超临界水氧化系统腐蚀的研究进展
Research Progress on Corrosion of Supercritical Water Oxidation System
摘 要
超临界水氧化技术(SCWO)是近30年发展起来的一种有机废弃物深度处理技术,与传统处理技术相比,具有明显的优势和广阔的应用前景.但运行过程中存在的设备腐蚀等问题严重制约着其推广与应用.为解决这一问题,国内外研究人员对SCWO过程的腐蚀机理及腐蚀控制方法进行了研究,以期从材料选择与结构优化两个方面控制SCWO设备的腐蚀.本文对国内外SCWO系统腐蚀研究的进展进行了综述,并对相关问题进行了讨论.
腐蚀
控制
材料
supercritical water oxidation
corrosion
control
material
Abstract
Supercritical water oxidation (SCWO) is a potential organic waste treatment technology developed in recent 30 years,which has significant advantages and broad application prospects compared with traditional treatment technologies.However,the corrosion of equipment during its operation has severely restricted its promotion and application.Research on corrosion mechanism and corrosion control of SCWO process has been conducted,and materials experiments have been performed so as to control the corrosion of SCWO equipment from material selection and structure optimization.In this paper,the research development about corrosion of SCWO system at home and abroad is summarized and related issues are discussed.
中图分类号 TG174
所属栏目 专论
基金项目 江苏省环保科研课题(2012031);中国石油和化学工业联合会科技指导计划(2012-12-03)
收稿日期 2014/7/17
修改稿日期
网络出版日期
作者单位点击查看
备注廖传华(1972-),教授,博士,从事超临界流体技术的研究与开发研究.
引用该论文: LIU Wei,LIAO Chuan-hua,CHEN Hai-jun,ZHU Yue-zhao. Research Progress on Corrosion of Supercritical Water Oxidation System[J]. Corrosion & Protection, 2015, 36(5): 487
共有人对该论文发表了看法，其中：
人认为该论文很差
人认为该论文较差
人认为该论文一般
人认为该论文较好
人认为该论文很好
参考文献
【1】MODELL M.Using supercritical water to destroy tough waters[J].Chemical Week,1982,4:21-26.
【2】朱自强.超临界流体技术-原理和应用[M].北京:化学工业出版社,2000.
【3】COCERO M J,ALONSO E,SANZ M T,et al.Supercritical water oxidation process under energetically self sufficient operation[J].Supercritical Fluids,2002,24(1):37-46.
【4】张丽,韩恩厚,关辉,等.超临界水氧化环境中材料腐蚀的研究现状[J].材料导报,2001,15(5):8-10.
【5】XIU D.Treatment of high strength coking waste water by supercritical water oxidation[J].Fuel,2013,89:77-82.
【6】HIROSE T,SHIBA K,ENOEDA M,et al.Corrosion and stress corrosion cracking of ferritic/martensition steel in supercritical pressurized water[J].Nucl Mater,2007,367:1185-1189.
【7】闫康平,陈匡民.过程装备腐蚀与防护[M].北京:化学工业出版社,2009.
【8】PHILIP A M,GLENN T H.Corrosion control methods in supercritical water oxidation and gasification processes[J].The Journal of Supercritical Fluids,2009:83-103.
【9】BRUNNER G.Near and supercritical water.Part II:Oxidative processes[J].The Journal of Supercritical Fluids,2009:382-390.
【10】黄晓慧,王增长,崔文全,等.超临界水氧化过程中的腐蚀控制方法[J].工业水处理,2013,33(12):6-10.
【11】JIAN L S,ZHI Y M,JIU Y Z,et al.A corrosion of titanium in supercritical water oxidation environments[J].Transactions of Nonferrous Metals Society of China,2002,12(6):1054-1060.
【12】STEIN A,FELCH C,DOYLE E F.Material selection for hydrothermal oxidation processes for the disposal of chemical demilitarization hazardous waste[J].Corrosion,2006,134-142.
【13】YOON J H,SON K S,KIM H S,et al.Corrosion behavior of 316L stainless steel in supercritical water environment[J].Material Science and Enginering,2005:475-479.
【14】SOMERDAY B P,WIGGANS K T,BRADSHAW R W.Environment assisted failure of alloy C-276 burst disks in a batch supercritical water oxidation reactor[J].Enginering Failure Analysis,2006:80-95.
【15】BAUR S,SCHMIDT H,KRAMER A,et al.The destruction of industrial aqueous waste containing biocides in supercritical water development of the SUWOX process for the technical application[J].The Journal of Supercritical Fluids,2005,33(2):149-157.
【16】赵军霞,柴涛,赵双喜,等.超临界水氧化六硝基菧废水及其对反应釜腐蚀研究[J].水处理技术,2010,36(12):50-54.
【17】唐兴颖,王树众,徐东海,等.超临界水氧化城市污泥中316L不锈钢的腐蚀行为[J].腐蚀与防护,2011,32(7):501-506.
【18】马承愚,姜安玺,彭英利,等.含氯介质超临界水氧化过程中几种镍基合金腐蚀的实验研究[J].过程工程学报,2006,6(1):124-127.
【19】SANG H S,JAE H L,CHANG H L.Corrosion phenomena of alloys by subcritical and supercritical water oxidation of 2-chlorophenol[J].The Journal of Supercritical Fluids,2008,44:370-378.
【20】SON S H,LEE J H,BYEON S H,et al.Surface chemical analysis of corroded alloys in subcritical and supercritical water oxidation of 2-chlorpenol in continuous anticorrosive react system[J].Industrial & Engineering Chemistry Research,2008,47(7):2265-2272.
【21】ZHANG Q,TANG R,YIN K J,et al.Corrosion behavior of hastelloy C-276 in supercritical water[J].Corrosion Science,2009,51(9):2092-2097.
【22】GAO X,WU X Q,ZHANG Z E,et al.Characterization of oxide films grown on 316L stainless steel exposed to H2O2-containing supercritical water[J].The Journal of Supercritical Fluids,2007,42(1):157-163.
【23】SUN C,HUI R,QU W,et al.Progress in corrosion resistant for supercritical water reactors[J].Corrosion,2009,51:2508-2523.
【24】SUN M,WU X,ZHANG Z,et al.Analyses of oxide films grown on alloy 625 in oxidizing supercritical water[J].The Journal of Supercritical Fluids,2008,47:309-317.
【25】XING Y T,SHU Z W,DONG H X,et al.Corrosion behavior of Ni-based alloys in supercritical water containing high concentrations of salt and oxygen[J].Industrial & Engineering Chemistry Research,2013:52,18241-18250.
【26】李海丰,范洪远,张强,等.C-276镍基合金在600 ℃超临界水中的腐蚀产物及形成的机理研究[J].核动力工程,2011,2(3):38-42.
【27】SUN M C,WU X Q,ZHANG Z E,et al.Aanlyses of oxide film formed grown on alloy 625 in oxidizing supercritical water[J].Supercritical Fluids,2008,47(2):309-317.
【28】EDOUARD A,AKFRAM A,STEVEN R.Corrosion of nickel-chromium alloys,stainless steel and niobium at supercritical water oxidation conditions[J].Corrosion Science,2010:118-124.
【29】黄寿强,申哲民,朱南,等.几种高温合金在超临界NaCl水溶液中的腐蚀行为对比[J].机械工程材料,2014,38(2):48-53.
【30】PETER K.Corrosion in high-temperature and supercritical water and aqueous solutions[J].Journal of Supercritical Fluids,2004,29(5):1-29.
【31】王增品,姜安玺.腐蚀与防护工程[M].北京:高等教育出版社,1991.
【32】CHUNWEN S,ROB H,WEI Q.Progress in corrosion resistant materials for supercritical water reactor[J].Corrosion Science,2009:2508-2523.
【33】马承愚,姜安玺,彭英利,等.钛合金在超临界水氧化含氯废水介质中腐蚀的研究[J].云南大学学报,2006,28(S1):274-276.
【34】MARRONE P A,HONG G T.Corrosion control methods in supercritical water oxidation and gasification processes[J].The Journal of Supercritical Fluids,2009,51(2):83-103.
【35】MARRONE P A,CANTWELL S D,DALTON D W.SCWO system designs for waste treatment:application to chemical weapons destruction[J].Industrial & Engineering Chemistry Research,2005,44(24):9030-9039.
【36】JAE H,SANG H S,TRAN T V,et al.Decomposition of 2-chlorophenol by supercritical water oxidation with zirconium corrosion[J].Korean Journal of Chemical Engineering,2009,26(2):398-402.
【37】龚为进.蒸发壁式超临界水氧化反应器处理高浓度有机废水实验研究[D].上海:东华大学硕士学位论文,2008.
【38】徐玥,龚为进,姜佩华,等.国外超临界水氧化技术的研究现状[J].工业用水与废水,2007,38(6):8-11.
【39】GARCIA K M,MIZIA R E.Heat transfer division[M].New York:American Society of Mechanical Engineers,1995.
【40】ROSS D S,JAYAWEERA I.Environmentally acceptable waste disposal by hydrothermal decomposition of labile compounds with nitrite:US,5709800[P].1998-07-21.
【41】ABELN J,KLUTH M,PAGEL M.Results and rough cost estimation for SCWO of painting effluents using a transpiring wall and a pipe reactor[J].Journal of Advanced Oxidation Technologies,2007,10(1):169-176.
【42】KIRA M,KUZUME H.Systems and equipment for realizing clean environment[J].Mitsubishi Heavy Industries Ltd.Technical Review,2003,40(1):1-5.
【43】LEE H,IN J H,LEE S Y,et al.An anti-corrosive reactor for the decomposition of halogenated hydrocarbons with supercritical water oxidation[J].The Journal of Supercritical Fluids,2005,36(1):59-69.
【44】HYEON C L,JUNG H I,SANG Y L,et al.An anti-corrosive reactor for the decomposition of halogenated hydrocarbons with supercritical water oxidation[J].The Journal of Supercritical Fluids,2005,36:59-69.
【45】MUEGGENBURG H H,ROUSAR D C,YOUNG M F.Supercritical water oxidation reactor with wall conduits for boundary flow control:US,5387398[P].1995-02-07.
【46】ABELN J,KLUTH M,BOTTEHER M,et al.Supercritical water oxidation (SCWO) using a transpiring wall reactor:CFD simulations and experimental results of ethanol oxidation[J].Environmental Engineering Seience,2004,21(1):93-99.
【47】WELLIG B,LIEBALL K,VON R P R.Operating characteristics of transpiring-wall SCWO reactor with a hydrothermal flame as internal heat source[J].The Journal of Supercritical Fluids,2005,34(1):35-50.
【48】PRKOPSKY K,WELLIG B,Von Rohr P R.SCWO of salt containing artificial waste water using a transpiring-wall reactor:experimental results[J].The Journal of Supercritical Fluids,2007,40(2):246-257.
【49】龚为进,李方,奚旦立.丙烯酸废水超临界水氧化动力学研究[J].环境工程学报,2008(5):643-646.
【50】龚为进,李方,奚旦立.超临界水氧化处理高浓度丙烯酸废水[J].化工环保,2007,27(5):413-416.
【51】陈忠,王光伟,陈鸿珍,等.气封壁高浓度有机污染物超临界水氧化处理系统[J].环境工程学报,2014(9):3825-3831.
【52】张勇,张凤鸣,马春元,等.超临界水氧化气膜反应器模拟[J].现代化工,2013,33(11):110-114.
【53】廖传华,朱跃钊,李永生.超临界水氧化反应器的研究进展[J].环境工程,2010,23(2):7-10.
【54】廖传华,褚旅云,李瑞容,等.一种超临界水氧化反应器及处理废水的方法[P].ZL200910027764.9,2009.
【2】朱自强.超临界流体技术-原理和应用[M].北京:化学工业出版社,2000.
【3】COCERO M J,ALONSO E,SANZ M T,et al.Supercritical water oxidation process under energetically self sufficient operation[J].Supercritical Fluids,2002,24(1):37-46.
【4】张丽,韩恩厚,关辉,等.超临界水氧化环境中材料腐蚀的研究现状[J].材料导报,2001,15(5):8-10.
【5】XIU D.Treatment of high strength coking waste water by supercritical water oxidation[J].Fuel,2013,89:77-82.
【6】HIROSE T,SHIBA K,ENOEDA M,et al.Corrosion and stress corrosion cracking of ferritic/martensition steel in supercritical pressurized water[J].Nucl Mater,2007,367:1185-1189.
【7】闫康平,陈匡民.过程装备腐蚀与防护[M].北京:化学工业出版社,2009.
【8】PHILIP A M,GLENN T H.Corrosion control methods in supercritical water oxidation and gasification processes[J].The Journal of Supercritical Fluids,2009:83-103.
【9】BRUNNER G.Near and supercritical water.Part II:Oxidative processes[J].The Journal of Supercritical Fluids,2009:382-390.
【10】黄晓慧,王增长,崔文全,等.超临界水氧化过程中的腐蚀控制方法[J].工业水处理,2013,33(12):6-10.
【11】JIAN L S,ZHI Y M,JIU Y Z,et al.A corrosion of titanium in supercritical water oxidation environments[J].Transactions of Nonferrous Metals Society of China,2002,12(6):1054-1060.
【12】STEIN A,FELCH C,DOYLE E F.Material selection for hydrothermal oxidation processes for the disposal of chemical demilitarization hazardous waste[J].Corrosion,2006,134-142.
【13】YOON J H,SON K S,KIM H S,et al.Corrosion behavior of 316L stainless steel in supercritical water environment[J].Material Science and Enginering,2005:475-479.
【14】SOMERDAY B P,WIGGANS K T,BRADSHAW R W.Environment assisted failure of alloy C-276 burst disks in a batch supercritical water oxidation reactor[J].Enginering Failure Analysis,2006:80-95.
【15】BAUR S,SCHMIDT H,KRAMER A,et al.The destruction of industrial aqueous waste containing biocides in supercritical water development of the SUWOX process for the technical application[J].The Journal of Supercritical Fluids,2005,33(2):149-157.
【16】赵军霞,柴涛,赵双喜,等.超临界水氧化六硝基菧废水及其对反应釜腐蚀研究[J].水处理技术,2010,36(12):50-54.
【17】唐兴颖,王树众,徐东海,等.超临界水氧化城市污泥中316L不锈钢的腐蚀行为[J].腐蚀与防护,2011,32(7):501-506.
【18】马承愚,姜安玺,彭英利,等.含氯介质超临界水氧化过程中几种镍基合金腐蚀的实验研究[J].过程工程学报,2006,6(1):124-127.
【19】SANG H S,JAE H L,CHANG H L.Corrosion phenomena of alloys by subcritical and supercritical water oxidation of 2-chlorophenol[J].The Journal of Supercritical Fluids,2008,44:370-378.
【20】SON S H,LEE J H,BYEON S H,et al.Surface chemical analysis of corroded alloys in subcritical and supercritical water oxidation of 2-chlorpenol in continuous anticorrosive react system[J].Industrial & Engineering Chemistry Research,2008,47(7):2265-2272.
【21】ZHANG Q,TANG R,YIN K J,et al.Corrosion behavior of hastelloy C-276 in supercritical water[J].Corrosion Science,2009,51(9):2092-2097.
【22】GAO X,WU X Q,ZHANG Z E,et al.Characterization of oxide films grown on 316L stainless steel exposed to H2O2-containing supercritical water[J].The Journal of Supercritical Fluids,2007,42(1):157-163.
【23】SUN C,HUI R,QU W,et al.Progress in corrosion resistant for supercritical water reactors[J].Corrosion,2009,51:2508-2523.
【24】SUN M,WU X,ZHANG Z,et al.Analyses of oxide films grown on alloy 625 in oxidizing supercritical water[J].The Journal of Supercritical Fluids,2008,47:309-317.
【25】XING Y T,SHU Z W,DONG H X,et al.Corrosion behavior of Ni-based alloys in supercritical water containing high concentrations of salt and oxygen[J].Industrial & Engineering Chemistry Research,2013:52,18241-18250.
【26】李海丰,范洪远,张强,等.C-276镍基合金在600 ℃超临界水中的腐蚀产物及形成的机理研究[J].核动力工程,2011,2(3):38-42.
【27】SUN M C,WU X Q,ZHANG Z E,et al.Aanlyses of oxide film formed grown on alloy 625 in oxidizing supercritical water[J].Supercritical Fluids,2008,47(2):309-317.
【28】EDOUARD A,AKFRAM A,STEVEN R.Corrosion of nickel-chromium alloys,stainless steel and niobium at supercritical water oxidation conditions[J].Corrosion Science,2010:118-124.
【29】黄寿强,申哲民,朱南,等.几种高温合金在超临界NaCl水溶液中的腐蚀行为对比[J].机械工程材料,2014,38(2):48-53.
【30】PETER K.Corrosion in high-temperature and supercritical water and aqueous solutions[J].Journal of Supercritical Fluids,2004,29(5):1-29.
【31】王增品,姜安玺.腐蚀与防护工程[M].北京:高等教育出版社,1991.
【32】CHUNWEN S,ROB H,WEI Q.Progress in corrosion resistant materials for supercritical water reactor[J].Corrosion Science,2009:2508-2523.
【33】马承愚,姜安玺,彭英利,等.钛合金在超临界水氧化含氯废水介质中腐蚀的研究[J].云南大学学报,2006,28(S1):274-276.
【34】MARRONE P A,HONG G T.Corrosion control methods in supercritical water oxidation and gasification processes[J].The Journal of Supercritical Fluids,2009,51(2):83-103.
【35】MARRONE P A,CANTWELL S D,DALTON D W.SCWO system designs for waste treatment:application to chemical weapons destruction[J].Industrial & Engineering Chemistry Research,2005,44(24):9030-9039.
【36】JAE H,SANG H S,TRAN T V,et al.Decomposition of 2-chlorophenol by supercritical water oxidation with zirconium corrosion[J].Korean Journal of Chemical Engineering,2009,26(2):398-402.
【37】龚为进.蒸发壁式超临界水氧化反应器处理高浓度有机废水实验研究[D].上海:东华大学硕士学位论文,2008.
【38】徐玥,龚为进,姜佩华,等.国外超临界水氧化技术的研究现状[J].工业用水与废水,2007,38(6):8-11.
【39】GARCIA K M,MIZIA R E.Heat transfer division[M].New York:American Society of Mechanical Engineers,1995.
【40】ROSS D S,JAYAWEERA I.Environmentally acceptable waste disposal by hydrothermal decomposition of labile compounds with nitrite:US,5709800[P].1998-07-21.
【41】ABELN J,KLUTH M,PAGEL M.Results and rough cost estimation for SCWO of painting effluents using a transpiring wall and a pipe reactor[J].Journal of Advanced Oxidation Technologies,2007,10(1):169-176.
【42】KIRA M,KUZUME H.Systems and equipment for realizing clean environment[J].Mitsubishi Heavy Industries Ltd.Technical Review,2003,40(1):1-5.
【43】LEE H,IN J H,LEE S Y,et al.An anti-corrosive reactor for the decomposition of halogenated hydrocarbons with supercritical water oxidation[J].The Journal of Supercritical Fluids,2005,36(1):59-69.
【44】HYEON C L,JUNG H I,SANG Y L,et al.An anti-corrosive reactor for the decomposition of halogenated hydrocarbons with supercritical water oxidation[J].The Journal of Supercritical Fluids,2005,36:59-69.
【45】MUEGGENBURG H H,ROUSAR D C,YOUNG M F.Supercritical water oxidation reactor with wall conduits for boundary flow control:US,5387398[P].1995-02-07.
【46】ABELN J,KLUTH M,BOTTEHER M,et al.Supercritical water oxidation (SCWO) using a transpiring wall reactor:CFD simulations and experimental results of ethanol oxidation[J].Environmental Engineering Seience,2004,21(1):93-99.
【47】WELLIG B,LIEBALL K,VON R P R.Operating characteristics of transpiring-wall SCWO reactor with a hydrothermal flame as internal heat source[J].The Journal of Supercritical Fluids,2005,34(1):35-50.
【48】PRKOPSKY K,WELLIG B,Von Rohr P R.SCWO of salt containing artificial waste water using a transpiring-wall reactor:experimental results[J].The Journal of Supercritical Fluids,2007,40(2):246-257.
【49】龚为进,李方,奚旦立.丙烯酸废水超临界水氧化动力学研究[J].环境工程学报,2008(5):643-646.
【50】龚为进,李方,奚旦立.超临界水氧化处理高浓度丙烯酸废水[J].化工环保,2007,27(5):413-416.
【51】陈忠,王光伟,陈鸿珍,等.气封壁高浓度有机污染物超临界水氧化处理系统[J].环境工程学报,2014(9):3825-3831.
【52】张勇,张凤鸣,马春元,等.超临界水氧化气膜反应器模拟[J].现代化工,2013,33(11):110-114.
【53】廖传华,朱跃钊,李永生.超临界水氧化反应器的研究进展[J].环境工程,2010,23(2):7-10.
【54】廖传华,褚旅云,李瑞容,等.一种超临界水氧化反应器及处理废水的方法[P].ZL200910027764.9,2009.
相关信息
