA K,MAKAROV V I,AVALOS J,et al.Luminescent graphene quantum dots fabricated by pulsed laser synthesis[J].Carbon,2013,64:341-350.
【8】SREEPRASAD T S,RODRIGUEZ A A,COLSTON J,et al.Electron-tunneling modulation in percolating network of graphene quantum dots:Fabrication,phenomenological understanding,and humidity/pressure sensing applications[J].Nano Letters,2013,13(4):1757-1763.
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【22】ZHANG Y,WANG L,ZHANG H,et al.Graphitic carbon quantum dots as a fluorescent sensing platform for highly efficient detection of Fe3+ ions[J].RSC Advances,2013,3(11):3733-3738.
【23】HABIBA K,MAKAROV V I,AVALOS J,et al.Luminescent graphene quantum dots fabricated by pulsed laser synthesis[J].Carbon,2013,64:341-350.
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【28】XU X Y,RAY R,GU Y L,et al.Electrophoretic analysis and purification of fluorescent single-walled carbon nanotube fragments[J].Journal of the American Chemical Society,2004,126(40):12736-12737.
【29】YURT A,ULUTAS S,DAL H.Electrochemical and theoretical investigation on the corrosion of aluminium in acidic solution containing some schiff bases[J].Applied Surface Science,2006,253(2):919-925.
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