高温高压水中镍基合金表面氧化膜的原位表面增强型拉曼光谱
In-situ Surface Enhanced Raman Spectroscopy of Surface Film Formed on Nickel-based Alloys in High-temperature and High-pressure Water
摘 要
采用表面增强型拉曼光谱方法原位研究了镍基合金在高温高压水环境中的腐蚀行为及其表面生成氧化膜.Ni-5Cr-8Fe表面氧化膜的拉曼光谱存在三个拉曼峰,位于540 cm-1,610 cm-1和670 cm-1.610 cm-1峰的出现表明了氧化膜中存在Cr2O3.540 cm-1峰则说明氧化膜中含有Cr2O3或NiO或两者的混合物.670 cm-1峰对应于FeCr2O4尖晶石的生成.Ni-10Cr-8Fe的表面氧化膜由Cr2O3、FeCr2O4构成,可能含有一定的NiO.Ni-10Cr和Ni-20Cr的表面氧化膜主要为Cr2O3,没有发现尖晶石相的存在.随着合金中铬含量的增加,表面氧化膜中Cr2O3的含量增加,NiO成分减少.
镍基合金
表面氧化膜
原位表面增强型拉曼光谱
high-temperature and high-pressure water
nickel-based alloy
surface film
in-situ SERS
Abstract
In-situ surface enhanced raman spectroscopy (SERS) was used to investigate the surface films formed on Ni-based alloys.SERS spectra measured for oxides of Ni-5Cr-8Fe shows Raman peaks at 540 cm-1,610 cm-1,and 670 cm-1.The peak at 610 cm-1 indicates the presence of Cr2O3.540 cm-1 peak is attributed to Cr2O3 or NiO or the mixture of both.670 cm-1 peak is assigned to FeCr2O4 spinel.The surface film of Ni-10Cr-8Fe alloy consists of Cr2O3,FeCr2O4 spinel and possibly NiO.Cr2O3 film is formed on Ni-10Cr and Ni-20Cr,but no spinel oxide peak is observed in the SERS spectra.As the Cr concentration increases,the amount of Cr2O3 in the surface film increases but the amount of NiO decreases.
中图分类号 TG172.82
所属栏目 试验研究
基金项目
收稿日期 2014/7/5
修改稿日期
网络出版日期
作者单位点击查看
备注汪峰(1977-),工程师,博士,从事核电材料腐蚀研究.
引用该论文: WANG Feng,Thomas M.Devine. In-situ Surface Enhanced Raman Spectroscopy of Surface Film Formed on Nickel-based Alloys in High-temperature and High-pressure Water[J]. Corrosion & Protection, 2015, 36(3): 300
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【2】KHALIFA M,KHAN F,HADDARA M.Reliability based inspection of nickel-based alloy welds in boiling water reactor environment[J].Reliability Engineering & System Safety,2010,95(5):494-498.
【3】REBAK R B,SZKLARSKA S Z.The mechanism of stress corrosion cracking of alloy 600 in high temperature water[J].Corrosion Science,1996,38(6):971-988.
【4】SCOTT P M.An overview of internal oxidation as a possible explanation of intergranular stress corrosion cracking of Alloy 600 in PWRs[C]//The Ninth International Symposium on Environmental Degradation of Materials in Nuclear Power Systems-Water Reactors,[S.l.]:[s.n.],1999:3-14.
【5】FLIS J.Role of oxide films in stress corrosion cracking of mild steel in nitrate solutions[J].Corrosion Science,1975,15(6/12):553-564.
【6】COMBRADE P,SCOTT P M,FOUCAULT M,et al.Oxidation of Ni base alloys in PWR water:oxide layers and associated damage to the base metal[C]//Proceedings of the 12th International Conference on Environmental Degradation of Materials in Nuclear Power System-Water Reactors,[S.l.]:[s.n.],2005:883-890.
【7】HALL JR M M.Film rupture model for aqueous stress corrosion cracking under constant and variable stress intensity factor[J].Corrosion Science,2009,51(2):225-233.
【8】BAEK J S,KIM J G,HUR D H,et al.Anodic film properties determined by EIS and their relationship with caustic stress corrosion cracking of Alloy 600[J].Corrosion Science,2003,45(5):983-994.
【9】SENNOUR M,MARCHETTI L,MARTIN F,et al.A detailed TEM and SEM study of Ni-base alloys oxide scales formed in primary conditions of pressurized water reactor[J].Journal of Nuclear Materials,2010,402(2/3):147-156.
【10】KUMAI C S,DEVINE T M.Influence of oxygen concentration of 288 ℃ water and alloy composition on the films formed on Fe-Ni-Cr alloys[J].Corrosion,2007,63(12):1101-1113.
【11】KUMAI C S,DEVINE T M.Oxidation of iron in 288 ℃,oxygen-containing water[J].Corrosion,2005,61(3):201-218.
【12】KADLEIKOVA M,BREZA J,VESELY M,et al.Raman spectra of synthetic sapphire[J].Microelectronics Journal,2001,32(12):955-958.
【13】WANG F,HARRINGTON S,DEVINE T M.In situ investigation of the passive films formed on chromium in aqueous (pH 8.4) borate buffer and aqueous chloride solutions[J].Electrochemical Society Transactions,2007,3(31):39-57.
【14】OBLONSKY L J,DEVINE T M.A surface enhanced raman spectroscopic study of the passive films formed in borate buffer on iron,nickel,chromium and stainless steel[J].Corrosion Science,1995,37(1):17-41.
【15】OBLONSKY L J,DEVINE T M.Surface enhanced Raman spectra from the films formed on nickel in the passive and transpassive regions[J].Journal of the Electrochemical Society,1995,142(11):3677-3682.
【16】DIETZ R E,PARISOT G I,MEIXNER A E.Infrared absorption and raman scattering by two-magnon processes in NiO[J].Physical Review B,1971,4(7):2302-2310.
【17】MASLAR J E,HURST W S,BOWERS JR W J,et al.In situ Raman spectroscopic investigation of chromium surfaces under hydrothermal conditions[J].Applied Surface Science,2001,180(1/2):102-118.
【18】FABIS P,HEIDERSBACH R,BROWN C,et al.Oxide scale formation on iron-chromium alloys in elevated temperature air environments[J].Corrosion,1981,37(12):700-711.
【19】THIERRY D,PERSSON D,LEYGRAF C,et al.In-situ Raman spectroscopy combined with X-Ray photoelectron spectroscopy and nuclear microanalysis for studies of anodic corrosion film formation on Fe-Cr single crystals[J].Journal of The Electrochemical Society,1988,135(2):305-310.
【20】CUBICCIOTTI D.Potential-pH diagrams for alloy-water systems under LWR conditions[J].Journal of Nuclear Materials,1993,201(2):176-183.
【21】KAUFMAN L.EPRI Report that considers the Thermodynamically Stable Oxidation Products of Alloy 600 and Alloy 690[R].2008.
【22】WANG F,DEVINE T M.In-situ surface enhanced raman spectroscopy investigation of surface film formed on nickel and chromium in high-temperature and high-pressure water[J].Atomic Energy Science and Technology,2013,47:7-13.
【23】FARROW R L,BENNER R E,NAGELBERG A S,et al.Characterization of surface oxides by Raman spectroscopy[J].Thin Solid Films,1980,73(2):353-358.
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【25】NAKAMURA K,ERA S,OZAKI Y,et al.Conformational changes in seventeen cystine disulfide bridges of bovine serum albumin proved by raman spectroscopy[J].FEBS Letters,1997,417(3):375-378.
【26】LIPPERT J L,TYMINSKI D,DESMEULES P J.Determination of the secondary structure of proteins by laser raman spectroscopy[J].Journal of the American Chemical Society,1976,98(22):7075-7080.
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