光致阴极保护研究进展
Progress in Research on Photo-cathodic Protection
摘 要
阴极保护技术是金属腐蚀与防护的主要技术之一,光致阴极保护技术作为一种新型的阴极保护技术近年来受到国内外学者的广泛关注.半导体薄膜在光致阴极保护过程中可作为永久性防护涂层,其中TiO2因具有独特的光电性能、良好的稳定性及无毒廉价等特点,在光致阴极保护技术中更具优势.综述了光致阴极保护技术的优越性,重点论述了TiO2光致阴极保护薄膜的制备及其在光致阴极保护技术领域的研究现状,提出了目前存在的问题及未来发展的方向.
TiO2
制备方法
第一性原理
研究进展
photo-cathodic protection
TiO2
preparation method
first principle
research advance
Abstract
Cathodic protection technology is one of the main technologies of metal corrosion and protection.As a new technology of cathodic protection,photo-cathodic protection technology is widely concerned in recent years by domestic and foreign scholars.Semiconductor films can be used as a permanent protective coating in photo-cathodic protection process.TiO2 has more advantages in photo-cathodic protection technology because its unique photoelectric properties,good stability,nontoxic and cheap characteristics.This paper reviews the superiority of photo-cathodic protection technology,focuses on the preparation and research status of TiO2 film in the field of photo-cathodic protection,puts forward the existing problems and development direction in the future.
中图分类号 TG174
所属栏目 阴极保护
基金项目 国家自然科学基金(21266006);广西自然科学基金(2012GXNSFAA053034)
收稿日期 2014/6/5
修改稿日期
网络出版日期
作者单位点击查看
联系人作者刘峥(lisa4.6@163.com)
备注刘峥(1962-),教授,博士,从事材料腐蚀与防护方向研究.
引用该论文: ZHANG Jing,LIU Zheng. Progress in Research on Photo-cathodic Protection[J]. Corrosion & Protection, 2015, 36(3): 250
被引情况:
【1】张 菁,刘 峥,郭亚晋,莫国芳, "Ni-P-SnO2复合镀层的制备及其性能",腐蚀与防护 37, 693-700(2016)
共有人对该论文发表了看法，其中：
人认为该论文很差
人认为该论文较差
人认为该论文一般
人认为该论文较好
人认为该论文很好
参考文献
【1】BARATI N,FAGHIHI S M A,GHASEMI H.Photocathodic protection of 316L stainless steel by coating of anatase nanoparticles[J].Protection of Metals and Physical Chemistry of Surfaces,2013,49(1):109-112.
【2】SUBASRL R,SHINOHSRA T.Photoelectrochemical characterization of TiO2 coatings derived from commercial sol solution for cathodic protection applications[J].Research on Chemical Intermediates,2005,31(4):275-283.
【3】BETTONI M,ROL C,SEBASTIANI G V.Photoelectrochemistry on TiO2/Ti anodes as a tool to increase the knowledge about some photo-oxidation mechanisms in CH3CN[J].Joumal of Physical Organic Chemistry,2008,21(3):219-224.
【4】SHEENEY-HAJ-ICHIA L,POGORELOVA S,GOFER Y.Enhanced photoelectrochemistry in CdS/Au nanoparticle bilayers[J].Advanced Function Materials,2004,14(5):416-424.
【5】HIGASHIMOTO S,KITAHATA N,MORI K,et al.Photo-electrochemical properties of amorphous WO3 supported on TiO2 hybrid catalysts[J].Catalysis Letters,2005(1/2):49-51.
【6】HOU L R,YUAN C Z,PENG Y.Synthesis and photocatalytic property of SnO2/TiO2 nanotubes composites[J].Journal of Hazardous Materials,2007,139(2):310-315.
【7】王芳.二氧化钛纳米材料结构的修饰和光电化学性质的研究[D].兰州:兰州大学博士学位论文,2013.
【8】HOU M J,ZHANG N,ZHANG L,et al.Photocathodic protection properties of NiP/TiO2 bilayer coatings by a combined electroless plating and sol-gel method[J].Materials and Corrosion,2012,63(8):703-706.
【9】SUBASRI R,SHINOHARA T.Investigation on SnO2-TiO2 composit photoelectrodes for corrision protection[J].Electrochemistry Communications,2003,5(10):897-902.
【10】张璐.溶胶-凝胶法制备高光催化活性二氧化钛薄膜[D].广州:华南理工大学硕士学位论文,2013.
【11】王永刚.MWCNT/TiO2复合薄膜的制备与光生阴极保护性能研究[D].青岛:中国海洋大学硕士学位论文,2012.
【12】SHEN G X,CHEN Y C,LIN C J.Corrosion protection of 316 L stainless steel by a TiO2 nanoparticle coating prepared by sol-gel method[J].Thin Solid Films,2005,489:130-136.
【13】ZHANG W,ZHU L,GU J S,et al.Photoelectrochemical properties of TiO2 thin film electrodes under visible light Illumination[J].Rare Metal Materials and Engineering,2010,39(6):1013-1017.
【14】张其君,李燕,赵雲,等.自持TiO2纳米管阵列薄膜与TiO2/FTO光电极制备工艺的研究[J].真空与低温,2011,17(1):7-12.
【15】刘世凯,杨海滨.TiO2纳米管阵列的制备及其光电化学性质研究[J].功能材料,2011,42(5):899-904.
【16】陶海军,陶杰,汪涛,等.有机电解液中TiO2纳米管阵列的制备及其光电性能[J].中国有色金属学报,2012,22(8):2326-2332.
【17】LI M C,LUO S Z,WU P F.Photocathodic protection effect of TiO2 films for carbon steel in 3% NaCl solutions[J].Electrochimica Acta,2005,50(16):3401-3406.
【18】LUO Y,CUI X L,XIE J Y.Preparation and visible light photoelectrochemical response of TiO2-MoO3 composite nanotube thin films[J].Acta Phys Chim Sin,2011,27(1):135-142.
【19】KANG M,CHOUNG S J,PARK J Y.Photocatalytic performance of nanometer-sized FexOy/TiO2 particle synthesized by hydrother-mal method[J].Catalysis Today,2003,87(1):87-97.
【20】ZHU Y F,DU R G,LI J.Photogenerated cathodic protection properties of a TiO2 nanowire film prepared by a hydrothermal method[J].Acta Phys Chim Sin,2010,26(9):2349-2353.
【21】LEI C X,ZHOU H,FENG Z D.Effect of liquid-phase-deposited parameters on the photogenerated cathodic protection properties of TiO2 films[J].Journal of Alloys and Compounds,2012,542(25):164-169.
【22】CHEN W W,GAO W,HE Y D.A novel electroless plating of Ni-P-TiO2 nano-composite coatings[J].Surface & Coatings Technology,2010,204(15):2493-2498.
【23】XUE J B,SHEN Q Q,LI G L,et al.Preparation and photoelectric property of different morphologies Cu2O Loaded on TiO2 nanotube arrays films[J].Chinese Journal of Inorganic Chemistry,2013,29(4):729-734.
【24】LEI C X,ZHOU H,WANG C,et al.Self-assembly of ordered mesoporous TiO2 thin films as photoanodes for cathodic protection of stainless steel[J].Electrochimica Acta,2013,87:245-249.
【25】贺明辉.TiO2、SnO2复合纳米膜的制备及光生阴极保护性能研究[D].青岛:中国海洋大学硕士学位论文,2010.
【26】王爱萍.改性纳米二氧化钛薄膜制备及其在模拟海水中光生阴极保护性能研究[D].青岛:中国海洋大学博士学位论文,2010.
【27】王洪芬.涉海抗菌耐蚀性TiO2复合薄膜的制备及其性能研究[D].青岛:中国海洋大学博士学位论文,2010.
【28】王永刚,柳伟,曹立新,等.多壁纳米碳管/TiO2复合薄膜的制备与光阴极保护性能研究[J].中国腐蚀与防护学报,2012,32(6):485-490.
【29】TATSUMA T,SATIOH S,NGAOTRA K,et al.Energy storage of TiO2-WO3 photocatalysis system with an energy in the gas phase[J].Langmuir,2002,18:7777-7779.
【30】张煜,刘兆阅,翟锦.Cu2O/TiO2纳米管阵列异质结的制备及其可见光光电响应性质[J].化学学报,2013,71:793-797.
【31】TSUI L K,ZANGARI G.Modification of TiO2 nanotubes by Cu2O for photoelectrochemical,photocatalytic,and photovoltaic devices[J].Electacta,2013,9:150-158.
【32】王爱萍,贺明辉,尹衍升.叠层式TiO2/SnO2复合纳米薄膜制备及其光电性能研究[J].功能材料,2011,4(42):728-731.
【33】PARK J H,KIM J S,PARK J M.Electrophoretic deposition of nano-ceramics for the photo-generated cathodic corrosion protection of steel substrates[J].Surface & Coatings Technology,2013,236:172-181.
【34】张娜,周民杰.纳米TiO2-WO3复合涂层及纳米TiO2/WO3叠层涂层的制备及性能[J].材料保护,2012,45(1):20-23.
【35】ZHOU M J,ZENG Z O,LI Z.Photogenerated cathode protection properties of nano-sized TiO2/WO3 coating[J].Corrosion Science,2009,51:1386-1391.
【36】LI H,WANG X T,LIU Y,et al.Ag and SnO2 co-sensitized TiO2 photoanodes for protection of 304SS under visible light[J].Corrosion Science,2014,67(1):1016-1021.
【37】PRAVEEN B M,VENKATESHA T V.Electrodeposition and properties of Zn-Nanosized TiO2 composite coatings[J].Applied Surface Science,2008,254(8):2418-2424.
【38】NIE J L,MO Y,ZHENG B Z,et al.Electrochemical fabrication of lanthanum-doped TiO2 nanotube array electrode and investigation of its photoelectrochemical capability[J].Electrochimica Acta,2013,90:589-596.
【39】林成钢,林泽泉,李静,等.钴离子(Co2+)掺杂TiO2纳米管阵列的光生阴极保护行为[J].电化学,2011,17(3):312-316.
【40】万冰华,费敬银,冯光勇,等.Zn-Co-TiO2纳米复合镀层的光生阴极保护特性[J].中国腐蚀与防护学报,2012,32(4):327-332.
【41】漆海清,朱燕峰,张娟,等.TiO2纳米管阵列膜的制备及对304不锈钢的光生阴极保护效应[J].功能材料,2012,43(9):1147-1150.
【42】LI S N,FU J J.Improvement in corrosion protection properties of TiO2 coatings by chromium doping[J].Corrosion Science,2013,68(1):101-110.
【43】SUN M M,CHEN Z Y,YU J Q.Highly efficient visible light induced photoelectrochemical anticorrosion for 304 SS by Ni-doped TiO2[J].Electrochimica Acta,2013,109:13-19.
【44】LI J,LIN C J,LAI Y K,et al.Photogenerated cathodic protection of flower-like,nanostructured,N-doped TiO2 film on stainless steel[J].Surface & Coatings Technology,2010,205(2):557-564.
【45】LIU W,WANG Y G,SU G,et al.The effect of incorporating carbon nanotubes in titania films used for the photocathode protection of 304 stainless steel[J].Carbon,2012,50(10):3641-3648.
【46】GUO X Q,LIU W,GAO L X,et al.Graphene incorporated nanocrystalline TiO2 films for thephotocathodic protection of 304 stainless steel[J].Applied Surface Science,2013,283(15):498-504.
【47】LEI C X,FENG Z D,ZHOU H.Visible-light-driven photogenerated cathodic protection of stainless steel by liquid-phase-deposited TiO2 films[J].Electrochimica Acta,2012,68:134-140.
【48】YU J C,HO W,YU J,et al.Efficient visible-light-induced photocatalytic disinfection on sulfur-doped nanocrystalline titania[J].Environ Sci Technol,2005,39(4):1175-1179.
【49】NARAYANAN T S N S,BASKARAN I,KRISHNAVENI K,et al.Deposition of electroless Ni-P graded coatings and evaluation of their corrosion resistance[J].Surface & Coatings Technology,2006,200(11):3438-3445.
【50】RANGANATHA S,VENKATESHA T V,VATHSALA K.Development of electroless Ni-Zn-P/nano-TiO2 composite coatings and their properties[J].Applied Surface Science,2010,256(24):2377-2383.
【51】NAKANO Y,MORIKAWA T,OHWAKI T,et al.Band-gap narrowing of TiO2 films induced by N-doping[J].Physica B,2006,376/377:823-826.
【52】郑树凯,吴国浩,刘磊.P掺杂锐钛矿相TiO2的第一性原理计算[J].物理学报,2013,62(4):043102.
【53】吴国浩,郑树凯,刘磊.Fe-S共掺杂锐钛矿相TiO2的第一性原理研究[J].中国有色金属学报,2013,23(3):852-858.
【54】ZHANG S Y,LI Q,YANG X K,et al.Corrosion resistance of AZ91D magnesium alloy with electroless plating pretreatment and Ni-TiO2 composite coating[J].Materials Characterization,2010,61(3):269-276.
【55】ZHU Y F,XU L,HU J,et al.Fabrication of heterostructured SrTiO3/TiO2 nanotube array films and their use in photocathodic protection of stainless steel[J].Electrochimica Acta,2014,121:361-368.
【56】孙大春,王丽萍,郭进,等.NiO/TiO2纳米管阵列异质结电极的制备及光电化学性能[J].吉林大学学报,2011,49(6):1124-1129.
【57】LI J,LIN C J,LI J T,et al.A photoelectrochemical study of CdS modified TiO2 nanotube arrays as photoanodes for cathodic protection of stainless steel[J].Thin Solid Films,2011,519(16):5494-5502.
【58】甘嘉永,徐明,赵栩枫,等.CdS/TiO2纳米管阵列的电化学构筑及其在光电化学池中的应用[J].材料研究与应用,2010,4(4):245-248.
【59】LIU L,HU J M,LENG W H,et al.Novel bis-silane/TiO2 bifunctional hybrid films for metal corrosion protection both under ultraviolet irradiation and in the dark[J].Scripta Materialia,2007,57(6):549-552.
【60】ZHANG J,DU R G,LIN Z Q,et al.Highly efficient CdSe/CdS co-sensitized TiO2 nanotube films for photocathodic protection of stainless steel[J].Electrochimica Acta,2012,83:59-64.
【2】SUBASRL R,SHINOHSRA T.Photoelectrochemical characterization of TiO2 coatings derived from commercial sol solution for cathodic protection applications[J].Research on Chemical Intermediates,2005,31(4):275-283.
【3】BETTONI M,ROL C,SEBASTIANI G V.Photoelectrochemistry on TiO2/Ti anodes as a tool to increase the knowledge about some photo-oxidation mechanisms in CH3CN[J].Joumal of Physical Organic Chemistry,2008,21(3):219-224.
【4】SHEENEY-HAJ-ICHIA L,POGORELOVA S,GOFER Y.Enhanced photoelectrochemistry in CdS/Au nanoparticle bilayers[J].Advanced Function Materials,2004,14(5):416-424.
【5】HIGASHIMOTO S,KITAHATA N,MORI K,et al.Photo-electrochemical properties of amorphous WO3 supported on TiO2 hybrid catalysts[J].Catalysis Letters,2005(1/2):49-51.
【6】HOU L R,YUAN C Z,PENG Y.Synthesis and photocatalytic property of SnO2/TiO2 nanotubes composites[J].Journal of Hazardous Materials,2007,139(2):310-315.
【7】王芳.二氧化钛纳米材料结构的修饰和光电化学性质的研究[D].兰州:兰州大学博士学位论文,2013.
【8】HOU M J,ZHANG N,ZHANG L,et al.Photocathodic protection properties of NiP/TiO2 bilayer coatings by a combined electroless plating and sol-gel method[J].Materials and Corrosion,2012,63(8):703-706.
【9】SUBASRI R,SHINOHARA T.Investigation on SnO2-TiO2 composit photoelectrodes for corrision protection[J].Electrochemistry Communications,2003,5(10):897-902.
【10】张璐.溶胶-凝胶法制备高光催化活性二氧化钛薄膜[D].广州:华南理工大学硕士学位论文,2013.
【11】王永刚.MWCNT/TiO2复合薄膜的制备与光生阴极保护性能研究[D].青岛:中国海洋大学硕士学位论文,2012.
【12】SHEN G X,CHEN Y C,LIN C J.Corrosion protection of 316 L stainless steel by a TiO2 nanoparticle coating prepared by sol-gel method[J].Thin Solid Films,2005,489:130-136.
【13】ZHANG W,ZHU L,GU J S,et al.Photoelectrochemical properties of TiO2 thin film electrodes under visible light Illumination[J].Rare Metal Materials and Engineering,2010,39(6):1013-1017.
【14】张其君,李燕,赵雲,等.自持TiO2纳米管阵列薄膜与TiO2/FTO光电极制备工艺的研究[J].真空与低温,2011,17(1):7-12.
【15】刘世凯,杨海滨.TiO2纳米管阵列的制备及其光电化学性质研究[J].功能材料,2011,42(5):899-904.
【16】陶海军,陶杰,汪涛,等.有机电解液中TiO2纳米管阵列的制备及其光电性能[J].中国有色金属学报,2012,22(8):2326-2332.
【17】LI M C,LUO S Z,WU P F.Photocathodic protection effect of TiO2 films for carbon steel in 3% NaCl solutions[J].Electrochimica Acta,2005,50(16):3401-3406.
【18】LUO Y,CUI X L,XIE J Y.Preparation and visible light photoelectrochemical response of TiO2-MoO3 composite nanotube thin films[J].Acta Phys Chim Sin,2011,27(1):135-142.
【19】KANG M,CHOUNG S J,PARK J Y.Photocatalytic performance of nanometer-sized FexOy/TiO2 particle synthesized by hydrother-mal method[J].Catalysis Today,2003,87(1):87-97.
【20】ZHU Y F,DU R G,LI J.Photogenerated cathodic protection properties of a TiO2 nanowire film prepared by a hydrothermal method[J].Acta Phys Chim Sin,2010,26(9):2349-2353.
【21】LEI C X,ZHOU H,FENG Z D.Effect of liquid-phase-deposited parameters on the photogenerated cathodic protection properties of TiO2 films[J].Journal of Alloys and Compounds,2012,542(25):164-169.
【22】CHEN W W,GAO W,HE Y D.A novel electroless plating of Ni-P-TiO2 nano-composite coatings[J].Surface & Coatings Technology,2010,204(15):2493-2498.
【23】XUE J B,SHEN Q Q,LI G L,et al.Preparation and photoelectric property of different morphologies Cu2O Loaded on TiO2 nanotube arrays films[J].Chinese Journal of Inorganic Chemistry,2013,29(4):729-734.
【24】LEI C X,ZHOU H,WANG C,et al.Self-assembly of ordered mesoporous TiO2 thin films as photoanodes for cathodic protection of stainless steel[J].Electrochimica Acta,2013,87:245-249.
【25】贺明辉.TiO2、SnO2复合纳米膜的制备及光生阴极保护性能研究[D].青岛:中国海洋大学硕士学位论文,2010.
【26】王爱萍.改性纳米二氧化钛薄膜制备及其在模拟海水中光生阴极保护性能研究[D].青岛:中国海洋大学博士学位论文,2010.
【27】王洪芬.涉海抗菌耐蚀性TiO2复合薄膜的制备及其性能研究[D].青岛:中国海洋大学博士学位论文,2010.
【28】王永刚,柳伟,曹立新,等.多壁纳米碳管/TiO2复合薄膜的制备与光阴极保护性能研究[J].中国腐蚀与防护学报,2012,32(6):485-490.
【29】TATSUMA T,SATIOH S,NGAOTRA K,et al.Energy storage of TiO2-WO3 photocatalysis system with an energy in the gas phase[J].Langmuir,2002,18:7777-7779.
【30】张煜,刘兆阅,翟锦.Cu2O/TiO2纳米管阵列异质结的制备及其可见光光电响应性质[J].化学学报,2013,71:793-797.
【31】TSUI L K,ZANGARI G.Modification of TiO2 nanotubes by Cu2O for photoelectrochemical,photocatalytic,and photovoltaic devices[J].Electacta,2013,9:150-158.
【32】王爱萍,贺明辉,尹衍升.叠层式TiO2/SnO2复合纳米薄膜制备及其光电性能研究[J].功能材料,2011,4(42):728-731.
【33】PARK J H,KIM J S,PARK J M.Electrophoretic deposition of nano-ceramics for the photo-generated cathodic corrosion protection of steel substrates[J].Surface & Coatings Technology,2013,236:172-181.
【34】张娜,周民杰.纳米TiO2-WO3复合涂层及纳米TiO2/WO3叠层涂层的制备及性能[J].材料保护,2012,45(1):20-23.
【35】ZHOU M J,ZENG Z O,LI Z.Photogenerated cathode protection properties of nano-sized TiO2/WO3 coating[J].Corrosion Science,2009,51:1386-1391.
【36】LI H,WANG X T,LIU Y,et al.Ag and SnO2 co-sensitized TiO2 photoanodes for protection of 304SS under visible light[J].Corrosion Science,2014,67(1):1016-1021.
【37】PRAVEEN B M,VENKATESHA T V.Electrodeposition and properties of Zn-Nanosized TiO2 composite coatings[J].Applied Surface Science,2008,254(8):2418-2424.
【38】NIE J L,MO Y,ZHENG B Z,et al.Electrochemical fabrication of lanthanum-doped TiO2 nanotube array electrode and investigation of its photoelectrochemical capability[J].Electrochimica Acta,2013,90:589-596.
【39】林成钢,林泽泉,李静,等.钴离子(Co2+)掺杂TiO2纳米管阵列的光生阴极保护行为[J].电化学,2011,17(3):312-316.
【40】万冰华,费敬银,冯光勇,等.Zn-Co-TiO2纳米复合镀层的光生阴极保护特性[J].中国腐蚀与防护学报,2012,32(4):327-332.
【41】漆海清,朱燕峰,张娟,等.TiO2纳米管阵列膜的制备及对304不锈钢的光生阴极保护效应[J].功能材料,2012,43(9):1147-1150.
【42】LI S N,FU J J.Improvement in corrosion protection properties of TiO2 coatings by chromium doping[J].Corrosion Science,2013,68(1):101-110.
【43】SUN M M,CHEN Z Y,YU J Q.Highly efficient visible light induced photoelectrochemical anticorrosion for 304 SS by Ni-doped TiO2[J].Electrochimica Acta,2013,109:13-19.
【44】LI J,LIN C J,LAI Y K,et al.Photogenerated cathodic protection of flower-like,nanostructured,N-doped TiO2 film on stainless steel[J].Surface & Coatings Technology,2010,205(2):557-564.
【45】LIU W,WANG Y G,SU G,et al.The effect of incorporating carbon nanotubes in titania films used for the photocathode protection of 304 stainless steel[J].Carbon,2012,50(10):3641-3648.
【46】GUO X Q,LIU W,GAO L X,et al.Graphene incorporated nanocrystalline TiO2 films for thephotocathodic protection of 304 stainless steel[J].Applied Surface Science,2013,283(15):498-504.
【47】LEI C X,FENG Z D,ZHOU H.Visible-light-driven photogenerated cathodic protection of stainless steel by liquid-phase-deposited TiO2 films[J].Electrochimica Acta,2012,68:134-140.
【48】YU J C,HO W,YU J,et al.Efficient visible-light-induced photocatalytic disinfection on sulfur-doped nanocrystalline titania[J].Environ Sci Technol,2005,39(4):1175-1179.
【49】NARAYANAN T S N S,BASKARAN I,KRISHNAVENI K,et al.Deposition of electroless Ni-P graded coatings and evaluation of their corrosion resistance[J].Surface & Coatings Technology,2006,200(11):3438-3445.
【50】RANGANATHA S,VENKATESHA T V,VATHSALA K.Development of electroless Ni-Zn-P/nano-TiO2 composite coatings and their properties[J].Applied Surface Science,2010,256(24):2377-2383.
【51】NAKANO Y,MORIKAWA T,OHWAKI T,et al.Band-gap narrowing of TiO2 films induced by N-doping[J].Physica B,2006,376/377:823-826.
【52】郑树凯,吴国浩,刘磊.P掺杂锐钛矿相TiO2的第一性原理计算[J].物理学报,2013,62(4):043102.
【53】吴国浩,郑树凯,刘磊.Fe-S共掺杂锐钛矿相TiO2的第一性原理研究[J].中国有色金属学报,2013,23(3):852-858.
【54】ZHANG S Y,LI Q,YANG X K,et al.Corrosion resistance of AZ91D magnesium alloy with electroless plating pretreatment and Ni-TiO2 composite coating[J].Materials Characterization,2010,61(3):269-276.
【55】ZHU Y F,XU L,HU J,et al.Fabrication of heterostructured SrTiO3/TiO2 nanotube array films and their use in photocathodic protection of stainless steel[J].Electrochimica Acta,2014,121:361-368.
【56】孙大春,王丽萍,郭进,等.NiO/TiO2纳米管阵列异质结电极的制备及光电化学性能[J].吉林大学学报,2011,49(6):1124-1129.
【57】LI J,LIN C J,LI J T,et al.A photoelectrochemical study of CdS modified TiO2 nanotube arrays as photoanodes for cathodic protection of stainless steel[J].Thin Solid Films,2011,519(16):5494-5502.
【58】甘嘉永,徐明,赵栩枫,等.CdS/TiO2纳米管阵列的电化学构筑及其在光电化学池中的应用[J].材料研究与应用,2010,4(4):245-248.
【59】LIU L,HU J M,LENG W H,et al.Novel bis-silane/TiO2 bifunctional hybrid films for metal corrosion protection both under ultraviolet irradiation and in the dark[J].Scripta Materialia,2007,57(6):549-552.
【60】ZHANG J,DU R G,LIN Z Q,et al.Highly efficient CdSe/CdS co-sensitized TiO2 nanotube films for photocathodic protection of stainless steel[J].Electrochimica Acta,2012,83:59-64.
相关信息
